Research Project
Grant-in-Aid for Challenging Exploratory Research
The sigma 5 (310)[001] MgO bicrystal was used as model system. Analyses of microstructure and electronic state near the boundary were performed based on an aberration corrected scanning transmission electron microscopy (STEM).The high angular annular dark field image in STEM showed formation of well-contacted atomically flat interface and also impurities segregation at or near the boundary. Ca and Ti impurities were detected at or near the boundary. The location of Ca and Ti atoms were examined by using atomic resolution elemental mapping. The elemental mapping revealed that the Ca atoms are localized only at the boundary, but Ti atoms form atomic wires along the neighboring sites of Ca. The theoretical calculation showed that Ti atomic wire induces semi conducing behavior in MgO insulator.
All 2014 2013 2012
All Journal Article (11 results) (of which Peer Reviewed: 11 results, Open Access: 2 results) Presentation (9 results) (of which Invited: 8 results) Book (3 results)
Nature Communications
Volume: 5
Volume: 5 Issue: 1
10.1038/ncomms4239
Angewandte Chemie International Edition
Volume: 126 Issue: 6 Pages: 1569-1573
10.1002/ange.201307689
Advanced Materials
Volume: 25
Nature Nanotechnology
Volume: 8
Volume: 126
Volume: 25[2] Issue: 2 Pages: 218-222
10.1002/adma.201203134
ACS NANO
Volume: 7 Issue: 7 Pages: 6310-6320
10.1021/nn4023679
Volume: 8 Issue: 4 Pages: 266-270
10.1038/nnano.2013.45
Journal of Applied Physics
Volume: 111(11) Issue: 11 Pages: 113717-113717
10.1063/1.4729074
Journal of Materials Science
Volume: 47(13) Issue: 13 Pages: 5148-5157
10.1007/s10853-012-6392-4