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Realization of four states in Bi-based ferroelectric materials with giant self-strain

Research Project

Project/Area Number 24656378
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Inorganic materials/Physical properties
Research InstitutionTokyo Institute of Technology

Principal Investigator

FUNAKUBO HIROSHI  東京工業大学, 総合理工学研究科(研究院), 教授 (90219080)

Co-Investigator(Kenkyū-buntansha) KIGUCHI Takanori  東北大学, 金属材料研究所, 准教授 (70311660)
Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords誘電体物質 / 強誘電体 / エピタキシャル膜 / 分極状態 / 誘電体物性
Research Abstract

Four states are tried to realize using Bi-based ferroelectric films having more than 20% self-strain. Epitaxial films having both of about 7 and 22% tetragonlity were successfully grown by changing the x values in [(2/3)[Bi((Zn1-xMgx)1/2Ti1/2)O3]-(1/3)[BiFeO3]. However,their tetragonality did not drastically change up to 800 degree. Epitaxial Bi((ZnxMg1-x)1/2Ti1/2)O3 films having about 22% tetragonlity were also grown, but smaller one cannot be obtained.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (35 results)

All 2014 2013 2012 Other

All Journal Article (19 results) (of which Peer Reviewed: 17 results) Presentation (14 results) Remarks (2 results)

  • [Journal Article] 巨大正方晶強誘電体薄膜2013

    • Author(s)
      安井伸太郎, 舟窪 浩
    • Journal Title

      工業製品技術協会(株式会社テクノプラザ)セラミックスデータブック 2013/14 工業と製品

      Volume: 41(95) Pages: 153-157

    • Related Report
      2013 Final Research Report
  • [Journal Article] Fabrication of BiFeO_3-Bi(Zn_1/2Ti_1/2)O_3 Solid Solution Thin Films Using Perovskite-Type Oxide Interface Layer2013

    • Author(s)
      Mari Hayashi, Shintaro Yasui, Hiroshi Funakubo, and Hiroshi Uchida
    • Journal Title

      Key. Eng. Mater

      Volume: 566 Pages: 163-166

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Unusual 90o domain structure in (2/3)Bi(Zn_1/2Ti_1/2)O_3 - (1/3)BiFeO_3 epitaxial films with giant 22% tetragonal distortion2013

    • Author(s)
      Shintaro Yasui, Keisuke Yazawa, Masaaki Matsushima, Tomoaki Yamada, Hiroshi Funakubo, Hitoshi Morioka, Hiroshi Uchida, Takashi Iijima, Lu You, and Junling Wang
    • Journal Title

      Appl. Phys Lett

      Volume: 103

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Bismuth – Based Perovskites with Non-integer A and B Site Valence and Their Properties2013

    • Author(s)
      Ichiro Fujii, Atsushi Shimamura, Kouichi Nakashima, Nobuhiro Kumada, Hiroshi Funakubo, Yoshihiro Kuroiwa, and Satoshi Wada
    • Journal Title

      Trans. Mater.Res. Soc. Jpn

      Volume: 8[1] Pages: 49-52

    • NAID

      130005004192

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Growth of (111) One-Axis-Oriented Bi(Mg_1/2Ti_1/2)O_3 Films on (100)Si Substrates2013

    • Author(s)
      Takahiro Oikawa, Shintaro Yasui, Takayuki Watanabe, Koji Ishii, Yoshitaka Ehara, Hisato Yabuta, Takeshi Kobayashi, Tetsuro Fukui, Kaoru Miura, and Hiroshi Funakubo
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 52

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Small-strain (100) / (001) -oriented Epitaxial PbTiO_3 Films with Film Thickness Ranging From Nano to Micrometer Order Grown on (100)CaF_2 Substrates by Metal Organic Chemical Vapor Deposition2013

    • Author(s)
      Mohamed-Tahar Chentir, Satoru Utsugi, Takashi Fujisawa, Yoshitaka Ehara, Mutsuo Ishikawa, Hitoshi orioka, Tomoaki Yamada, Masaaki Matsushima, and Hiroshi Funakubo
    • Journal Title

      J. Mater. Res

      Volume: 28(5) Pages: 696-701

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Growth of (111) One-Axis-Oriented Bi(Mg1/2Ti1/2)O3 Films on (100)Si Substrates2013

    • Author(s)
      Takahiro Oikawa, Shintaro Yasui, Takayuki Watanabe, Koji Ishii, Yoshitaka Ehara, Hisato Yabuta, Takeshi Kobayashi, Tetsuro Fukui, Kaoru Miura, and Hiroshi Funakubo
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 52

    • NAID

      210000142080

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Bismuth-Based Perovskites with Non-integer A and B Site Valence and Their Properties.2013

    • Author(s)
      Ichiro Fujii, Atsushi Shimamura, Kouichi Nakashima, Nobuhiro Kumada, Hiroshi Funakubo,Yoshihiro Kuroiwa, and Satoshi Wada
    • Journal Title

      Trans. Mat. Res. Soc. Japan.

      Volume: 38[1] Pages: 49-52

    • NAID

      130005004192

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unusual 90° domain structure in (2/3)Bi(Zn1/2Ti1/2)O3-(1/3)BiFeO3 epitaxial films with giant 22% tetragonal distortion2013

    • Author(s)
      Shintaro Yasui,, Keisuke Yazawa, Masaaki Matsushima,Tomoaki Yamada, Hiroshi Funakubo, Hitoshi Morioka, Hiroshi Uchida,Takashi Iijima, Lu You, and Junling Wang
    • Journal Title

      Appl. Phys. Lett.

      Volume: 103

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of BiFeO3-Bi(Zn1/2Ti1/2)O3 Solid Solution Thin Films Using Perovskite-Type Oxide Interface Layer2013

    • Author(s)
      Mari Hayashi, Shintaro Yasui, Hiroshi Funakubo, and Hiroshi Uchida
    • Journal Title

      Key. Eng. Mater.

      Volume: 566 Pages: 163-166

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 巨大正方晶強誘電体薄膜2013

    • Author(s)
      安井伸太郎、舟窪 浩
    • Journal Title

      セラミックスデータブック 2013/14工業と製品

      Volume: Vol.41 No.95 Pages: 153-157

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Small-strain (100)/(001)-oriented epitaxial PbTiO3 films with film thickness ranging from nano to micrometer order grown on (100)CaF2 substrates by metal organic chemical vapor deposition2013

    • Author(s)
      Mohamed-Tahar Chentir, Satoru Utsugi, Takashi Fujisawa, Yoshitaka Ehara, Mutsuo Ishikawa, Hitoshi Morioka, Tomoaki Yamada, Masaaki Matsushima, and Hiroshi Funakubo
    • Journal Title

      J. Mater Res.

      Volume: 28(5) Pages: 696-701

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Growth of (111) One-Axis-Oriented Bi(Mg1/2Ti1/2)O3 Films on (100)Si Substrates2013

    • Author(s)
      Takahiro Oikawa, Shintaro Yasui, Takayuki Watanabe, Koji Ishii, Yoshitaka Ehara, Hisato Yabuta, Takeshi Kobayashi, Tetsuro Fukui, Kaoru Miura, and Hiroshi Funakubo
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 52

    • NAID

      210000142080

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Film Thickness Dependence of Ferroelectric Properties of (111)-Oriented Epitaxial Bi(Mg_1/2Ti_1/2)O_3 Films2012

    • Author(s)
      Takahiro Oikawa, Shintaro Yasui, Takayuki Watanabe, Hisato Yabuta, Yoshitaka Ehara, Tetsuro Fukui, and Hiroshi Funakubo
    • Journal Title

      Jpn. J. App. Phys

      Volume: 51

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Complex Domain Structure in Relaxed PbTiO_3 Thick Films Grown on (100)_cSrRuO_3//(100)SrTiO_3 Substrates2012

    • Author(s)
      Shintaro Yasui, Yoshitaka Ehara, Satoru Utsugi, Mitsumasa Nakajima, Hiroshi Funakubo, and Alexei Gruverman
    • Journal Title

      J. Appl. Phys

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Growth of (111)-oriented BaTiO_3 - Bi(Mg_<0.5>Ti_<0.5>)O_3 Epitaxial Films and Their Crystal Structure and Electrical Property Characterizations2012

    • Author(s)
      Hidenori Tanaka, M.T. Chentir, Tomoaki Yamada, Shintaro Yasui, Yoshitaka Ehara, Keisuke Yamato, Yuta Kashiwagi, Chua Ngeah Theng, Junling Wang, Soichiro Okamura, Hiroshi Uchida, Takashi Iijima, Satoshi Wada, and Hiroshi Funakubo
    • Journal Title

      J. Appl. Phys

      Volume: 111 Pages: 84108-84108

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Growth of (111)-oriented BaTiO_3-Bi(Mg_<0.5>Ti_<0.5>)O_3 epitaxial films and their crystal structure and electrical property characterizations2012

    • Author(s)
      Hidenori Tanaka, Mohamed- Tahar Chentir, Tomoaki Yamada, Shintaro Yasui, Yoshitaka Ehara, Keisuke Yamato, Yuta Kashiwagi, Chua Ngeah Theng, Junling Wang, Soichiro Okamura, Hiroshi Uchida, Takashi Iijima, Satoshi Wada, Hiroshi Funakubo
    • Journal Title

      J. Appl. Phys.

      Volume: 112 Issue: 8 Pages: 84108-84108

    • DOI

      10.1063/1.4704384

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Complex Domain Structure in Relaxed PbTiO3 Thick Films Grown on (100)cSrRuO3//(100)SrTiO3 Substrates2012

    • Author(s)
      Shintaro Yasui, Yoshitaka Ehara, Satoru Utsugi, Mitsumasa Nakajima, Hiroshi Funakubo, and Alexei Gruverman
    • Journal Title

      J. Appl. Phys.

      Volume: 112

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Film Thickness Dependence of Ferroelectric Properties of (111)-Oriented Epitaxial Bi(Mg1/2Ti1/2)O3 Films2012

    • Author(s)
      Takahiro Oikawa, Shintaro Yasui, Takayuki Watanabe, Hisato Yabuta, Yoshitaka Ehara, Tetsuro Fukui, and Hiroshi Funakubo
    • Journal Title

      Jpn. J. App. Phys.

      Volume: 51

    • NAID

      210000141222

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Piezoresponse behavior at a Morphotropic Phase Boundary in (Bi,Sm)FeO_3 Films2014

    • Author(s)
      S. Yasui, Y. Ehara, T. Shiraishi, T. Shimizu,H. Funakubo, M. Itoh, Y. Imai, H. Tajiri, O.Sakata, I. Takeuchi
    • Organizer
      Electronic Materialsand Applications 2014
    • Place of Presentation
      Double Tree by Hilton Orland at Sea World,Orland, FL., USA
    • Related Report
      2013 Final Research Report
  • [Presentation] Piezoresponse behavior at a Morphotropic Phase Boundary in (Bi,Sm)FeO3 Films2014

    • Author(s)
      S. Yasui, Y. Ehara, T. Shiraishi, T. Shimizu, H. Funakubo, M. Itoh, Y. Imai, H. Tajiri, O. Sakata,and I. Takeuchi
    • Organizer
      Electronic Materials and Applications 2014
    • Place of Presentation
      Double Tree by Hilton Orland at Sea World, Orland, FL., USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Characterizations of Bi(Mg_1/2Ti_1/2)O_3 - Bi(Zn_1/2Ti_1/2)O_3 Solid Solution Films Prepared by Pulsed Laser Deposition2013

    • Author(s)
      Takahiro Oikawa, Shintaro Yasui, TakayukiWatanabe, Hisato Yabuta, Kaoru Miura,Takeshi Kobayashi, and Hiroshi Funakubo
    • Organizer
      2013JSAP-MRS Joint Symposia
    • Place of Presentation
      Doshisha University, Kyoto,Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] PLD法によるBi(Mg_1/2Ti_1/2)O_3基固溶体膜の作製と評価2013

    • Author(s)
      及川貴弘, 安井伸太郎, 真鍋直人, 渡邉隆之, 薮田久人, 三浦薫, 小林健, 舟窪浩
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2013 Final Research Report
  • [Presentation] Characterizations of Bi(Mg1/2Ti1/2)O3-Bi(Zn1/2Ti1/2)O3 Solid Solution Films Prepared by Pulsed Laser Deposition2013

    • Author(s)
      Takahiro Oikawa, Shintaro Yasui, Takayuki Watanabe, Hisato Yabuta, Kaoru Miura, Takeshi Kobayashi, and Hiroshi Funakubo
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府)
    • Related Report
      2013 Annual Research Report
  • [Presentation] PLD法によるBi(Mg1/2Ti1/2)O3基固容体膜の作製と評価2013

    • Author(s)
      及川貴弘、安井伸太郎、真鍋直人、渡邉隆之、薮田久人、三浦薫、小林健、舟窪浩
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川工科大学(神奈川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 高圧合成法で作製したBi(Zn_1/2Ti_1/2)O_3 - Bi(Mg_1/2Ti_1/2)O_3 - BiFeO_3系における単斜晶相の特徴2012

    • Author(s)
      真鍋直人, 安井伸太郎, 坂口智可, 岡研吾, 東正樹, 舟窪浩
    • Organizer
      第32回エレクトロセラミックス研究討論会
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] Characterization of Lead-free Piezoelectric Bi(Mg_1/2Ti_1/2)O_3 Films2012

    • Author(s)
      T. Oikawa, S. Yasui, T. Watanabe, H. Yabuta, T. Fukui, and H. Funakubo
    • Organizer
      IUMRSInternational Conference on Electronic Materials 2012 (IUMRS-ICEM 2012)
    • Place of Presentation
      Pacifico Yokohama,Yokohama, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] シリコン基板上に作製したビスマス基圧電体膜の特性評価2012

    • Author(s)
      及川貴弘,安井伸太郎,真鍋直人,小林健,渡邉隆之,薮田久人,三浦 薫,舟窪 浩
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      松山大学文京キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] PLD 法で作製したBi(Mg_1/2Ti_1/2)O_3 膜の評価2012

    • Author(s)
      及川貴弘, 安井伸太郎, 渡邉隆之, 薮田久人, 福井哲朗, 舟窪 浩
    • Organizer
      第29回強誘電体応用会議(FMA29)
    • Place of Presentation
      コープイン京都
    • Related Report
      2013 Final Research Report
  • [Presentation] PLD法で作製したBi(Mg1/2Ti1/2)O3膜の評価2012

    • Author(s)
      及川貴弘、安井伸太郎、渡邉隆之、薮田久人、福井哲朗、舟窪浩
    • Organizer
      第29回強誘電体応用会議(FMA29)
    • Place of Presentation
      コープイン京都(京都府)
    • Related Report
      2012 Research-status Report
  • [Presentation] シリコン基板上に作製したビスマス基圧電体膜の特性評価2012

    • Author(s)
      及川貴弘,安井伸太郎,真鍋直人,小林健,渡邉隆之,薮田久人,三浦薫,舟窪浩
    • Organizer
      第73回応用物理学会秋季学術講演会
    • Place of Presentation
      松山大学 文京キャンパス(愛媛県)
    • Related Report
      2012 Research-status Report
  • [Presentation] Characterization of lead-free piezoelectric Bi(Mg1/2Ti1/2)O3 films2012

    • Author(s)
      T. Oikawa, S. Yasui, T. Watanabe, H. Yabuta, T. Fukui, and H. Funakubo
    • Organizer
      IUMRS-International Conference on Electronic Materials(IUMRS-ICEM 2012)
    • Place of Presentation
      Pacifico Yokohama, Yokohama, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] 高圧合成法で作製したBi(Zn1/2Ti1/2)O3-Bi(Mg1/2Ti1/2)O3-BiFeO3系における単斜晶相の特徴2012

    • Author(s)
      真鍋直人、安井伸太郎、坂口智可、岡研吾、東正樹、舟窪浩
    • Organizer
      第32回エレクトロセラミックス研究討論会
    • Place of Presentation
      東京工業大学 大岡山キャンパス(東京都)
    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://f-lab.iem.titech.ac.jp/

    • Related Report
      2013 Final Research Report
  • [Remarks] 東京工業大学 舟窪研究室

    • URL

      http://f-lab.iem.titech.ac.jp/f-lab.htm

    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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