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Dense-structured Mg-O films formation by X-ray radiation and its application to surface modification

Research Project

Project/Area Number 24656446
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Material processing/treatments
Research InstitutionOsaka University

Principal Investigator

KONDOH Katsuyoshi  大阪大学, 接合科学研究所, 教授 (50345138)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywords表面・界面制御 / X線照射 / 電子励起場 / ラジカル種 / 酸化皮膜 / 表面電位 / 塩水浸漬試験
Research Abstract

Mg is easy to corrode because of its low standard electrode potential. In this study, a new method of corrosion protection using the surface potential change of pure Mg was investigated. The surface potential of pure Mg was changed by electron excitation. The correlation between surface potential variation and galvanic corrosion behavior was investigated by Scanning Kelvin Probe Force Microscopy. The electron excited area by X-ray irradiation analyzed by SEM-EDS showed lower surface potential than that of the as-polished area. The value of VSPC increased with the increase amounts of the electron irradiation. VSPC can be controlled by amounts of the electron irradiation. Salt water immersion test was conducted in order to investigate the effect of VSPC on corrosion phenomena. It reveals that electron excited area showed excellent corrosion resistance. It is concluded that X-ray irradiation excitation possibly improves corrosion resistance of pure Mg.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (12 results)

All 2013 2012 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (6 results)

  • [Journal Article] Quantitative evaluation of initial galvanic corrosion behavior of CNTs reinforced Mg–Al alloy2013

    • Author(s)
      Keisuke Funatsu, Hiroyuki Fukuda, Rei Takei, Junko Umeda, Katsuyoshi Kondoh
    • Journal Title

      Advanced Powder Technology

      Volume: 24

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Quantitative evaluation of initial galvanic corrosion behavior of CNTs2013

    • Author(s)
      Keisuke Funatsu, Hiroyuki Fukuda, Rei Takei, Junko Umeda, Katsuyoshi Kondoh
    • Journal Title

      Advanced Powder Technology

      Volume: 24 Issue: 5 Pages: 833-837

    • DOI

      10.1016/j.apt.2013.02.002

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] X線照射による励起場形成を利用した純マグネシウムの表面改質現象2012

    • Author(s)
      船津恵介,梅田純子,高橋誠,近藤勝義
    • Journal Title

      スマートプロセス学会誌

      Volume: 1巻 Pages: 293-297

    • NAID

      10031134283

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mg合金中の微視的異材界面における表面電位差が初期ガルバニック腐食現象へ及ぼす影響2012

    • Author(s)
      船津恵介,竹井怜,梅田純子,近藤勝義
    • Journal Title

      日本機械学会論文集(A編)

      Volume: 78巻 Pages: 616-622

    • NAID

      130002050367

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] X線照射による励起場形成を利用した純マグネシウムの表面改質現象2012

    • Author(s)
      船津恵介,梅田純子,高橋誠,近藤勝義
    • Journal Title

      スマートプロセス学会誌

      Volume: 1 Pages: 293-297

    • NAID

      10031134283

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Mg合金中の微視的異材界面における表面電位差が初期ガルバニック腐食現象へ及ぼす影響2012

    • Author(s)
      船津恵介,竹井怜,梅田純子,近藤勝義
    • Journal Title

      日本機械学会論文集(A編)

      Volume: 78 Pages: 616-622

    • NAID

      130002050367

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Potential difference at interface between second phases and metal matrix measured by SKPFM2012

    • Author(s)
      Katsuyoshi Kondoh, Keisuke Funatsu, Junko Umeda, Hisashi Imai
    • Organizer
      The 5th International Symposium on Designing, Processing and Properties of Advanced Engineering Materials
    • Year and Date
      2012-11-06
    • Related Report
      2013 Final Research Report
  • [Presentation] X線照射による表面改質を施した純マグネシウムの腐食現象2012

    • Author(s)
      船津恵介,梅田純子,近藤勝義
    • Organizer
      日本機械学会2012年度年次大会
    • Year and Date
      2012-09-10
    • Related Report
      2013 Final Research Report
  • [Presentation] Surface Potential Controlled by Al Additive at Interface between Mg Matrix and CNTs2012

    • Author(s)
      Keisuke Funatsu, Hiroyuki Fukuda, Rei Takei, Junko Umeda, Katsuyoshi Kondoh
    • Organizer
      The Fourth International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials
    • Year and Date
      2012-09-03
    • Related Report
      2013 Final Research Report
  • [Presentation] Potential difference at interface between second phases and metal matrix measured by SKPFM

    • Author(s)
      Katsuyoshi Kondoh, Keisuke Funatsu, Junko Umeda, Hisashi Imai
    • Organizer
      The 5th International Symposium on Designing, Processing and Properties of Advanced Engineering Materials
    • Place of Presentation
      ロワジールホテル豊橋(愛知県)
    • Related Report
      2012 Research-status Report
  • [Presentation] X線照射による表面改質を施した純マグネシウムの腐食現象

    • Author(s)
      船津恵介,梅田純子,近藤勝義
    • Organizer
      日本機械学会2012年度年次大会
    • Place of Presentation
      金沢大学(石川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] Surface Potential Controlled by Al Additive at Interface between Mg Matrix and CNTs

    • Author(s)
      Keisuke Funatsu, Hiroyuki Fukuda, Rei Takei, Junko Umeda, Katsuyoshi Kondoh
    • Organizer
      The Fourth International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials
    • Place of Presentation
      ホテル日航倉敷(岡山県)
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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