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High Efficiency Electrodeposition of Manganese Using Ionic Liquids

Research Project

Project/Area Number 24656458
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Metal making engineering
Research InstitutionKyoto University

Principal Investigator

MURASE Kuniaki  京都大学, 大学院・工学研究科, 教授 (30283633)

Co-Investigator(Kenkyū-buntansha) KITADA Atsushi  京都大学, 大学院・工学研究科, 助教 (30636254)
Research Collaborator SUZUKI Ryohei  京都大学, 大学院・工学研究科, 修士課程学生
SUGIMURA Hiroyuki  京都大学, 大学院・工学研究科, 教授 (10293656)
ICHII Takashi  京都大学, 大学院・工学研究科, 助教 (30447908)
Project Period (FY) 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Keywords電析 / マンガン / イオン液体 / 常温溶融塩 / 室温溶融塩
Research Abstract

Electrodeposition of manganese was tried using ionic liquids as solventshaving relatively wide electrochemical windows compared to water. A conventional ionic liquid, 1-ethyl-3-methylimidazolium chloride, however, had the window ranging from 0 to 2 V vs. Mn, that was insufficient for Mn deposition. In contrast, 1-butyl-2,3-dimethylimidazoliumum chloride (1), in which the 2-position of imidazolium cation was substituted, or masked, by methyl group, made possible a reversible deposition/dissolution of Mn on a cyclic voltammerty. Potentiostatic electrolysis using ionic liquid 1 gave a gray amorphous deposit containing manganese. The deposition current efficiency was, however, lower than that reported for aqueous systems.

Report

(2 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • Research Products

    (6 results)

All 2013 2012 Other

All Journal Article (2 results) Presentation (3 results) (of which Invited: 1 results) Remarks (1 results)

  • [Journal Article] イオン液体の基礎(第2回)~イオン液体とは?その構造と歩み~2013

    • Author(s)
      邑瀬邦明
    • Journal Title

      めっき技術

      Volume: Vol.26, No.4 Pages: 49-58

    • Related Report
      2012 Final Research Report
  • [Journal Article] イオン液体の基礎(第1回)~イオン液体とは? その構造と歩み~2013

    • Author(s)
      邑瀬邦明
    • Journal Title

      めっき技術

      Volume: Vol.26, No.3 Pages: 45-54

    • Related Report
      2012 Final Research Report
  • [Presentation] イオン液体における参照電極~金属電極を実例に~、非水溶液の電気化学の基礎~データの実例とその考え方~2012

    • Author(s)
      邑瀬邦明
    • Organizer
      第42回電気化学講習会
    • Place of Presentation
      大阪商工会議所
    • Year and Date
      2012-11-21
    • Related Report
      2012 Final Research Report
  • [Presentation] 水溶液系およびイオン液体系における電析プロセスの熱力学的設計2012

    • Author(s)
      邑瀬邦明
    • Organizer
      電気化学会ナノ・マイクロファブリケーション研究会/表面技術協会エレクトロニクス部会 講演会
    • Place of Presentation
      豊橋技術科学大学 豊橋駅前サテライトオフィス
    • Year and Date
      2012-11-19
    • Related Report
      2012 Final Research Report
  • [Presentation] 水溶液系およびイオン液体系における電析プロセスの熱力学的設計2012

    • Author(s)
      邑瀬邦明
    • Organizer
      電気化学会ナノ・マイクロファブリケーション研究会/表面技術協会エレクトロニクス部会 講演会
    • Place of Presentation
      豊橋技術科学大学 豊橋駅前サテライトオフィス
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Remarks] Web site

    • URL

      http://www.mtl.kyoto-u.ac.jp/groups/murase-g/

    • Related Report
      2012 Final Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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