Project/Area Number |
24656464
|
Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
Allocation Type | Single-year Grants |
Research Field |
Properties in chemical engineering process/Transfer operation/Unit operation
|
Research Institution | Tokyo University of Agriculture and Technology |
Principal Investigator |
KAMIYA Hidehiro 東京農工大学, 工学(系)研究科(研究院), 教授 (20183783)
|
Co-Investigator(Kenkyū-buntansha) |
IIJIMA Motoyuki 横浜国立大学, 大学院環境情報研究院, 講師 (70513745)
OGINO Kenji 東京農工大学, 大学院工学研究院, 教授 (10251589)
|
Project Period (FY) |
2012-04-01 – 2014-03-31
|
Project Status |
Completed (Fiscal Year 2013)
|
Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
|
Keywords | ミクロ相分離 / ナノ複合体 / 表面修飾 / ナノ粒子 / 界面設計 / 表面設計 / 導電性ポリマー / ナノファイバー |
Research Abstract |
In order to prepare inorganic functional nanoparticle structure formation in block co-polymer, the effect of surface modification on the packing structure of nanoparticles in polymer was investigated. Block co-polymer, PEO-b-PS were used for matrix and 3 kinds of silica nanoparticles with different surface modification were mixed into PEO-b-PS. After the observation micro phase segregation of prepared block co-polymer by using nuclear magnetic resonance, NMR and other methods, surface modified silica nanoparticles were mixed into polymer and prepared polymer composite. The dispersion and array of nanoparticles in polymer composite depended on the modified silica surface molecular structure.
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