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Control of nanoparticle packing structure in polymer by using psedo-liquid polymerizable nanopaticulate preparation and its phase segregation behavior

Research Project

Project/Area Number 24656464
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

KAMIYA Hidehiro  東京農工大学, 工学(系)研究科(研究院), 教授 (20183783)

Co-Investigator(Kenkyū-buntansha) IIJIMA Motoyuki  横浜国立大学, 大学院環境情報研究院, 講師 (70513745)
OGINO Kenji  東京農工大学, 大学院工学研究院, 教授 (10251589)
Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsミクロ相分離 / ナノ複合体 / 表面修飾 / ナノ粒子 / 界面設計 / 表面設計 / 導電性ポリマー / ナノファイバー
Research Abstract

In order to prepare inorganic functional nanoparticle structure formation in block co-polymer, the effect of surface modification on the packing structure of nanoparticles in polymer was investigated. Block co-polymer, PEO-b-PS were used for matrix and 3 kinds of silica nanoparticles with different surface modification were mixed into PEO-b-PS. After the observation micro phase segregation of prepared block co-polymer by using nuclear magnetic resonance, NMR and other methods, surface modified silica nanoparticles were mixed into polymer and prepared polymer composite. The dispersion and array of nanoparticles in polymer composite depended on the modified silica surface molecular structure.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (16 results)

All 2014 2013 2012 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (10 results) (of which Invited: 4 results) Book (1 results) Remarks (2 results)

  • [Journal Article] Fabrication of composite particles by attaching surface-modified nanoparticles to core particles by wet processing in organic solvents2014

    • Author(s)
      Motoyuki Iijima, Kazuki Oguma, Aki Kurumiya, Hidehiro Kamiya
    • Journal Title

      Colloids and Surfaces A

      Volume: 452 Pages: 51-58

    • DOI

      10.1016/j.colsurfa.2014.03.101

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Free-standing, roll-able, and transparent silicone polymer film prepared by using nanoparticles as cross-linking agents2013

    • Author(s)
      Motoyuki Iijima, Sayaka Omori, Keisuke Hirano, Hidehiro Kamiya
    • Journal Title

      Adv. Powder Technol.

      Volume: Vol24(3) Issue: 3 Pages: 625-631

    • DOI

      10.1016/j.apt.2012.11.011

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Analysis of dispersion and aggregation behavior of carbon black particles in aqueous suspension by colloid probe AFM method2013

    • Author(s)
      Yoko Hanada, Shoichi Masuda, Motoyuki Iijima, Hidehiro Kamiya
    • Journal Title

      Adv. Powder Technol.

      Volume: Vol 24(5) Issue: 5 Pages: 844-851

    • DOI

      10.1016/j.apt.2013.02.010

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 機能性分子を修飾したSiO2ナノ粒子の有機ナノファイバーを介した配列化プロセス2014

    • Author(s)
      木村窓香・神谷秀博・飯島志行
    • Organizer
      日本セラミックス協会2014年会
    • Place of Presentation
      慶応大学、東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] 異なる凝集状態の高濃度微粒子サスペンション挙動の解析2014

    • Author(s)
      桑原奈緒子・神谷秀博、飯島志行
    • Organizer
      日本セラミックス協会2014年会
    • Place of Presentation
      慶応大学、東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] Nanoparticle and nanomaterial dispersion behaviour control forapplication in polymer composites and Li-ion batteries2013

    • Author(s)
      H. Kamiya
    • Organizer
      PARTEC 2013
    • Place of Presentation
      Nurunberg, Germany (Plenary)
    • Year and Date
      2013-04-25
    • Related Report
      2013 Final Research Report
  • [Presentation] Transparent Silicone Polymer Composite Films with Silica and Functional Nanoparticles2013

    • Author(s)
      M. Iijima, S. Omori, M. Kimura, K. Hirano, H. Kamiya
    • Organizer
      10th Pacific Rim Conference on Ceramic and Glass Technology
    • Place of Presentation
      San Diego, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] コロイドプローブAFM 法を用いた有機溶媒中での微粒子複合過程における表面間相互作用の評価2013

    • Author(s)
      小熊一樹、久留宮晶、飯島志行、神谷秀博
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学、長野
    • Related Report
      2013 Annual Research Report
  • [Presentation] 湿式プロセスによる機能性微粒子の表面改質と液中分散制御2013

    • Author(s)
      飯島志行、神谷秀博
    • Organizer
      第48回技術討論会ならびに展示会(粉体工学会/日本粉体工業技術協会)
    • Place of Presentation
      東京大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Nanoparticle surface design for controlling their dispersion stability and processing functional composite materials2013

    • Author(s)
      M. Iijima, H. Kamiya
    • Organizer
      The American Ceramic Society, 37th International Conference and Expo on Advanced Ceramics and Composites
    • Place of Presentation
      Hilton Hotel Daytona Beach resort, FL, USA
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Nanoparticle Aggregation and Dispersion Behavior Control for Material Processing2012

    • Author(s)
      H. Kamiya
    • Organizer
      ModTech2012
    • Place of Presentation
      Rumania
    • Year and Date
      2012-05-24
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] ITO微粒子を分散したシリコーンポリマーシートの調製と機能評価2012

    • Author(s)
      木村窓香,飯島志行,神谷秀博,平野敬祐
    • Organizer
      第47様式C-19、F-19、Z-19(共通)回技術討論会(粉体工学会・日本粉体工業技術協会)
    • Place of Presentation
      東京大学(駒場キャンパス)
    • Related Report
      2013 Final Research Report
  • [Presentation] ITO微粒子を分散したシリコーンポリマーシートの調製と機能評価2012

    • Author(s)
      木村、飯島、神谷、平野
    • Organizer
      第47回粉体工学会・日本粉体工業技術協会技術討論会
    • Place of Presentation
      東京大学生産技術研究所
    • Related Report
      2012 Research-status Report
  • [Book] 分散・塗布・乾燥の基礎と応用2014

    • Author(s)
      山口由岐夫・神谷秀博・辻佳子・淵上修三・山村方人
    • Total Pages
      600
    • Publisher
      株式会社テクノシステム
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~kamihide/index.html

    • Related Report
      2013 Final Research Report
  • [Remarks] 東京農工大学、神谷研究室

    • URL

      http://www.tuat.ac.jp/~kamihide/

    • Related Report
      2013 Annual Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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