| Project/Area Number |
24656477
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Reaction engineering/Process system
|
|---|
| Research Institution | Hokkaido University |
|---|
Principal Investigator |
MASUDA Takao 北海道大学, 工学(系)研究科(研究院), 教授 (20165715)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
TAGO Teruoki 北海道大学, 大学院工学研究院, 准教授 (20304743)
NAKASAKA Yuta 北海道大学, 大学院工学研究院, 助教 (30629548)
|
|---|
| Project Period (FY) |
2012-04-01 – 2014-03-31
|
| Project Status |
Completed (Fiscal Year 2013)
|
| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
|
|---|
| Keywords | 反応工学 / 触媒・化学プロセス / バイオマス / 触媒設計 / 多価アルコール / グリセリン / エチレングリコール / エリスリトール / ギ酸 / 酸化鉄系触媒 / ブタジエン / アリルアルコール / 酸化分解 / 水 / アルカリ |
|---|
| Research Abstract |
Main object of this research is to develop a catalytic reaction process to achieve direct allyl compounds synthesis from liner polyalcohols. Potassium supported iron oxide catalysis containing zirconia or alumina showed higher allyl alcohol yield from glycerol compared to the glycerol conversion over the iron oxide catalyst without potassium. In addition, it was clarified that polyalcohol conversion with formic acid, which is hydrogen donor, over the potassium supported iron oxide catalysis increase allyl compounds yield. Moreover, developed catalyst was effective for allyl alcohol formation from crude glycerol generated as a by-product in biodiesel production process.
|
