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Growth of Compound Semiconductor Single Crystal and Application for Solar Cell

Research Project

Project/Area Number 24656582
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Energy engineering
Research InstitutionUniversity of Miyazaki

Principal Investigator

YOSHINO Kenji  宮崎大学, 工学部, 准教授 (80284826)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords化合物半導体 / 単結晶基板 / 太陽電池 / 太陽電池材料 / CIGS / バルク多結晶 / バルク単結晶
Research Abstract

The purpose of this study is to investigate growth and characterization of a CIGS single crystal to elucidate its basic properties in order to enable higher efficiency photovoltaic panels. Large size CIGS single crystal was successfully grown by THM. No secondary phases are observed from XRD and Raman spectroscopy measurements. The FWHM of the XRC for the (112) oriented CIGS single crystal is 103 arcsec. The results show that good-quality single-phase CZTSe single crystals can be obtained by THM growth. The composition of the CIGS single crystal was homogeneous and the stoichiometric ratio of CIGS was found to be slightly Cu-poor, In-rich, Ga-rich and Se-poor. Therefore, it is assumed that the In on Cu antisite and the Se vacancy are dominant, leading to n-type conduction.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (7 results)

All 2014 2013 2012 Other

All Presentation (4 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Presentation] Solution Growth of CuInGaSe_2 Single Crystal2014

    • Author(s)
      A. Nagaoka, H. Miyake, K. Yoshino
    • Organizer
      MRS spring meeting
    • Place of Presentation
      San Francisco (USA)
    • Related Report
      2013 Final Research Report
  • [Presentation] Solution growth of CuInGaSe2 single crystal2014

    • Author(s)
      Akira Nagaoka, Kenji Yoshino
    • Organizer
      MRS Sprong Meeting
    • Place of Presentation
      SAN FRANCISCO, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Solution Growth of Chalcopyrite Compounnds Single Crystal2013

    • Author(s)
      Nagaoka, H. Miyake, K. Yoshino
    • Organizer
      Asia-Pacfic Forum on Renewable Energy
    • Place of Presentation
      Jeju (Korea)
    • Related Report
      2013 Final Research Report
  • [Presentation] Solution growth of chalcopyrite compounds single crystal2013

    • Author(s)
      Akira Nagaoka, Hideto Miyake, Kenji Yoshino
    • Organizer
      Asia-Pacific Forum on Renewable Energy 2013
    • Place of Presentation
      JEJU, KOREA
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.cc.miyazaki-u.ac.jp/yoshino/about.html

    • Related Report
      2013 Final Research Report
  • [Patent(Industrial Property Rights)] n型CIGSS合金およびその製造方法並びに太陽電池2012

    • Inventor(s)
      吉野賢二、永岡章
    • Industrial Property Rights Holder
      吉野賢二、永岡章
    • Industrial Property Rights Type
      特許
    • Filing Date
      2012
    • Related Report
      2012 Research-status Report
  • [Patent(Industrial Property Rights)] Na添加CIGSS5元系合金及びその製造方法並びにこの合金を用いた太陽電池の製造方法2012

    • Inventor(s)
      吉野賢二、永岡章
    • Industrial Property Rights Holder
      吉野賢二、永岡章
    • Industrial Property Rights Type
      特許
    • Filing Date
      2012
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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