Single crystal neutron diffraction study of crystalline-state photo-induced phenomena by using high intensity neutron of J-PARC

• Project/Area Number: 24681016
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Partial Multi-year Fund
• Research Field: Quantum beam science
• Research Institution: Japan Atomic Energy Agency (2013-2014); 一般財団法人総合科学研究機構(総合科学研究センター(総合科学研究室)及び東海事業センター(利用研究促進部)) (2012)
• Principal Investigator: OHHARA Takashi 独立行政法人日本原子力研究開発機構, 原子力科学研究部門J-PARCセンター, 研究副主幹 (60391249)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000); Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2013: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000); Fiscal Year 2012: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
• Keywords: 単結晶中性子構造解析 / 光誘起 / 結晶相反応 / J-PARC / SENJU / プロトン移動 / ESIPT / 量子ビーム科学 / 量子ビーム測定手法 / 中性子

Outline of Final Research Achievements

This proposal aims to establish the in situ single crystal neutron structure analysis technique of crystalline-state photo-induced phenomena In order to achieve the purpose, a new closed-cycle cryostat with a light guide and 2-axes goniometer for a single crystal diffractometer SENJU at J-PARC was developed and in situ light exposure neutron diffraction measurement of 2-(2’-hydroxyphenyl)benzimidazol (HPBI), in which a photo-induced intramolecular proton transfer is reported, with a Xe light and 425 nm long-cut filter at 18 K was successfully carried out.

Research Products

• [Journal Article] Current Status of an Extreme Environment Single Crystal Neutron Diffractometer SENJU at J-PARC (2015)
  • Author(s): Takashi OHHARA, Ryoji Kiyanagi, Koji KANEKO, Itaru TAMURA, Akiko NAKAO, Takayasu HANASHIMA, Koji MUNAKATA, Taketo MOYOSHI, Tetsuo KURODA, Kenichi OIKAWA, Takuro KAWASAKI, Yasuhiro YAMAUCHI, Seiko OHIRA-KAWAMURA
  • Journal Title: JPS Conf. Proc. Volume: 印刷中
  • Peer Reviewed / Open Access
• [Journal Article] Current status of a TOF-Laue single crystal neutron diffractometer SENJU (2015)
  • Author(s): T. Ohhara, R. Kiyanagi, A. Nakao, T. Hanashima, K. Munakata, T. Moyoshi, T. Kuroda, K. Kaneko, I. Tamura, K. Oikawa, T. Kawasaki, Y. Yamauchi and S. O. Kawamura
  • Journal Title: ICANS-XXI Proceedings Volume: 印刷中
• [Journal Article] Proton Order−Disorder Phenomena in a Hydrogen-Bonded Rhodium−η5-Semiquinone Complex: A Possible Dielectric Response Mechanism (2015)
  • Author(s): Minoru Mitsumi, Kazunari Ezaki, Yuuki Komatsu, Koshiro Toriumi, Tatsuya Miyatou, Motohiro Mizuno, Nobuaki Azuma, Yuji Miyazaki, Motohiro Nakano, Yasutaka Kitagawa, Takayasu Hanashima, Ryoji Kiyanagi, Takashi Ohhara, and Kazuhiro Nakasuji
  • Journal Title: Chemistry - A European Journal Volume: 印刷中
  • Peer Reviewed
• [Journal Article] Recent Advance of the Neutron Crystal Chemistry by using High Intensity Neutron Beam at J-PARC (2014)
  • Author(s): 大原高志
  • Journal Title: Nihon Kessho Gakkaishi Volume: 56 Issue: 5 Pages: 301-306
  • DOI: 10.5940/jcrsj.56.301
  • NAID: 130004714199
  • ISSN: 0369-4585, 1884-5576
  • Peer Reviewed / Open Access
• [Journal Article] Detector system of the SENJU single-crystal time-of-flight neutron Diffractometer at J-PARC/MLF (2014)
  • Author(s): T. Kawasaki, T. Nakamura, K. Toh, T. Hosoya, K. Oikawa, T. Ohhara, R. Kiyanagi, M. Ebine, A. Birumachi, K. Sakasai, K. Soyama, M. Katagiri
  • Journal Title: Nuclear Instruments and Methods in Physics Research, A. Volume: 735 Pages: 444-451
  • DOI: 10.1016/j.nima.2013.09.057
  • Peer Reviewed
• [Journal Article] Single crystal neutron diffraction study of high neutron absorbing compound EuGa4 (2014)
  • Author(s): T. Kawasaki, K. Kaneko, N. Aso, A. Nakamura, M. Hedo, T. Nakama, and Y. Onuki
  • Journal Title: JPS Conf. Proc. Volume: 1 Pages: 0140091-4
  • DOI: 10.7566/jpscp.1.014009
  • Peer Reviewed / Open Access
• [Journal Article] Instrument Design and Performance Evaluation of a New Single Crystal Neutron Diffractometer SENJU at J-PARC (2014)
  • Author(s): K. Oikawa, T. Kawasaki, T. Ohhara, R. Kiyanagi, K. Kaneko, I. Tamura, T. Nakamura, M. Harada, A. Nakao, T. Hanashima, K. Munakata, H. Kimura, Y. Noda, M. Takahashi, and T. Kiyotani
  • Journal Title: JPS Conf. Proc. Volume: 1 Pages: 0140131-4
  • DOI: 10.7566/jpscp.1.014013
  • Peer Reviewed
• [Journal Article] Evaluation of performance for IBARAKI biological crystal diffractometer iBIX with new detectors (2013)
  • Author(s): K. Kusaka, T. Hosoya, T. Yamada, K. Tomoyori, T. Ohhara, M. Katagiri, K. Kurihara, I. Tanaka, N. Niimura
  • Journal Title: J. Synchrotron Radiat. Volume: 2013 Issue: 6 Pages: 994-998
  • DOI: 10.1107/s0909049513021845
  • Peer Reviewed
• [Journal Article] Hydrogen-bond network and pH sensitivity in human transthyretin (2013)
  • Author(s): T. Yokoyama, M. Mizuguchi, Y. Nabeshima, K. Kusaka, T. Yamada, T. Hosoya, T. Ohhara, K. Kurihara, I. Tanaka, N. Niimura
  • Journal Title: J. Synchrotron Radiat. Volume: 2013 Issue: 6 Pages: 834-837
  • DOI: 10.1107/s090904951302075x
  • Peer Reviewed
• [Journal Article] A Functional [NiFe] Hydrogenase Mimic that Catalyzes Electron and Hydride T ransfer from H_2 (2013)
  • Author(s): Seiji Ogo, Koji Ichikawa, et al.
  • Journal Title: Science Volume: 339 Issue: 6120 Pages: 682-684
  • DOI: 10.1126/science.1231345
  • Peer Reviewed
• [Journal Article] Structure of Morpholinium Tribromoplumbate C_4H_8ONH_2PbBr_3 Studied Using Single-Crystal Neutron Diffraction (2012)
  • Author(s): T. Kawasaki, M. Takahashi, T.Ohhara, I. Tanaka, K. Kusaka, T.Hosoya, T. Yamada, K.Kurihara
  • Journal Title: J. Phys. Soc. Jpn. Volume: 81 Issue: 9 Pages: 94602-94602
  • DOI: 10.1143/jpsj.81.094602
  • Peer Reviewed
• [Presentation] 大強度パルス中性子線による結晶構造解析の基礎理論と最新状況 (2015)
  • Author(s): 大原高志
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学(船橋)
  • Year and Date: 2015-03-26 – 2015-03-29
  • Invited
• [Presentation] 励起状態プロトン移動を示す有機発光材料2-(2’-hydroxyphenyl) benzimidazoleの単結晶中性子構造解析 (2014)
  • Author(s): 大原 高志、鬼柳 亮嗣、花島 隆泰、茂吉 武人、中尾 朗子、宗像 孝司、黒田 哲也
  • Organizer: 日本中性子科学会第14回年会
  • Place of Presentation: 北海道立道民活動センター(札幌)
  • Year and Date: 2014-12-11 – 2014-12-12
• [Presentation] J-PARCの大強度中性子を用いた結晶化学の新展開 (2014)
  • Author(s): 大原高志
  • Organizer: 平成26年度日本結晶学会年会
  • Place of Presentation: 東京大学(東京)
  • Year and Date: 2014-11-01 – 2014-11-03
  • Invited
• [Presentation] Current status of a TOF-Laue single crystal neutron diffractometer SENJU (2014)
  • Author(s): T. Ohhara, R. Kiyanagi, A. Nakao, T. Hanashima, K. Munakata, T. Moyoshi, T. Kuroda, K. Kaneko, I. Tamura, K. Oikawa, T. Kawasaki, Y. Yamauchi and S. O. Kawamura
  • Organizer: ICANS-XXI
  • Place of Presentation: Ibaraki Prefectural Culture Center (Mito, Japan)
  • Year and Date: 2014-09-30 – 2014-10-03
• [Presentation] J-PARCの大強度中性子を利用した単結晶中性子構造解析の最前線 (2014)
  • Author(s): 大原高志
  • Organizer: 分子連関相乗系研究部門研究会「分子機能解明のための結晶学の利用」
  • Place of Presentation: 東京理科大学(東京)
  • Year and Date: 2014-08-30
  • Invited
• [Presentation] SENJU, Extreme Environment Single Crystal Neutron Diffractometer at J-PARC (2014)
  • Author(s): Takashi Ohhara, Ryoji Kiyanagi, Koji Kaneko, Takuro Kawasaki, kenichi Oikawa, Itaru Tamura, Akiko Nakao, Takayasu Hanashima, Koji Munakata, Taketo Moyoshi, Tetsuya Kuroda, Yasuhiro Yamauchi, Seiko Ohira-Kawamura
  • Organizer: Twenty-Third Congress and General Assembly of the International Union of Crystallography
  • Place of Presentation: Palais des congrès de Montréal (Montreal, Canada)
  • Year and Date: 2014-08-05 – 2014-08-12
• [Presentation] Sample environment devices for a TOF-Laue single crystal diffractometer SENJU at J-PARC (2013)
  • Author(s): T. Ohhara, R. Kiyanagi, K. Kaneko, T. Kawasaki, K. Oikawa, I. Tamura, A. Nakao, T. Hanashima, K. Munakata, T. Moyoshi, T. Kuroda, Y. Yamauchi, S. O.-Kawamura
  • Organizer: The 12th Conference of the Asian Crystallographica Association
  • Place of Presentation: HKUST(HongKong)
• [Presentation] 単結晶中性子回折計SENJUの高度化と試料環境の現状 (2013)
  • Author(s): 大原高志、鬼柳亮嗣、及川健一、川崎卓郎、金子耕士、田村格良、中尾朗子、花島隆泰、宗像孝司、茂吉武人、木村宏之、野田幸男、高橋美和子、清谷多美子、山内康弘、河村聖子
  • Organizer: 平成25年度日本結晶学会年会
  • Place of Presentation: 熊本大学(熊本市)
• [Presentation] Development of a new TOF single crystal diffractometer SENJU at J-PARC (2013)
  • Author(s): T. Ohhara, R. Kiyanagi, T. Kawasaki, K. Oikawa, K. Kaneko, I. Tamura, A. Nakao, T. Hanashima, K. Munakata, H. Kimura, C.-H. Lee, Y. Noda, M. Takahashi, T. Kiyotani, K. Oshima, M. Arai
  • Organizer: International Conference on Neutron Scattering
  • Place of Presentation: Edinburgh International Conference Centre (Edinburg , U.K.)
• [Presentation] Current Status of Extreme Environment Single Crystal Neutron Diffrac tometer SENJU at J-PARC (2013)
  • Author(s): T. Ohhara, R. Kiyanagi, 以下
  • Organizer: The 12^<th> Korea-Japan Meeting on Neutron Science
  • Place of Presentation: 琉球大学(沖縄)
• [Presentation] 新規単結晶中性子回折計「SENJU」による有機化合物結晶の構造解析 (2013)
  • Author(s): 大原高志, 中尾朗子, 以下
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 立命館大学(草津)
• [Presentation] 特殊環境微小単結晶中性子回折計SENJUの立ち上げと現状 (2012)
  • Author(s): 大原高志, 鬼柳亮嗣, 以下
  • Organizer: 第4回MLFシンポジウム
  • Place of Presentation: 日本未来館(東京)
• [Presentation] 特殊環境微小単結晶中性子回折計SENJUの立ち上げと現状 (2012)
  • Author(s): 大原高志, 鬼柳亮嗣, 以下
  • Organizer: 平成24年度日本結晶学会年会
  • Place of Presentation: 東北大学(仙台)
• [Presentation] SENJU: A New Extreme Environment Single Crystal Neutron Diffracto meter at BL18 of J-PARC (2012)
  • Author(s): T. Ohhara, R. Kiyanagi, 以下
  • Organizer: A Joint Meeting of the Asian Crystallographic Association (AsCA), Society of Crystallographeres in Australia and New Zealand (SCANZ)
  • Place of Presentation: Adelaide, Australia
• [Book] X線・中性子構造解析の基礎：有機結晶から薄膜まで (2015)
  • Author(s): 大橋裕二、植草秀裕、大原高志、小島優子、根本隆
  • Publisher: 東京化学同人
• [Remarks]
  • URL: http://www.cross-tokai.jp/ja/news/2013/v13001