Stereochemistry of organic solids in solar system primitive materials: Development of thermochemolysis chiral-GCMS
Project/Area Number |
24684040
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Research Category |
Grant-in-Aid for Young Scientists (A)
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Allocation Type | Partial Multi-year Fund |
Research Field |
Geochemistry/Astrochemistry
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Research Institution | Osaka University |
Principal Investigator |
Yabuta Hikaru 大阪大学, 理学(系)研究科(研究院), 助教 (30530844)
|
Project Period (FY) |
2012-04-01 – 2016-03-31
|
Project Status |
Completed (Fiscal Year 2015)
|
Budget Amount *help |
¥25,480,000 (Direct Cost: ¥19,600,000、Indirect Cost: ¥5,880,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
|
Keywords | 光学分割 / 隕石 / 固体有機物 / 反応熱分解GCMS / 宇宙塵 |
Outline of Final Research Achievements |
In this study, we attempted a new method to determine the molecular structures and enantiomeric excesses (ee) of enentiomers in organic macromolecular solids in meteorites, in order to understand the diversity and universality in homochirality emergence and amplification mechanisms in the early Solar System. Insoluble organic matter (IOM) isolated from Murchison meteorite powder was chemically degraded by alkaline CuO degradation, and the degradation products were analyzed by a gas chromatograph-mass spectrometry (GCMS). As a result, 7 kinds of dicarboxylic acids and 7 kinds of hydroxy acids, which have enantiomers, were identified. This result indicates that extraterrestrial homochirality could have existed not only in meteoritic amino acids but also in organic macromolecular solids. Further experiment to estimate ee values for the individual molecules will be necessary.
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Report
(5 results)
Research Products
(77 results)
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[Journal Article] A Strategy for Origins of Life Research2015
Author(s)
Scharf C., Virgo N., Cleaves H. J., Aono M., Aubert-Kato N., Barge L. M., Benner S. A., Cronin L., Danielache S., Fischer J., Hernlund J., Hut P., Ikegami T., Kimura J., McGlynn S., Pascal R., Pereto J., Smith E., Takai K., Tian F., Ueno Y., Voytek M., Witkowski O., Yabuta H. and others
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Journal Title
Astrobiology
Volume: 15
Pages: 1031-1042
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research
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[Journal Article] Mineralogy and noble-gas isotopes of micrometeorites collected from Antarctic snow2015
Author(s)
Okazaki, R., Noguchi, T., Tsujimoto, S., Tobimatsu, Y., Nakamura, T., Ebihara, M., Itoh, S., Nagahara, H., Tachibana, S., Terada, K. and Yabuta, H.
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Journal Title
Earth, Planets and Space
Volume: 67
Pages: 90
DOI
Related Report
Peer Reviewed / Open Access
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[Journal Article] ToF-SIMS analysis of carbonaceous particles in the sample catcher of the Hayabusa spacecraft2015
Author(s)
Naraoka, H., Aoki, D., Fukushima, K., Uesugi, M., Ito, M., Kitajima, F., Mita, H., Yabuta, H., Takano, Y., Yada, T., Ishibashi, Y., Karouji, Y., Okada, T. and Abe, M.
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Journal Title
Earth, Planets and Space
Volume: 67
Pages: 67
DOI
Related Report
Peer Reviewed / Open Access / Acknowledgement Compliant
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[Journal Article] A micro-Raman and infrared study of the several Hayabusa category 3 (organic) particles2015
Author(s)
Kitajima, F., Uesugi, M., Karouji, Y., Ishibashi, Y., Yada, T., Naraoka, H., Abe, M., Fujimura, A., Ito, M., Yabuta, H., Mita, H., Takano, Y. and Okada, T.
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Journal Title
Earth, Planets and Space
Volume: 67
Pages: 20
DOI
Related Report
Open Access / Acknowledgement Compliant
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[Journal Article] X-ray absorption near edge structure spectroscopic study of Hayabusa Category 3 carbonaceous particles2014
Author(s)
Yabuta, H., Uesugi, M., Naraoka, H., Ito, M., Kilcoyne, A. L. D., Sandford, S. A., Kitajima, F., Mita, H., Takano, Y., Yada, T., Karouji, Y., Ishibashi, Y., Okada, T. and Abe, M.
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Journal Title
Earth, Planets and Space
Volume: 66
Pages: 156
DOI
Related Report
Open Access / Acknowledgement Compliant
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[Journal Article] Sequential analysis of carbonaceous materials in Hayabusa-returned samples for the determination of their origin2014
Author(s)
Uesugi, M., Naraoka, H., Ito, M., Yabuta, H., Kitajima, F., Takano, Y., Mita, H., Ohnishi, I., Kebukawa, Y., Yada, T., Karouji, Y., Ishibashi, Y., Okada, T. and Abe, M.
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Journal Title
Earth, Planets and Space
Volume: 66
Pages: 102
DOI
Related Report
Open Access / Acknowledgement Compliant
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[Journal Article] Design of a silica-aerogel-based cosmic dust collector for the Tanpopo mission aboard the International Space Station. Transactions of the Japan Society for Aeronautical and Space Sciences, Aerospace Technology Japan.2014
Author(s)
Tabata, M., Imai, E., Yano, H., Hashimoto, H., Kawai, H., Kawaguchi, Y., Kobayashi, K., Mita, H.,, Okudaira, K., Sasaki S., Yabuta, H., Yokobori, S., Yamagishi, A.
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Journal Title
Transactions of the Japan Society for Aeronautical and Space Sciences, Aerospace Technology Japan
Volume: 12
Pages: Pk_21-Pl_27
DOI
Related Report
Acknowledgement Compliant
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[Journal Article] Space Exposure of Amino Acids and Their Precursors in the Tanpopo Mission Using the International Space Station.2014
Author(s)
Kobayashi, K., Mita, H., Yabuta, H., Nakagawa, K., Kawamoto, T., Kaneko, T., Obayashi, Y., Kanda, K., Yoshida, S., Narumi, I., Imai, E., Hashimoto, H., Yokobori, S., Yamagishi, A. and Tanpopo WG.
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Journal Title
Transactions of the Japan Society for Aeronautical and Space Sciences, Aerospace Technology Japan
Volume: 12
Pages: Pp_1-Pp_6
DOI
Related Report
Acknowledgement Compliant
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[Journal Article] Exploration of Enceladus' water-rich plumes toward understanding of chemistry and biology of the interior ocean2014
Author(s)
Sekine, Y., Takano, Y., Yano, H., Funase, R., Takai, K., Ishihara, M., Shibuya, T., Tachibana, S., Kuramoto, K., Yabuta, H., Kimura, J. and Furukawa, Y.
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Journal Title
Transactions of the Japan Society for Aeronautical and Space Sciences, Aerospace Technology Japan
Volume: 12
Pages: Tk7- Tk11
DOI
Related Report
Acknowledgement Compliant
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[Presentation] High power laser-shock experiment of chondritic meteorites: Contributions of hydrocarbons and sulfur-bearing compounds to the early Earth atmosphere2015
Author(s)
H. Yabuta, T. Sakaiya, T. Kondo, S. Ohno, K. Kurosawa, T. Kadono, K. Shigemori, Y. Hironaka, T. Yamanaka
Organizer
The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem 2015)
Place of Presentation
Honolulu, Hawaii, USA
Year and Date
2015-12-15 – 2015-12-20
Related Report
Int'l Joint Research
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[Presentation] Variations in Organic Functional Groups between Hydrous and Anhydrous Antarctic Micrometeorites2015
Author(s)
H. Yabuta, T. Noguchi, S. Itoh, T. Nakamura, T. Mitsunari, A. Okubo, R. Okazaki, S. Tachibana, K. Terada, M. Ebihara and H. Nagahara
Organizer
Meteoritical Society Meeting 2015
Place of Presentation
Berkeley, California, USA
Year and Date
2015-07-27 – 2015-07-31
Related Report
Int'l Joint Research
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[Presentation] Capture of Cosmic Dusts on the International Space Station by the Japanese Astrobiology Mission (TANPOPO)2015
Author(s)
H. Yabuta, K. Okudaira, M. Tabata, H. Mita, K. Kobayashi, H. Yano, H. Hashimoto, S. Yokobori, E. Imai, H. Kawai, Y. Kawaguchi, K. Hamase, Y. Kebukawa, A. Yamagishi, and others
Organizer
Astrobiology Science Conference 2015
Place of Presentation
Chicago, USA
Year and Date
2015-06-15 – 2015-06-19
Related Report
Int'l Joint Research
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[Presentation] X-ray absorption spectroscopic study of carbonaceous materials from Hayabusa-returned samples2014
Author(s)
Yabuta H., Uesugi M., Naraoka H., Ito M., Kilcoyne D., Sandford S. A., Kitajima F., Mita H., Takano Y., Yada T., Karouji Y., Ishibashi Y., Okada T. and Abe M.
Organizer
はやぶさシンポジウム
Place of Presentation
宇宙科学研究所、相模原
Year and Date
2014-12-04 – 2014-12-05
Related Report
Int'l Joint Research
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[Presentation] Source of Carbonaceous Materials from Hayabusa-Returned Samples: Evaluation from XANES study.2014
Author(s)
Yabuta H., Uesugi M., Naraoka H., Ito M., Kilcoyne D., Sandford S. A., Kitajima F., Mita H., Takano Y., Yada T., Karouji Y., Ishibashi Y., Okada T. and Abe M.
Organizer
第5回極域科学シンポジウム
Place of Presentation
極地研究所,調布
Year and Date
2014-12-02 – 2014-12-03
Related Report
Int'l Joint Research
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[Presentation] Functional group compositions of carbonaceous materials of HAYABUSA-returned samples.2014
Author(s)
Yabuta H., Uesugi M., Naraoka H., Ito M., Kilcoyne A.L.D., Sandford S.A., Kitajima F., Mita H., Takano Y., Yada T., Karouji Y., Ishibashi Y., Okada T. and Abe M.
Organizer
77th Annual Meeting of the Meteoritic Society
Place of Presentation
カサブランカ、モロッコ
Year and Date
2014-09-07 – 2014-09-12
Related Report
Int'l Joint Research
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[Presentation] Relationship of organics, minerals, and water in ice-rock small body recorded in an ultracarbonaceous Antarctic micrometeorite.2014
Author(s)
Yabuta H., Noguchi T., Itoh S., Nakamura T., Tsujimoto S., Sakamoto N., Hashiguchi M., Abe K., Kilcoyne A. L. D., Okubo A., Tachibana S., Okazaki R., Terada K., Ebihara M. and Nagahara H.
Organizer
Origins 2014
Place of Presentation
奈良新公会堂, 奈良
Year and Date
2014-07-06 – 2014-07-11
Related Report
Int'l Joint Research
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[Presentation] Hypervelocity Capture of Murchison Meteorite Particles in Aerogel:Ground-based experiment for the Cosmic Dusts Capture at the International Space Station2013
Author(s)
Ogata Y., Yabuta H., Nakashima S., Okudaira K., Moriwaki T.,Ikemoto Y., Hasegawa S., Tabata M.,Yokobori S., Mita H., Kobayashi K.,Imai E., Hashimoto H., Kawaguchi Y.,Sugino T., Yano H., Yamagishi A. and Tanpopo WG
Organizer
29th International Symposium on Space Technology and Science
Place of Presentation
名古屋
Year and Date
20130602-20130609
Related Report
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[Presentation] Evidence of minimum aqueous alteration of rock-ice body: Update of organic chemistly and mineralogy of Antarctic ultracarbonaceous microme teorite.2013
Author(s)
Yabuta, H., Noguchi, T., Itoh, S., Tsujimoto. S., Sakamoto, N., Hashiguchi, M., Abe、K., Kilcoyne, A. L. D., Okubo. A., Okazaki, R.、Tachibana. S., Terada, K., Nakamura, T., Ebihara, M. and Nagahara, H.
Organizer
44th Lunar and Planetary Science Conference
Place of Presentation
ヒューストン、アメリカ合衆国
Year and Date
2013-03-20
Related Report
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[Presentation] Coexisting nitlrogen-ricb and poor organic Materials in ultracarbonaceous Antarctic micrometeorite2012
Author(s)
Yabuta, H., Itoh, S., Noguchi, T., Sakamoto, N., Hashiguchi, M., Abe, K., Tsujimoto, S., Kilcoyne, A. L .D., Okubo, A., Okazaki, R., Tachibana, S., Terada, K., Nakamura, T. and Nagahara, H
Organizer
The 75th Meteoritical Society Meeting
Place of Presentation
ケアンズ、オーストラリア
Year and Date
2012-08-14
Related Report
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[Presentation] Finding of Nitrogen-rich Organic Material in Antarctic Ultracarbonaceous Micrometeorite2012
Author(s)
Yabuta, H., Itoh、S., Noguchi, T., Sakamoto, N.. Hashiguchi, M., Abe, K, Tsujimoto, S., Kilcoyne, A. L. D., Okubo. A., Okazaki, R., Tachibana、 S., Terada, K., Nakamura, T. and Nagahara, H
Organizer
日本地球惑星科学連合2012年度連合大会
Place of Presentation
幕張メッセ(千葉県)
Year and Date
2012-05-20
Related Report
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[Presentation] Organic analysis of terminal particles obtained from aerogel captuire experiment of Murehison meteoirite at 4 km/s2012
Author(s)
Ogata. Y., Yabuta, H., Nakashima, S., Okudaira. K., Moriwaki, T., Ikemoto、 Y,. Hasegawa, S., Tabala, M., Yokobori, S., Mita, H., Kobayashi、K., Imai, E., Hashimoto. H., Kawaguchi, Y., Sugino. T., Yano、H,、Yamashita, M. Yamagishi, A. and TANPOPO Working group
Organizer
Asteroids, Comels, Meteors(ACM)
Place of Presentation
朱鷺メッセ(新潟県)
Year and Date
2012-05-16
Related Report
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[Presentation] High power laser-shock experiment of carbonaceous chondrite at 400 G Pa: Contribution of impacts to early Earth atmospheric chemistry2012
Author(s)
Yabuta, H., Sakaiya, T., Kondo, T., Ohno, S., Nakabayashi, M., Kadono, T., Shigemori, K., Hiroonaka, Y. and Yamanaka, T.
Organizer
Astrobiology Science Conference (AbScicon)
Place of Presentation
アトランタ、アメリカ合衆国
Year and Date
2012-04-17
Related Report
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[Presentation] High power laser-shock experiment of chondrites: Contribution of impacts to the early Earth atmosphere
Author(s)
Yabuta, H., Sakaiya, T., Kondo, T., Ohno, S., Nakabayashi, M., Kadono, T., Shigemori, K., Hironaka, K., Yamanaka , T.
Organizer
45th Lunar and Planetary Science Conference
Place of Presentation
The Woodlands, Texas, USA
Related Report
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[Presentation] Organic Nitrogen Cosmochemistry of Ultracarbonaceous Micrometeorite
Author(s)
Yabuta H., Noguchi T., Itoh S., Tsujimoto S., Sakamoto N., Hashiguchi M., Abe K., Kilcoyne D., Okubo A., Okazaki R., Tachibana S., Terada K., Nakamura T., Ebihara M. and Nagahara H.
Organizer
Goldschmidt 2013
Place of Presentation
Florence, Italy
Related Report
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