| Budget Amount *help |
¥24,960,000 (Direct Cost: ¥19,200,000、Indirect Cost: ¥5,760,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2013: ¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Fiscal Year 2012: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
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| Outline of Final Research Achievements |
A cooperation of dynamic imine-bon formations and cooperativity of allosteric bindings has been incorporated into various supramolecular motifs and studied to create "dynamic molecular system" with dynamic motion and dynamic equilibrium in this project: The following outstanding results has found: A) Preservation effect of DPs in cooperative supramolecular copolymerization based on allosteric bindings, B) Cooperative hydrogen-bonding in the hydrindacene-geared molecules, C) Opposite thermodynamic selectivity among two formyl-stations in the imine-bridged rotaxane under the hydrolytic conditions and D) Shape-memory effect and template effect by incorporating atropisomerism to imine-based macrocyclic receptors.
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