Synthesis and Reactivity of Metallocenoid Clusters Using Late-Transition Metals
| Project/Area Number |
24685016
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Partial Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Tokyo Institute of Technology (2015)
Institute for Molecular Science (2012-2014) |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥24,180,000 (Direct Cost: ¥18,600,000、Indirect Cost: ¥5,580,000)
Fiscal Year 2014: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2013: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Fiscal Year 2012: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
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| Keywords | 金属クラスター / 有機金属錯体 / サンドイッチ化合物 / クラスター / 触媒 / 反応性 / 金属錯体 / 後周期遷移金属 |
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| Outline of Final Research Achievements |
The elaborate design of the molecular structures of late transition-metal catalysts may give desired catalytic functions. In this project, we focused on the development of the structural principle of "metallocenoid" structures for late-transition metal catalysts. We found that tri- or tetranuclear metallocenoid clusters are obtained by using unsaturated carbocycle binders such as benzene, cyclooctatetraene, or naphthalene. Furthermore, we also revealed the formation of half-sandwich type trinuclear sandwich structures from the metallocenoid clusters.
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Report
(4 results)
Research Products
(15 results)
