| Budget Amount *help |
¥24,180,000 (Direct Cost: ¥18,600,000、Indirect Cost: ¥5,580,000)
Fiscal Year 2014: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2013: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Fiscal Year 2012: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
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| Outline of Final Research Achievements |
The elaborate design of the molecular structures of late transition-metal catalysts may give desired catalytic functions. In this project, we focused on the development of the structural principle of "metallocenoid" structures for late-transition metal catalysts. We found that tri- or tetranuclear metallocenoid clusters are obtained by using unsaturated carbocycle binders such as benzene, cyclooctatetraene, or naphthalene. Furthermore, we also revealed the formation of half-sandwich type trinuclear sandwich structures from the metallocenoid clusters.
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