Self-assembly of dinuclear metal complexes via diblock copolypeptide amphiphiles
| Project/Area Number |
24685019
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Partial Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Sojo University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥22,230,000 (Direct Cost: ¥17,100,000、Indirect Cost: ¥5,130,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Fiscal Year 2012: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
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| Keywords | 自己組織化 / 金属錯体 / ポリペプチド / 脂質 / 混合原子価錯体 / ナノ構造 / 両親媒性 / 両親媒性ジブロックコポリペプチド / 機能性金属錯体 / 超分子錯体 / 高分子錯体 / 膜・集合体 / 超分子 / 発光 |
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| Outline of Final Research Achievements |
Supramolecular self-assemblies have been attracting much interest due to construction of novel nanomaterials of functional coordination compounds. In this study, I focus on the self-assembly of discrete metal complexes with supramolecular amphiphiles such as lipids and block copolypeptides.
Discrete metal complexes with supramolecular amphiphiles displayed self-assembly in solution. Formation of a bilayer structure caused morphological evolution from microtapes to nanoarchitecture (tubes, ellipse, and so on). Furthermore, the study leads not only to morphological transformation of self-assembled structures, but also to the intermolecular interaction such as hypochromic effect and luminescence. The concept of amphiphile packaging could be expanded of other useful coordination compounds and should allow us to further develop the nanochemistry of coordination materials.
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Report
(4 results)
Research Products
(43 results)
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[Journal Article] Electrical Conductivity and Ferromagnetism in a Reduced Graphene--Metal Oxide Hybrid2013
Author(s)
Mohammad Razaul Karim, Hideaki Shinoda, Mina Nakai, Kazuto Hatakeyama, Hidenobu Kamihata, Takeshi Matsui, Takaaki Taniguchi, Michio Koinuma, Keita Kuroiwa, Mohamedally Kurmoo, Yasumichi Matsumoto, Shinya Hayami
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Journal Title
Adv. Func. Mater.
Volume: 23
Issue: 3
Pages: 323-332
DOI
Related Report
Peer Reviewed
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