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Materials Science of Metal Complex Arrays

Research Project

Project/Area Number 24685020
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Polymer chemistry
Research InstitutionNational Institute for Materials Science

Principal Investigator

TASHIRO Kentaro  独立行政法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA研究者 (40332598)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥27,040,000 (Direct Cost: ¥20,800,000、Indirect Cost: ¥6,240,000)
Fiscal Year 2013: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2012: ¥23,010,000 (Direct Cost: ¥17,700,000、Indirect Cost: ¥5,310,000)
Keywords生体関連高分子 / 多核金属錯体 / タンパク質 / 二次構造 / シークエンス
Research Abstract

We investigated the subjects related with the construction of 3D structures of metal complex arrays mainly from protein structural science point of view, where the targets were to gain deeper insights on their secondary structures and to develop the methods to make multiple secondary structures couple. Through the researches we found that a heteremetallic sequence can stabilize a helical conformation of the metal complex arrays compared with the corresponding homometallic sequences. Moreover, we also successfully established a new synthetic approach for the construction of sequence-controlled metal complex arrays that have molecular weights comparable to small proteins.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • Research Products

    (13 results)

All 2013 2012 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (5 results) Book (2 results) Remarks (2 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Isomers of Metal-Organic Complex Arrays2012

    • Author(s)
      A. M. Fracaroli, K. Tashiro, O. M. Yaghi
    • Journal Title

      Inorg. Chem.

      Volume: 51

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Isomers of Metal-Organic Complex Arrays2012

    • Author(s)
      A. M. Fracaroli, K. Tashiro, O.M. Yaghi
    • Journal Title

      Inorganic Chemistry

      Volume: 51 Issue: 12 Pages: 6437-6439

    • DOI

      10.1021/ic300744x

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] 金属錯体アレイの高次構造2013

    • Author(s)
      田代健太郎
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学、東京
    • Year and Date
      2013-09-06
    • Related Report
      2013 Final Research Report
  • [Presentation] Secondary Structures of Metal–Organic Complex Arrays2013

    • Author(s)
      P. Lakshminarayanan, A. Fracaroli, O. Yaghi, K. Tashiro
    • Organizer
      2013 NIMS Conference
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      2013-07-02
    • Related Report
      2013 Final Research Report
  • [Presentation] Networking of Metal Complexes2013

    • Author(s)
      K. Tashiro
    • Organizer
      Second International Workshop on Advanced Functional Nanomaterials
    • Place of Presentation
      Chennai, India
    • Year and Date
      2013-01-29
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] Networking of Metal Complexes2012

    • Author(s)
      K. Tashiro
    • Organizer
      International Conference on Emerging Advanced Nanomaterials
    • Place of Presentation
      Brisbane, Australia
    • Year and Date
      2012-10-24
    • Related Report
      2013 Final Research Report 2012 Annual Research Report
  • [Presentation] 金属錯体アレイの高次構造

    • Author(s)
      田代健太郎
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      学習院大学
    • Related Report
      2013 Annual Research Report
  • [Book] π電子化合物のシークエンス制御(高次π空間の創発と機能開発)2013

    • Author(s)
      田代健太郎
    • Related Report
      2013 Final Research Report
  • [Book] 高次π空間の創発と機能開発2013

    • Author(s)
      田代健太郎
    • Publisher
      シーエムシー出版
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.nims.go.jp/reticular/Japanese.html

    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://www.nims.go.jp/reticular/

    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 自己組織化ペプチド2013

    • Inventor(s)
      山本洋平、中山徹、田代健太郎
    • Industrial Property Rights Holder
      筑波大学、物質・材料研究機構
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-05-27
    • Related Report
      2013 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 自己組織化ペプチド2013

    • Inventor(s)
      山本洋平、中山徹、田代 健太郎
    • Industrial Property Rights Holder
      筑波大学、物質・材料研究機構
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-05-27
    • Related Report
      2013 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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