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Controlled fabrication of anode microstructures in solid oxide fuel cells

Research Project

Project/Area Number 24686019
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Production engineering/Processing studies
Research InstitutionThe University of Tokyo

Principal Investigator

NAGATO Keisuke  東京大学, 工学(系)研究科(研究院), 講師 (50546231)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥26,910,000 (Direct Cost: ¥20,700,000、Indirect Cost: ¥6,210,000)
Fiscal Year 2013: ¥11,310,000 (Direct Cost: ¥8,700,000、Indirect Cost: ¥2,610,000)
Fiscal Year 2012: ¥15,600,000 (Direct Cost: ¥12,000,000、Indirect Cost: ¥3,600,000)
Keywordsナノ・マイクロ加工 / 固体酸化物 / 燃料電池 / 燃料極 / 微細構造 / 配列
Research Abstract

Conventional microstructures in anode of solid-oxide fuel cells has not been necessarily optimized in a view point of the transfer of matters or chemical reactions at their boundaries because the paths are located randomly. In this study, we aimed for alignment of YSZ, Ni and pore along the thickness direction, in which the oxygen ions, electrons and gases are effectively transferred respectively. Ni particles were aligned by magnetic field and the maximum power improved to 1.6 times as the conventional cell. The reconstruction of the microstructure with FIB-SEM and electrochemical reaction calculation indicated that the tortuosity was improved to about 3 from 7. Furthermore, Al film was deposited on a Zr substrate and alumina through nanoholes were formed by anodic oxidation, and then the zirconia pillars were successfully synthesized by reanodization using the nanoholes as a mold.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • Research Products

    (18 results)

All 2014 2013 2012 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (12 results) Remarks (1 results)

  • [Journal Article] Fabrication of highly ordered Ta_2O_5 and Ta_3N_5 nanorod arrays by nanoimprinting and through-mask anodization2014

    • Author(s)
      Y. Li, K. Nagato, J.-J. Delaunay, J. Kubota, and K. Domen
    • Journal Title

      Nanotechnology

      Volume: Vol.25

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of highly ordered Ta2O5 and Ta3N5 nanorod arrays by nanoimprinting and through-mask anodization2014

    • Author(s)
      Y. Li, K. Nagato, J.-J. Delaunay, J. Kubota, and K. Domen
    • Journal Title

      Nanotechnology

      Volume: 25

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] SOFC Anode Fabricated by Magnetically Aligning of Ni Particles2013

    • Author(s)
      Keisuke Nagato, Naoki Shikazono, André Weber, Dino Klotz, Masayuki Nakao, and Ellen Ivers-Tiffée
    • Journal Title

      ECS Transasctions

      Volume: Vol.57 Pages: 1307-1311

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] SOFC Anode Fabricated by Magnetically Aligning of Ni Particles2013

    • Author(s)
      Keisuke Nagato, Naoki Shikazono, Andre Weber, Dino Klotz, Masayuki Nakao, and Ellen Ivers-Tiffee
    • Journal Title

      ECS Transasctions

      Volume: 57 Pages: 1307-1311

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Morphology control of nickel oxide nanowires2012

    • Author(s)
      K. Sekiya, K. Nagato, T. Hamaguchi, M. Nakao
    • Journal Title

      Microelectronic Engineering

      Volume: 98 Pages: 532-535

    • DOI

      10.1016/j.mee.2012.07.049

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] 数値解析を用いたNi・YSZ柱状配向構造を有するSOFC燃料極微細構造設計2014

    • Author(s)
      岩崎志貢,長藤圭介,品川俊太,西橋健,鹿園直毅,中尾政之
    • Organizer
      2014年度精密工学会春季大会学術講演会
    • Place of Presentation
      東京大学,東京
    • Year and Date
      2014-03-19
    • Related Report
      2013 Final Research Report
  • [Presentation] 数値解析を用いたNi・YSZ柱状配向構造を有するSOFC燃料極微細構造設計2014

    • Author(s)
      岩崎志貢,長藤圭介,品川俊太,西橋健,鹿園直毅,中尾政之
    • Organizer
      2014年度精密工学会春季大会学術講演会
    • Place of Presentation
      東京大学,東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] Orientation-controlled microfabrication of anode of solid oxide fuel cells2013

    • Author(s)
      Shunta Shinagawa, Keisuke Nagato, Naoki Shikazono, Tetsuya Hamaguchi, Masayuki Nakao
    • Organizer
      American Society for Precision Engineering (ASPE) Annual Meeting
    • Place of Presentation
      St. Paul, Minnesota, USA
    • Year and Date
      2013-10-22
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] Niが配列した構造を有するSOFC燃料極の開発2013

    • Author(s)
      品川俊太,長藤圭介,鹿園直毅,濱口哲也,中尾政之
    • Organizer
      日本機械学会2013年度年次大会
    • Place of Presentation
      岡山大学,岡山
    • Year and Date
      2013-09-09
    • Related Report
      2013 Final Research Report
  • [Presentation] Niが配列した構造を有するSOFC燃料極の開発2013

    • Author(s)
      品川俊太,長藤圭介,鹿園直毅,濱口哲也,中尾政之
    • Organizer
      日本機械学会2013年度年次大会
    • Place of Presentation
      岡山大学,岡山
    • Related Report
      2013 Annual Research Report
  • [Presentation] Enhancement of power efficiency of solid oxide fuel cells by aligning microstructure path of ion/electron/gas in anode2012

    • Author(s)
      Shunta Shinagawa, Keisuke Nagato, Naoki Shikazono, Tetsuya Hamaguchi, Masayuki Nakao
    • Organizer
      American Society for Precision Engineering (ASPE) Annual Meeting
    • Place of Presentation
      San Diego, CA, USA
    • Year and Date
      2012-10-23
    • Related Report
      2013 Final Research Report
  • [Presentation] Orienattion control of anisotropic particle by shear force2012

    • Author(s)
      Shota Ikeshima, Keisuke Nagato, Tetsuya Hamaguchi, Masayuki Nakao
    • Organizer
      American Society for Precision Engineering (ASPE) Annual Meeting
    • Place of Presentation
      San Diego, CA, USA
    • Year and Date
      2012-10-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] Micromixer of multi-material slurry with rotation-split-combination cycle for ceramic components2012

    • Author(s)
      Takuma Yamauchi, Keisuke Nagato, Shota Ikeshima, Tetsuya Hamaguchi, Masayuki Nakao
    • Organizer
      American Society for Precision Engineering (ASPE) Annual Meeting
    • Place of Presentation
      San Diego, CA, USA
    • Year and Date
      2012-10-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] Enhancement of power efficiency of solid oxide fuel cells by aligninh microstructure path of ion/electron/gas in anode2012

    • Author(s)
      Shunta Shinagawa, Keisuke Nagato, Naoki Shikazono, Tetsuya Hanaguchi, Masayuki Nakao
    • Organizer
      American Society for Precision Engineering (ASPE) Annual Meeting
    • Place of Presentation
      San Diego, CA, USA
    • Year and Date
      2012-10-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] SOFC燃料極内におけるNiとYSZの配列制御2012

    • Author(s)
      品川俊太,長藤圭介,鹿園直毅,関谷要,尺田将喜,濱口哲也,中尾政之
    • Organizer
      日本機械学会2012年度年次大会
    • Place of Presentation
      金沢大学,石川
    • Year and Date
      2012-09-10
    • Related Report
      2013 Final Research Report
  • [Presentation] SOFC燃料極内におけるNiとYSZの配列制御2012

    • Author(s)
      品川俊太, 長藤圭介, 鹿園直毅, 関谷要, 尺田将喜, 濱口哲也, 中尾政之
    • Organizer
      日本機械学会2012年度年次大会
    • Place of Presentation
      金沢大学
    • Year and Date
      2012-09-10
    • Related Report
      2012 Annual Research Report
  • [Presentation] Roller Replication of Nano/Microstructures of Polymers, Glasses, Metals, and Ceramics2012

    • Author(s)
      Keisuke Nagato, Daisuke Suehiro, Toshimi Sato, Shota Ikeshima, Yasuaki Watanabe, Masayuki Nakao
    • Organizer
      The 3rd International Conference on Nanomanufacturing
    • Place of Presentation
      理化学研究所, 日本
    • Year and Date
      2012-07-26
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.hnl.t.u-tokyo.ac.jp/

    • Related Report
      2013 Final Research Report

URL: 

Published: 2012-04-24   Modified: 2019-07-29  

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