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Realization of quantum well structure in bulk thermoelectric semiconductor by control of the formation of stacking fault in SiC

Research Project

Project/Area Number 24686078
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Structural/Functional materials
Research InstitutionNagoya University

Principal Investigator

HARADA Shunta  名古屋大学, グリーンモビリティ連携研究センター, 助教 (30612460)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥26,000,000 (Direct Cost: ¥20,000,000、Indirect Cost: ¥6,000,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2013: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Fiscal Year 2012: ¥13,260,000 (Direct Cost: ¥10,200,000、Indirect Cost: ¥3,060,000)
Keywords格子欠陥 / 量子井戸構造 / 熱電変換 / シリコンカーバイト / 熱電変換材料 / 積層欠陥 / 量子井戸 / 量子細線 / 部分転位分解 / 低次元電気伝導
Outline of Final Research Achievements

Thermoelectric materials which convert heat energy to electric energy attract great attention due to the efficient use of limited energy sources. Recently, Drastic improvement in the thermoelectric properties were expected by the quantum well structures. In the present study, by controlling the stacking fault formation in SiC crystal, we attempted to form the quantum well structure in the bulk semiconductors.
By the addition of nitrogen in SiC, cubic-type stacking faults are introduced to the hexagonal SiC crystal. The stacking fault would be quantum-well because the band-gap energy of cubic SiC is smaller than that of hexagonal SiC.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (28 results)

All 2015 2014 2013 2012 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 2 results) Presentation (21 results) (of which Invited: 4 results) Remarks (2 results)

  • [Journal Article] Dislocation Conversion during SiC Solution Growth for High-quality Crystals2015

    • Author(s)
      Shunta Harada, Yuji Yamamoto, Shiyu Xiao, Daiki Koike, Takuya Mutoh, Kenta Murayama, Kenta Aoyagi, Takenobu Sakai, Miho Tagawa and Toru Ujihara
    • Journal Title

      Materials Forum

      Volume: N/A

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Different behavior of threading edge dislocation conversion during the solution growth of 4H–SiC depending on the Burgers vector2014

    • Author(s)
      S. Harada, Y. Yamamoto, K. Seki, A. Horio, M. Tagawa, T. Ujihara
    • Journal Title

      Acta Materialia

      Volume: 81 Pages: 284-290

    • DOI

      10.1016/j.actamat.2014.08.027

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Surface Morphology and Threading Dislocation Conversion Behavior during Solution Growth of 4HSiC Using Al-Si Solvent2014

    • Author(s)
      S.Harada, Y.Yamamoto, S.Y.Xiao, M.Tagawa, T.Ujihara
    • Journal Title

      Mater. Sci. Forum

      Volume: 778-780 Pages: 67-70

    • DOI

      10.4028/www.scientific.net/msf.778-780.67

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evolution of threading screw dislocation conversion during solution growth of 4H-SiC2013

    • Author(s)
      S.Harada, Y.Yamamoto, K.Seki, A.Horio, T.Mitsuhashi, M.Tagawa, T.Ujihara
    • Journal Title

      APL Mater.

      Volume: 1(2) Issue: 2 Pages: 22109-22109

    • DOI

      10.1063/1.4818357

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reduction of Threading Screw Dislocation Utilizing Defect Conversion during Solution Growth of 4HSiC2013

    • Author(s)
      S.Harada, Y.Yamamoto, K.Seki, T.Ujihara
    • Journal Title

      Mater. Sci. Forum

      Volume: 740-742 Pages: 189-192

    • DOI

      10.4028/www.scientific.net/msf.740-742.189

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] SiC溶液成長における貫通転位変換と成長表面のマクロステップの関係2015

    • Author(s)
      原田 俊太, 肖 世玉, 青柳 健大, 村山 健太, 酒井 武信, 田川 美穂, 宇治原 徹
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学 湘南キャンパス、神奈川県
    • Year and Date
      2015-03-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] シンクロトロン X 線トポグラフィによる溶液成長 SiC 結晶の欠陥評価と高品質化2015

    • Author(s)
      原田俊太
    • Organizer
      第4回名古屋大学シンクロトロン光研究センターシンポジウム
    • Place of Presentation
      名古屋大学 坂田平田ホール、愛知県
    • Year and Date
      2015-01-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] SiC溶液成長における転位伝播挙動と高品質化2015

    • Author(s)
      原田俊太
    • Organizer
      第2回グリーンエネルギー材料のマルチスケール創製研究会
    • Place of Presentation
      松江市
    • Year and Date
      2015-01-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] SiC溶液成長過程における貫通転位変換現象の成長表面との相互作用による考察2014

    • Author(s)
      原田俊太, 肖世玉, 村山健太, 青柳健大, 酒井武信, 田川美穂, 宇治原徹
    • Organizer
      先進パワー半導体分科会 第1回講演会
    • Place of Presentation
      ウインクあいち、愛知県
    • Year and Date
      2014-11-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] SiC溶液成長過程における貫通転位変換現象の弾性論的考察2014

    • Author(s)
      原田俊太, 肖世玉, 村山健太, 青柳健大, 酒井武信, 田川美穂, 宇治原徹
    • Organizer
      第44回結晶成長国内会議(NCCG-44)
    • Place of Presentation
      学習院創立百周年記念会館, 東京都
    • Year and Date
      2014-11-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] Dislocation conversion during SiC solution growth for high-quality crystal2014

    • Author(s)
      S. Harada, Y. Yamamoto, S. Xiao, N. Hara, D. Koike, T. Mutoh, M. Tagawa, T. Sakai, T. Ujihara
    • Organizer
      10th European Conference on Silicon Carbide and Related Materials(ECSCRM 2014)
    • Place of Presentation
      The congress center of the World Trade Center, Grenoble, France
    • Year and Date
      2014-09-23
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 高品質4H-SiC溶液成長における多形変化抑制メカニズム2014

    • Author(s)
      原田俊太, 山本祐治, 村山健太, 青柳健大, 酒井武信, 田川美穂, 宇治原徹
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス, 北海道
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Structure of basal plane defects formed by the conversion of threading screw dislocation during solution growth of SiC2014

    • Author(s)
      S. Harada, S.Y. Xiao, M. Tagawa, Y. Yamamoto, S. Arai, N. Tanaka, T. Ujihara
    • Organizer
      SSDM2014
    • Place of Presentation
      Tsukuba International Congress Center, Ibaraki, Japan
    • Year and Date
      2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] Correlation between Surface Morphology and Threading Dislocation Conversion in Solution Growth of SiC2014

    • Author(s)
      S. Harada S.Y. Xiao, N. Hara, D. Koike, T. Mutoh, M. Tagawa, T. Ujihara
    • Organizer
      SSDM2014
    • Place of Presentation
      Fukuoka University, Fukuoka, Japan
    • Year and Date
      2014-08-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Defect evolution in high-qualit 4H-SiC grown by solution method2014

    • Author(s)
      S. Harada, M. Tagawa, T. Ujihara
    • Organizer
      IUCr 2014
    • Place of Presentation
      The Palais des congres de Montreal, Montreal, Quebec, Canada
    • Year and Date
      2014-08-11
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 溶液成長過程における貫通らせん転位変換により形成する基底面欠陥の微細構造2013

    • Author(s)
      原田俊太
    • Organizer
      2013年春季第60回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学
    • Year and Date
      2013-03-28
    • Related Report
      2012 Annual Research Report
  • [Presentation] Structure of basal plane defects formed by threading screw dislocation conversion during high quality SiC solution growth2013

    • Author(s)
      S.Harada, R.Kunimatsu, S. Xiao, Y.Yamamoto, M.Tagawa, Y.Yamamoto, S.Arai, N.Tanaka, T.Ujihara
    • Organizer
      ISETS '13
    • Place of Presentation
      Nagoya University
    • Related Report
      2013 Annual Research Report
  • [Presentation] 4H-SiC溶液成長における成長表面のステップ構造と貫通転位変換挙動の相関2013

    • Author(s)
      原田俊太、山本祐治、肖世玉、堀尾篤史、田川美穂、宇治原徹
    • Organizer
      第22回SiC講演会
    • Place of Presentation
      埼玉会館
    • Related Report
      2013 Annual Research Report
  • [Presentation] SiC溶液成長における欠陥変換挙動と高品質結晶成長2013

    • Author(s)
      原田俊太
    • Organizer
      表面技術協会 関東支部・第86回講演会「ひらめき・未来材料~進化する選択的物質貯蔵・輸送・分離・変換材料~
    • Place of Presentation
      信州大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 4H-SiC溶液成長過程における貫通転位変換挙動と成長表面モフォロジーの相関2013

    • Author(s)
      原田俊太,山本祐治,肖世玉,堀尾篤史、田川美穂,宇治原徹
    • Organizer
      第43回結晶成長国内会議
    • Place of Presentation
      長野市生涯学習センター
    • Related Report
      2013 Annual Research Report
  • [Presentation] Control of dislocation conversion during solution growth by changing surface step structure2013

    • Author(s)
      S.Harada, Y.Yamamoto, S. Xiao, A. Horio, M.Tagawa, T.Ujihara
    • Organizer
      ICSCRM 2013
    • Place of Presentation
      Phoenix Seagia Resort, Miyazaki
    • Related Report
      2013 Annual Research Report
  • [Presentation] Evolution of threading screw dislocation conversion during solution growth of 4H-SiC2013

    • Author(s)
      S.Harada, Y.Yamamoto, K. Seki, A. Horio, T. Mitsuhashi, M.Tagawa, T.Ujihara
    • Organizer
      ICCGE-17
    • Place of Presentation
      Warsaw university
    • Related Report
      2013 Annual Research Report
  • [Presentation] 透過電子顕微鏡法によるSiC溶液成長における欠陥挙動解析2012

    • Author(s)
      原田俊太
    • Organizer
      SiC及び関連ワイドギャップ半導体研究会第21回講演会
    • Place of Presentation
      大阪市中央公会堂
    • Year and Date
      2012-11-20
    • Related Report
      2012 Annual Research Report
  • [Presentation] SiC溶液成長における窒素ドープによる積層欠陥の形成2012

    • Author(s)
      原田俊太
    • Organizer
      第42回日本結晶成長学会 NCCG-42
    • Place of Presentation
      九州大学
    • Year and Date
      2012-11-10
    • Related Report
      2012 Annual Research Report
  • [Presentation] Direct Observation of Defect Evolution during Solution Growth of SiC by Synchrotron X-ray Topography2012

    • Author(s)
      原田俊太
    • Organizer
      IUMRS-ICEM 2012
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2012-09-23
    • Related Report
      2012 Annual Research Report
  • [Presentation] Possibility for elimination of dislocations in SiC crystal : conversion of threading edge dislocations by solution growth2012

    • Author(s)
      原田俊太
    • Organizer
      ECSCRM 2012
    • Place of Presentation
      Russia, Saint-Peterburg
    • Year and Date
      2012-09-05
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://shuntaharada.web.fc2.com/japanese/index.htm

    • Related Report
      2014 Annual Research Report
  • [Remarks]

    • URL

      http://shuntaharada.web.fc2.com/japanese/index.htm

    • Related Report
      2012 Annual Research Report

URL: 

Published: 2012-04-24   Modified: 2019-07-29  

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