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Determination of dynamics of SiC solution growth by real-time observation of growth interface

Research Project

Project/Area Number 24686083
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Metal making engineering
Research InstitutionThe University of Tokyo

Principal Investigator

TAKESHI Yoshikawa  東京大学, 生産技術研究所, 准教授 (90435933)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥26,650,000 (Direct Cost: ¥20,500,000、Indirect Cost: ¥6,150,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2012: ¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Keywordsシリコンカーバイド / 溶液成長 / 成長界面 / リアルタイム観察 / バンチング
Outline of Final Research Achievements

To determine the interfacial phenomena at the SiC-solution interface during solution growth of single crystalline SiC, observation and measurement techniques of high temperature interface has been established, and then growth behavior was investigated.
At first, white color and single color laser lights were irradiated through seed crystal, and the reflected lights at the interface were captured. 2-dimenstional observation of the interface structure composed of 10-100nm height and t measurement of step height with 2 nm have been achieved. Then, interfacial observation was conducted for various conditions, and effect of temperature condition and solvent system on the interfacial structure was examined. The difference of the step stability when using Si, Si-Cr, Fe-Si solvents was demonstrated. Furthermore, the nucleation of 3C-SiC on 4H-SiC substrate was directly observed and the mechanism of different poly-type formation was suggested.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • 2012 Annual Research Report
  • Research Products

    (15 results)

All 2014 2013 2012 Other

All Journal Article (3 results) (of which Peer Reviewed: 2 results) Presentation (12 results) (of which Invited: 2 results)

  • [Journal Article] 可視光透過法によるSiC結晶-溶融合金界面のIn-situ観察2014

    • Author(s)
      吉川 健, 川西咲子
    • Journal Title

      金属

      Volume: 84 Pages: 36-43

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Real-time observation of the interface between SiC and a liquid alloy and its application to the dissolution behavior of SiC at 1573 K2013

    • Author(s)
      Sakiko Kawanishi, Takeshi Yoshikawa, Kazuki Morita, Kazuhiko Kusunoki, Kazuhito Kamei, Hiroshi Suzuki and Hidemitsu Sakamoto
    • Journal Title

      Journal of Applied Physics

      Volume: 114 Issue: 21 Pages: 214313-214313

    • DOI

      10.1063/1.4837575

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Real-time observation of high temperature interface between SiC substrate and solution during dissolution of SiC2013

    • Author(s)
      Sakiko Kawanishi, Takeshi Yoshikawa and Kazuki Morita
    • Journal Title

      Materials Science Forum

      Volume: 740-742 Pages: 35-38

    • DOI

      10.4028/www.scientific.net/msf.740-742.35

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Interfacial behavior at the initial stage of solution growth of SiC investigated by real-time observation of the growth interface2014

    • Author(s)
      Sakiko Kawanishi and Takeshi Yoshikawa
    • Organizer
      The 10th European Conference on Silicon Carbide & Related Materials
    • Place of Presentation
      グルノーブル
    • Year and Date
      2014-09-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] In-situ Observation of SiC Growth from Fe-Si-C Solution2014

    • Author(s)
      Sakiko Kawanishi and Takeshi Yoshikawa
    • Organizer
      The 15th IUMRS-International Conference in Asia
    • Place of Presentation
      福岡
    • Year and Date
      2014-08-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] SiCの溶液成長と成長界面のリアルタイム観察2013

    • Author(s)
      吉川健, 川西咲子, 森田一樹
    • Organizer
      資源・素材学会
    • Place of Presentation
      千葉工業大学(招待講演)
    • Year and Date
      2013-03-30
    • Related Report
      2012 Annual Research Report
  • [Presentation] 干渉縞を利用した溶融合金へのSiC溶解時の高温界面リアルタイム観察2013

    • Author(s)
      川西咲子, 吉川健, 森田一樹, 鈴木寛, 坂元秀光
    • Organizer
      応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学
    • Year and Date
      2013-03-28
    • Related Report
      2012 Annual Research Report
  • [Presentation] 干渉縞を利用したSiC-溶融合金間界面の高温リアルタイム観察2013

    • Author(s)
      川西咲子, 吉川健, 森田一樹 ,鈴木竈, 坂元秀光
    • Organizer
      日本鉄鋼協会
    • Place of Presentation
      東京電機大学
    • Year and Date
      2013-03-28
    • Related Report
      2012 Annual Research Report
  • [Presentation] 溶融合金へのSiC溶解時の高温界面のリアルタイム観察2012

    • Author(s)
      川西咲子, 吉川健, 森田一樹, 亀井一人, 坂元秀光, 鈴木竈
    • Organizer
      日本鉄鋼協会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2012-09-19
    • Related Report
      2012 Annual Research Report
  • [Presentation] Real-time observation of high temperature interface between SiC substrate and solution during dissolution of SiC2012

    • Author(s)
      Sakiko Kawanishi, Takesni Yoshikawa and Kazuki Morita
    • Organizer
      The 9th European Conference on Silicon Carbide & Related Materials
    • Place of Presentation
      St. Petersburg (Russia)
    • Year and Date
      2012-09-02
    • Related Report
      2012 Annual Research Report
  • [Presentation] 温度差法によるSiCの低温溶液成長と成長界面リアルタイム観察

    • Author(s)
      吉川 健, 川西咲子, 森田一樹
    • Organizer
      日本結晶成長学会ナノ構造・エピタキシャル成長分科会
    • Place of Presentation
      大阪大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 可視光透過法によるSiC溶液成長界面の高温下リアルタイム観察

    • Author(s)
      川西咲子, 吉川 健, 森田 一樹, 亀井 一人,楠 一彦,坂元 秀光,鈴木 寛,
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Interference observation of the interface between SiC and liquid alloy and its application to dissolution process of SiC

    • Author(s)
      Sakiko Kawanishi, Takeshi Yoshikawa and Kazuki Morita
    • Organizer
      International Conference on Silicon Carbide and Related Materials 2013 (ICSCRM 2013)
    • Place of Presentation
      宮崎シーガイア
    • Related Report
      2013 Annual Research Report
  • [Presentation] SiCのメルトバック・溶液成長界面のリアルタイム観察

    • Author(s)
      川西咲子, 吉川 健, 森田 一樹
    • Organizer
      SiC及び関連半導体研究 第22回講演会
    • Place of Presentation
      埼玉会館
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] SiC溶液成長界面の明視野像・干渉像のリアルタイム同時観察

    • Author(s)
      川西咲子, 吉川 健, 森田 一樹
    • Organizer
      第75回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学
    • Related Report
      2013 Annual Research Report

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Published: 2012-04-24   Modified: 2019-07-29  

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