| Budget Amount *help |
¥26,650,000 (Direct Cost: ¥20,500,000、Indirect Cost: ¥6,150,000)
Fiscal Year 2015: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2013: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2012: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
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| Outline of Final Research Achievements |
In this research, we have developed novel bond-forming methods not usually occurring without the use of metal catalysts, by modifying the introduction of hypervalent iodine species and the reductive bond-forming processes of specific importance in reaction design of hypervalent iodine chemistry. In addition, a new design of the reagents and process development aiming at enhancing the reaction efficiencies have been carried out with success. Based on the newly developed strategy as well as our original synthetic techniques, by synthesizing a family of highly oxygenated and functionalized aromatics and their derivatives, we have further extended the strategy to a series of new constructing methods of molecular backbones for enabling the synthesis of core structures of bioactive compounds and functional materials.
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