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High value-added technology of molten blast furnace slag using unutilized waste heat

Research Project

Project/Area Number 24710086
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental technology/Environmental materials
Research InstitutionChiba University (2013-2014)
Akita University (2012)

Principal Investigator

WAJIMA Takaaki  千葉大学, 工学(系)研究科(研究院), 准教授 (00380808)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords鉄鋼スラグ / 未利用廃熱 / アルカリ溶融 / 機能性素材 / ハイドロカルマイト / 炭酸ナトリウム / ケイ酸ナトリウム / 酸化カルシウム / 未利用廃熱利用 / アルカリ溶融反応 / 溶融高炉スラグ / 高付加価値化 / 冷却過程 / 高反応性前駆体 / リン除去能 / 高炉スラグ
Outline of Final Research Achievements

In this study, we attempted to convert molten blast furnace slag into functional materials via alkali fusion using unutilized waste heat. With addition of sodium carbonate, blast furnace slag molten at 1500 oC can be converted into alkali fused materials with high reactivity, and fused materials can be converted into functional materials, such as hydrocalumite, hydrogarnet, hydroxysodalite, zeolite-A and zeolite-X. The product including hydrocalumite can be synthesized from fused material in distilled water at room temperature, and has high removal ability for phosphate from aqueous solution. The product including hydrogarnet can be synthesized in distilled water at 80 oC, and those including zeolites can be synthesized in distilled water with addition of EDTA at 80oC.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (18 results)

All 2015 2014 2013 2012 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (10 results) Remarks (1 results)

  • [Journal Article] Synthesis of Zeolite from Blast Furnace Slag using Alkali Fusion with Addition of EDTA2014

    • Author(s)
      Takaaki Wajima
    • Journal Title

      Advanced Materials Research

      Volume: 1044-45 Pages: 124-127

    • DOI

      10.4028/www.scientific.net/amr.1044-1045.124

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Removal of fluoride ions using calcined paper sludge2013

    • Author(s)
      Takaaki Wajima, John F. Rakovan
    • Journal Title

      Journal of Thermal Analysis and Calorimetry

      Volume: Accepted

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Removal behavior of phosphate from aqueous solution by calcined paper sludge2013

    • Author(s)
      Takaaki Wajima, John F. Rakovan
    • Journal Title

      Colloids and Surfaces A: Physicochemical and Engineering Aspects

      Volume: Accepted

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation of adsorbent with high removal ability for phosphate ion from blast furnace slag using alkali fusion2012

    • Author(s)
      Takaaki Wajima, Kazuko Oya, Atsushi Shibayama, Kenzo Munakata
    • Journal Title

      International Journal of the Society of Materials Engineering for Resources

      Volume: 18 Pages: 59-63

    • NAID

      130003377330

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of zeolitic material from paper sludge ash using diatomite2012

    • Author(s)
      Takaaki Wajima, Kenzo Munakata
    • Journal Title

      Materials Transactions

      Volume: 53 Pages: 592-596

    • NAID

      10030550448

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of alkali species on synthesis of K-F zeolitic materials from paper sludge ash for soil amendment2012

    • Author(s)
      Takaaki Wajima, Kenzo Munakata
    • Journal Title

      Chemical Engineering Journal

      Volume: 207-208 Pages: 906-912

    • DOI

      10.1016/j.cej.2012.06.136

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] A novel adsorbent synthesized from blast furnace slag with phosphate sorption capacity2012

    • Author(s)
      Takaaki Wajima
    • Journal Title

      Proceedings of XXVI International Mineral Processing Congress (IMPC2012)

      Volume: 1 Pages: 5757-5767

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 炭酸ナトリウムを用いた高炉スラグの機能性物質転換法の開発2015

    • Author(s)
      金塚恭平、和嶋隆昌
    • Organizer
      日本海水学会若手会第6回学生研究発表会
    • Place of Presentation
      北海道登別
    • Year and Date
      2015-03-09 – 2015-03-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] 未利用廃熱を利用した高炉スラグのアルカリ溶融処理とその生成物評価2015

    • Author(s)
      金塚恭平、和嶋隆昌
    • Organizer
      第17回化学工学会学生発表会
    • Place of Presentation
      青森県八戸市
    • Year and Date
      2015-03-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] アルカリ溶融反応を利用したパーライト砕石微粒分からのフォージャサイト型ゼオライトの合成2014

    • Author(s)
      和嶋隆昌、今井敏夫、佐野奨、神谷隆、高野博幸
    • Organizer
      第30回ゼオライト研究発表会
    • Place of Presentation
      船堀
    • Year and Date
      2014-11-26 – 2014-11-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 砕石微粒分からの機能性材料製造におけるアルカリ溶融処理プロセス2014

    • Author(s)
      和嶋隆昌、今井敏夫、佐野奨、神谷隆、高野博幸
    • Organizer
      資源・素材学会秋季大会
    • Place of Presentation
      熊本
    • Year and Date
      2014-09-15 – 2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高炉スラグからの高機能リン回収材の合成2014

    • Author(s)
      和嶋隆昌
    • Organizer
      日本鉄鋼協会第167回春季講演大会
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Presentation] Removal behavior of phosphate from aqueous solution by calcined paper paper sludge2012

    • Author(s)
      Takaaki Wajima, John F. Rakovan
    • Organizer
      7th International Conference on Interface Against Pollution (IAP2012)
    • Place of Presentation
      Nancy, France
    • Related Report
      2012 Research-status Report
  • [Presentation] Removal of fluoride ions using calcined paper sludge2012

    • Author(s)
      Takaaki Wajima, John F. Rakovan
    • Organizer
      15th International Congress on Thermal Analysis and Calorimetry (ICTAC15)
    • Place of Presentation
      近畿大学、東大阪市
    • Related Report
      2012 Research-status Report
  • [Presentation] Effect of alkali species on synthesis of K-F zeolitic materials from paper sludge ash for soil amendment2012

    • Author(s)
      Takaaki Wajima, Kenzo Munakata
    • Organizer
      International Symposium on Chemical Reaction Engineering (ISCRE22)
    • Place of Presentation
      Maastricht, Netherland
    • Related Report
      2012 Research-status Report
  • [Presentation] A novel adsorbent synthesized from blast furnace slag with phosphate sorption capacity2012

    • Author(s)
      Takaaki Wajima
    • Organizer
      XXVI International Mineral Processing Congress (IMPC2012)
    • Place of Presentation
      New Delhi, India
    • Related Report
      2012 Research-status Report
  • [Presentation] ハイドロキシソーダライトの塩化水素ガス除去能

    • Author(s)
      (和嶋隆昌、宗像健三)
    • Organizer
      日本素材物性学会平成24年度年会
    • Place of Presentation
      秋田ビューホテル、秋田市
    • Related Report
      2012 Research-status Report
  • [Remarks] 岩石系副産物を原料とした機能性物質転換プロセスに関する研究

    • URL

      http://wajima-lab.tu.chiba-u.ac.jp/research.html

    • Related Report
      2013 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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