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Average and local structural study of proton conductivity by complementary use of neutron and X-ray

Research Project

Project/Area Number 24710100
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Quantum beam science
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

KIYANAGI RYOJI  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 J-PARCセンター, 研究員 (50521770)

Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2014: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords中性子構造解析 / プロトン伝導体 / 中性子回折 / 結晶構造 / 超プロトン伝導体
Outline of Final Research Achievements

The purpose of this research is to elucidate the underlying mechanism of the super protonic conduction realized in solid acids. Solid solutions of the solid acids were selected as the target materials in order to precisely understand the relationship between the crystal structure and the super protonic conductivity. The conductivity measurements revealed that the phase transition temperature to the super protonic conductive phase non-linearly varies as the ratio of the solid solutions were changed. Meanwhile, the crystal structure analyses by the neutron diffraction method displayed that the distortion of SeO4 tetrahedrons changes as the ratio of the solid solutions changes. This variation was also non-linear to the ratio of the solid solution, suggesting the direct relationship to the phase transition temperature.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (9 results)

All 2015 2014 2013

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (7 results)

  • [Journal Article] Phase transition and internal crystal structure of superprotonic conductor, Rb3-xKxH(SeO4)22015

    • Author(s)
      Ryoji Kiyanagi, Yasumitsu Matsuo, Takshi Ohhara, Takuro Kawasaki, Kenichi Oikawa, Koji Kaneko, Itraru Tamura, Takayasu Hanashima, Koji Munakata, Akiko Nakao, Yukinobu Kawakita
    • Journal Title

      JPS Conf. Proc.

      Volume: 印刷中

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Proton Conduction Path in Rb3H(SeO4)2 Studied by High Temperature Neutron Single Crystal Diffraction2014

    • Author(s)
      R. Kiyanagi, Y. Ishikawa, Y. Noda
    • Journal Title

      JPS Conf. Proc.

      Volume: 1 Pages: 0120341-6

    • DOI

      10.7566/jpscp.1.012034

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Proton conduction mechanism and phase transition of (Rb,K)3H(SeO4)22014

    • Author(s)
      Ryoji Kiyanagi, Yasumitsu Matsuo, Yoshihisa Ishikawa, Yukio Noda, Takashi Ohhara, Takuro Kawasaki, Kenichi Oikawa, Koji Kaneko, Itaru Tamura, Takayasu Hanashima, Koji Munakata, Akiko Nakao, Yukinobu Kawakita
    • Organizer
      Congress and General Assembly of International Union of Crystallography
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      2014-08-05 – 2014-08-12
    • Related Report
      2014 Research-status Report
  • [Presentation] Structural study of Solid solution of protonic conductors Rb3-xKxH(SeO4)2 by single crystal neutron diffraction2013

    • Author(s)
      Ryoji Kiyanagi, Yasumitsu Matsuo, Takashi Ohhara, Takuro Kawasaki, Kenichi Oikawa, Koji Kaneko, Itaru Tamura, Takayasu Hanashima, Koji Munakata, Akiko Nakao, Yukinobu Kawakita
    • Organizer
      International Conference on Neutron Scattering
    • Place of Presentation
      イギリス エディンバラ
    • Related Report
      2013 Research-status Report
  • [Presentation] Proton conduction path in Rb3H(SeO4)2 studied by high temperature neutron single crystal diffraction2013

    • Author(s)
      R. Kiyanagi, Y. Ishikawa, Y. Noda
    • Organizer
      The 12th Asia Pacific Physics Conference of AAPPS
    • Place of Presentation
      幕張
    • Related Report
      2013 Research-status Report
  • [Presentation] 超プロトン伝導体Rb3-xKxH(SeO4)2の結晶構造と相転移2013

    • Author(s)
      鬼柳亮嗣,松尾康光、大原高志、川崎卓郎、及川建一、金子耕士、田村格良、中尾朗子、花島隆泰、宗像孝司、川北至信
    • Organizer
      平成25年度日本結晶学会年会
    • Place of Presentation
      熊本
    • Related Report
      2013 Research-status Report
  • [Presentation] Relation between crystal structure and phase transition of protonic conductor, Rb3-xKxH(SeO4)22013

    • Author(s)
      Ryoji Kiyanagi, Yasumitsu Matsuo, Takashi Ohhara, Takuro Kawasaki, Kenichi Oikawa, Koji Kaneko, Itaru Tamura, Takayasu Hanashima, Koji Munakata, Akiko Nakao, Yukinobu Kawakita
    • Organizer
      The 12th conference of the Asian Crystallographic Association
    • Place of Presentation
      中国 香港
    • Related Report
      2013 Research-status Report
  • [Presentation] Structural study of solid solution of protonic conductors Rb3-xKxH(SeO4)2 by single crystal neutron diffraction2013

    • Author(s)
      Ryoji Kiyanagi, et. al.
    • Organizer
      International Conference on Neutron Scattering
    • Place of Presentation
      Edinburgh(英国)
    • Related Report
      2012 Research-status Report
  • [Presentation] Proton conduction path in Rb3H(SeO4)2 studied by high temperature neutron single crystal diffraction2013

    • Author(s)
      Ryoji Kiyanagi, et. al.
    • Organizer
      The 12th Asia Pacific Physics Conference
    • Place of Presentation
      千葉
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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