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Structural determination of nanoparticulate catalysts during the synthesis of carbon nanomaterials using aberration-corrected environmental transmission electron microscopy

Research Project

Project/Area Number 24710117
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nanomaterials/Nanobioscience
Research InstitutionOsaka University

Principal Investigator

YOSHIDA Hideto  大阪大学, 産業科学研究所, 准教授 (00452425)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsカーボンナノチューブ / ナノ粒子 / 触媒 / 欠陥 / 環境制御型透過電子顕微鏡 / その場観察 / 成長機構 / 界面構造 / 電子顕微鏡 / グラフェン
Research Abstract

We obtained new atomic-scale insights into the growth mechanism of carbon nanotubes from nanoparticle catalysts in chemical vapor deposition. Using environmental transmission electron microscopy, we observed that small deformations of nanoparticle catalysts at the interface with carbon nanotubes result in bends and disorder of the interlayer spacing of growing carbon nanotubes. Changes in the diameter and number of graphitic layers in growing carbon nanotubes are caused by large protrusions and shrink deformations of nanoparticle catalysts. Furthermore, we succeeded in determining the structure of fluctuating nanoparticle catalysts during carbon nanotube growth by comparing image simulations with the time-dependent environmental transmission electron microscope images.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (16 results)

All 2014 2013 2012 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (12 results) (of which Invited: 2 results) Remarks (2 results)

  • [Journal Article] Elucidation of the Origin of Grown-in Defects in Carbon Nanotubes2014

    • Author(s)
      Hideto Yoshida and Seiji Takeda
    • Journal Title

      Carbon

      Volume: 70 Pages: 266-272

    • DOI

      10.1016/j.carbon.2014.01.006

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] In Situ Analysis of Crystalline Fe-Mo-C Nanoparticle Catalysts during the Growth of Carbon Nanotubes2012

    • Author(s)
      Hideto Yoshida, Hideo Kohno, and Seiji Takeda
    • Journal Title

      Micron

      Volume: 43 Issue: 11 Pages: 1176-1180

    • DOI

      10.1016/j.micron.2012.04.008

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Structure of Nanoparticles during the Cobalt-Catalyzed Carbon Nanotube Growth2013

    • Author(s)
      Yusuke Kohigashi, Hideto Yoshida, Seiji Takeda
    • Organizer
      2013 MRS Fall Meeting
    • Place of Presentation
      Hynes Convention Center (Boston, USA)
    • Year and Date
      2013-12-05
    • Related Report
      2013 Final Research Report
  • [Presentation] In-Situ Environmental TEM Observation of Formation of Defects in Growing Carbon Nanotubes2013

    • Author(s)
      Hideto Yoshida, Seiji Takeda
    • Organizer
      2013 MRS Fall Meeting
    • Place of Presentation
      Hynes Convention Center (Boston, USA)
    • Year and Date
      2013-12-04
    • Related Report
      2013 Final Research Report
  • [Presentation] カーボンナノチューブ成長時における欠陥生成のその場TEM観察2013

    • Author(s)
      吉田秀人,竹田精治
    • Organizer
      2013年第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2013-09-16
    • Related Report
      2013 Final Research Report
  • [Presentation] カーボンナノチューブ成長時の金属ナノ粒子触媒のその場観察2013

    • Author(s)
      小東勇亮,吉田秀人,竹田精治
    • Organizer
      日本顕微鏡学会第69回学術講演会
    • Place of Presentation
      ホテル阪急エキスポパーク
    • Year and Date
      2013-05-20
    • Related Report
      2013 Final Research Report
  • [Presentation] カーボンナノチューブ成長時の金属ナノ粒子触媒のその場観察2013

    • Author(s)
      小東 勇亮,吉田 秀人,竹田 精治
    • Organizer
      日本顕微鏡学会第69回学術講演会
    • Place of Presentation
      ホテル阪急エキスポパーク(大阪府)
    • Related Report
      2013 Annual Research Report
  • [Presentation] カーボンナノチューブ成長時における欠陥生成のその場TEM観察2013

    • Author(s)
      吉田秀人,竹田精治
    • Organizer
      2013年第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府)
    • Related Report
      2013 Annual Research Report
  • [Presentation] In-Situ Environmental TEM Observation of Formation of Defects in Growing Carbon Nanotubes2013

    • Author(s)
      Hideto Yoshida, Seiji Takeda
    • Organizer
      2013 MRS Fall Meeting
    • Place of Presentation
      Hynes Convention Center, Boston, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structure of Nanoparticles during the Cobalt-Catalyzed Carbon Nanotube Growth2013

    • Author(s)
      Yusuke Kohigashi, Hideto Yoshida, Seiji Takeda
    • Organizer
      2013 MRS Fall Meeting
    • Place of Presentation
      Hynes Convention Center, Boston, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] コバルトを触媒とするカーボンナノチューブ成長におけるナノ粒子の構造2012

    • Author(s)
      吉田秀人,小東勇亮,竹田精治
    • Organizer
      2012年秋季第73回応用物理学会秋季学術講演会
    • Place of Presentation
      愛媛大学・松山大学
    • Year and Date
      2012-09-13
    • Related Report
      2013 Final Research Report
  • [Presentation] In situ observation of carbon nanotube growth from catalyst nanoparticles by environmental TEM2012

    • Author(s)
      Hideto Yoshida, Seiji Takeda
    • Organizer
      The 6th International Conference on the Science and Technology for Advanced Ceramics (STAC-6)
    • Place of Presentation
      Mielparque Yokohama
    • Year and Date
      2012-06-26
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] In situ observation of carbon nanotube growth from catalyst nanoparticles by environmental TEM2012

    • Author(s)
      Hideto Yoshida and Seiji Takeda
    • Organizer
      The 6th International Conference on the Science and Technology for Advanced Ceramics (STAC-6)
    • Place of Presentation
      Mielparque Yokohama, Yokohama, Japan
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] コバルトを触媒とするカーボンナノチューブ成長におけるナノ粒子の構造2012

    • Author(s)
      吉田 秀人,小東 勇亮,竹田 精治
    • Organizer
      2012年秋季第73回応用物理学会秋季学術講演会
    • Place of Presentation
      愛媛大学・松山大学,愛媛県
    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://www.sanken.osaka-u.ac.jp/labs/nnf/achievement.html

    • Related Report
      2013 Final Research Report
  • [Remarks] 大阪大学産業科学研究所竹田研究室ホームページ

    • URL

      http://www.sanken.osaka-u.ac.jp/labs/nnf/achievement.html

    • Related Report
      2013 Annual Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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