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Diffusion dynamics of hydrogen molecules in clathrate hydrate

Research Project

Project/Area Number 24740198
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Condensed matter physics I
Research InstitutionThe University of Tokyo

Principal Investigator

KOFU Maiko  東京大学, 物性研究所, 助教 (70549568)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2012: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords水素 / 包接化合物 / 中性子散乱 / 拡散 / 国際研究者交流(米国) / 国際研究者交流(フランス)
Research Abstract

The relaxation dynamics of the H2 molecules in the clathrate hydrate has been investigated by using quasielastic neutron scattering (QENS) techniques. New type of samples cell were developed for high-pressure measurements. We have found that the H2 molecules move in the timescale of 10ps between 180K and 210K. By investigating how the relaxation changes with the scattering vector, it is made clear that the relaxation is of local origin. On the other hand, no relaxation was detected in the timescale between 0.1ns and 2ns at the temperature ranging from 5K to 260K. To understand what happens, we are now planning to investigate the relaxation of the H2 molecules between 10ps and 0.1ns. These measurements can reveal the motion of the H2 molecules in the clathrate hydrate.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (10 results)

All 2013 2012 Other

All Presentation (8 results) Remarks (2 results)

  • [Presentation] 抱接水和物中の水素の拡散ダイナミクス2013

    • Author(s)
      古府麻衣子、奥地拓生、Hannu Mutka、jacques Ollivier、Craig Brown、Madhusudan Tyagi、山室修
    • Organizer
      日本中性子科学会第13回年会
    • Place of Presentation
      さわやかちば県民プラザ(千葉県)
    • Year and Date
      2013-12-13
    • Related Report
      2013 Final Research Report
  • [Presentation] 中性子散乱で観た抱接水和物中の水素の拡散ダイナミクス2013

    • Author(s)
      古府麻衣子、奥地拓生、Hannu Mutka、jacques Ollivier、Craig Brown、Madhusudan Tyagi、山室修
    • Organizer
      日本物理学会2013年秋季大会
    • Place of Presentation
      徳島大学(徳島県)
    • Year and Date
      2013-09-26
    • Related Report
      2013 Final Research Report
  • [Presentation]2013

    • Author(s)
      Maiko Kofu, Takuo Okuchi,Hannu Mutka, Jacques Ollivier, Craig Brown, Madhusudan Tyagi, Osamu Yamamuro
    • Organizer
      International Conference on Neutron Scattering (ICNS2013)
    • Place of Presentation
      Edingburgh (UK)
    • Year and Date
      2013-07-10
    • Related Report
      2013 Final Research Report
  • [Presentation] Dynamics of hydrogen molecules in clathrate hydrate2013

    • Author(s)
      古府麻衣子
    • Organizer
      International Conference on Neutron Scattering
    • Place of Presentation
      エディンバラ(UK)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 中性子散乱で観た包椄水和物中の水素の拡散ダイナミクス2013

    • Author(s)
      古府麻衣子
    • Organizer
      物理学会秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス(徳島県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 包接水和物中の水素の拡散ダイナミクス2013

    • Author(s)
      古府麻衣子
    • Organizer
      日本中性子科学会第13回年会
    • Place of Presentation
      さわやかちば県民プラザ(千葉県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 中性子散乱で観た水素ハイドレート中の水素の拡散ダイナミクス2012

    • Author(s)
      古府麻衣子、山室修、奥地拓生
    • Organizer
      第53回高圧討論会
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2012-11-07
    • Related Report
      2013 Final Research Report
  • [Presentation] 中性子散乱で観た水素ハイドレート中の水素の拡散ダイナミクス2012

    • Author(s)
      古府麻衣子、山室修、奥地拓生
    • Organizer
      第53回高圧討論会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://yamamuro.issp.u-tokyo.ac.jp/

    • Related Report
      2013 Final Research Report
  • [Remarks] 東京大学物性研究所山室研究室

    • URL

      http://yamamuro.issp.u-tokyo.ac.jp/

    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2020-05-15  

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