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Thermodynamic study of anisotropic excitation stracture and quantum critical behavior on quantum spin liquid

Research Project

Project/Area Number 24740252
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Condensed matter physics II
Research InstitutionOsaka University

Principal Investigator

Yamashita Satoshi  大阪大学, 理学(系)研究科(研究院), 助教 (40587466)

Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords量子スピン液体 / 分子性導体 / 熱測定 / 強相関 / 分子性固体 / 磁性
Outline of Final Research Achievements

Quantum spin liquid(QSL) with gap-less excitation was observed in dithiolene complex EtMe3Sb[Pd(dmit)2]2. In order to distinguish whether the gap-less behavior is one kind of critical behavior or a character of “QSL phase”, we have performed systematic heat capacity measurements for caion mixed solid solution system of XY[Pd(dmit)2]2. From the measurements for QSL+Antiferromangetic(AF) system, QSL+Charge order(CO) System, we found that the g values in heat capacity were slightly decrease with increasing AF content and slightly increase with increase CO content. This behavior was reproduced in AF+CO system. We confirmed the gap-less character is originated from the QSL phase. The critical like behavior was also observed on QSL-AF phase boundary.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (24 results)

All 2016 2015 2014 2013 2012 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Open Access: 1 results) Presentation (15 results) (of which Int'l Joint Research: 1 results,  Invited: 3 results) Remarks (1 results)

  • [Journal Article] Construction of Relaxation Carorimetry for 101-2 Micro-gram Samples and Heat Capacity Measurements of Organic Complexes2016

    • Author(s)
      Shusaku Imajo, Shuhei Fukuoka, Satoshi Yamashita, and Yasuhiro Nakazawa
    • Journal Title

      Journal of Thermal Analysis and Calorimetry

      Volume: 123 Issue: 3 Pages: 1871-1876

    • DOI

      10.1007/s10973-015-4885-5

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rotational Tunneling of Methyl Groups and the Electronic Heat Capacity of EtMe3Sb[Pd(dmit)2]2 under Magnetic Fields2016

    • Author(s)
      Satoshi Yamashita, Masayuki Yoshizumi, Hiroki Akutsu, Yasuhiro Nakazawa, Kohei Ueda, Reizo Kato
    • Journal Title

      International Journal of Modern Physics B

      Volume: in press Issue: 13 Pages: 1642007-1642007

    • DOI

      10.1142/s0217979216420078

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heat Capacity of Spin Liquid System of EtMe3Sb[Pd(dmit)2]22015

    • Author(s)
      S. Yamashita, R. Yoshimoto, S. Fukuoka, Y. Nakazawa, R. Kato
    • Journal Title

      Quantum Matter

      Volume: 4 Issue: 4 Pages: 1-4

    • DOI

      10.1166/qm.2015.1198

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Coupling of Charge and Lattice Degrees of Freedoms in θ-Type BEDT-TTF Compound Probed by Low-Temperature Heat Capacity Measurements2014

    • Author(s)
      R. Yoshimoto, Y. Takane, K. Hino, S. Yamashita, Y. Nakazawa
    • Journal Title

      PhysicaB

      Volume: 449 Pages: 19-24

    • DOI

      10.1016/j.physb.2014.04.076

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic Behavior of Quantum Spin Liquid State with Gapless Excitation Structure in Molecule Based Dimer Mott Insulators2014

    • Author(s)
      山下智史
    • Journal Title

      Netsu Sokutei

      Volume: 40 Pages: 120-126

    • NAID

      40019782409

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Heat Capacity of Spin Liquid System of EtMe3Sb[Pd(dmit)2]22013

    • Author(s)
      S. Yamashita, R. Yoshimoto, S. Fukuoka, Y. Nakazwa, R. Kato
    • Journal Title

      Quantum Matter

      Volume: in press

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Thermodynamics of a Liquid-Like Spin State in Molecule-Based Magnets with Geometric Frustrations2013

    • Author(s)
      Y. Nakazawa and S. Yamashita
    • Journal Title

      Chem. Lett. Highlight Review

      Volume: 42 Issue: 12 Pages: 1446-1454

    • DOI

      10.1246/cl.130656

    • NAID

      130004867820

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic Properties of k-(BEDT -TTF)_2X Salts: Electron Correlations and Superconductivity2012

    • Author(s)
      Y. Nakazawa, S. Yamashita
    • Journal Title

      Crystals

      Volume: 2 Issue: 3 Pages: 741-761

    • DOI

      10.3390/cryst2030741

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Thermdynamic Properties of Spin Liquid in Dimer-Mott Organic Compounds2015

    • Author(s)
      Yasuhiro Nakazawa , Satoshi Yamashita, Hiroki Akutsu, Hengbo Cui Kohei Ueda Reizo Kato
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Hawaii(USA)
    • Year and Date
      2015-12-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] X[PtxPd1-x(dmit)2]2混晶塩の低温熱容量2015

    • Author(s)
      山下智史,中澤康浩,上田康平,加藤礼三
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学千里山キャンパス
    • Year and Date
      2015-09-18
    • Related Report
      2015 Annual Research Report
  • [Presentation] フェルミ液体的性質を有するスピン液体相における励起構造に関する熱力学的研究2015

    • Author(s)
      山下智史
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学早稲田キャンパス(東京,新宿)
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] X[Pd(dmit)2]2 塩における電荷秩序状態に関する熱的研究2014

    • Author(s)
      山下智史,中澤康浩,上田康平,加藤礼三
    • Organizer
      第50回記念熱測定討論会
    • Place of Presentation
      大阪大学豊中キャンパス(大阪,豊中)
    • Year and Date
      2014-09-28 – 2014-09-30
    • Related Report
      2014 Research-status Report
  • [Presentation] Thermodynamic Behavior of the Spin-Liquid Compound in Dimerized Charge Transfer Salts2014

    • Author(s)
      Satoshi Yamashita, Yasuhiro Nakazawa, Reizo Kato
    • Organizer
      The International Symposium on Structural Thermodynamics in Memory of Prof. Syuzo Seki (ISST-2014)
    • Place of Presentation
      大阪大学豊中キャンパス(大阪,豊中)
    • Year and Date
      2014-09-27
    • Related Report
      2014 Research-status Report
  • [Presentation] Phase Relation of Quantum Spin Liquid in X[Pd(dmit)2]2 System2014

    • Author(s)
      Satoshi Yamashita
    • Organizer
      Gordon Research Conference, Conductivity & Magnetism in Molecular Materials
    • Place of Presentation
      Lewiston(USA)
    • Year and Date
      2014-08-03 – 2014-08-08
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] EtxMe4-xSb[Pd(dmit)2]2塩における電荷秩序状態と量子スピン液体状態の熱容量差に関する考察2014

    • Author(s)
      山下智史,上田康平,中澤康浩,加藤礼三
    • Organizer
      第69回日本物理学会年次大会
    • Place of Presentation
      湘南
    • Related Report
      2013 Research-status Report
  • [Presentation] THERMODYNAMIC BEHAVIOR OF QUANTUM SPIN LIQUID STATE IN DIMER MOTT INSULATOR2013

    • Author(s)
      S. Yamashita, Y. Nakazawa, R. Kato
    • Organizer
      THe Fifth International Symposium on the New Frontiers of Thermal Studies of Materials
    • Place of Presentation
      Yokohama, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] 分子性導体における格子熱容量と電子基底状態の関係に関する熱的考察2013

    • Author(s)
      山下智史,中澤康浩,加藤礼三
    • Organizer
      第49回熱測定討論会
    • Place of Presentation
      習志野
    • Related Report
      2013 Research-status Report
  • [Presentation] 重水素置換したX[Pd(dmit)2]2の低温熱容量2013

    • Author(s)
      山下智史,福岡脩平,中澤康浩,上田康平,崔亨波,山本浩史,加藤礼三
    • Organizer
      2013年日本物理学会秋季大会
    • Place of Presentation
      徳島
    • Related Report
      2013 Research-status Report
  • [Presentation] X[Pd(dmit)2]2系における量子スピン液体-電荷秩序近傍の低温熱挙動2013

    • Author(s)
      山下智史,福岡脩平,中澤康浩,上田康平,崔亨波,山本浩史,加藤礼三
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      東広島
    • Related Report
      2012 Research-status Report
  • [Presentation] Thermodynamic Study of Chemical Pressure Effet on Quantum Spin Liquid2012

    • Author(s)
      S. Yamashita, S. Fukuoka, Y. Nakazawa K. Ueda, H. M. Yamamoto, and R. Kato
    • Organizer
      The 15th International Congress on Thermal Analysis and Calorimetry (ICTAC15) & the 48th Japanese Conference on Calorimetry and Thermal Analysis (JCCTA48)
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Fermi Liquid Character of Organic Spin Liquid in X[Pd(dmit)2]2 System2012

    • Author(s)
      S. Yamashita
    • Organizer
      KITP Conference 2012 Exotic Phases in Frustrated Magnets
    • Place of Presentation
      Santa Barbara, USA
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Thermodynamic Properties of the Spin-Liquid State in Dimer-Mott Systems2012

    • Author(s)
      S. Yamashita, Y. Nakazawa, and R. Kato
    • Organizer
      International Symposium on Materials Science Openes by Molecular Degrees of Freedom (MDF2012)
    • Place of Presentation
      Miyazaki Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Et2Me2AsxSb1-x[Pd(dmit)2]2におけるギャップレスな量子スピン液体2012

    • Author(s)
      山下智史,福岡脩平,中澤康浩,上田康平,山本浩史,加藤礼三
    • Organizer
      日本物理学会2012 秋季大会
    • Place of Presentation
      横浜
    • Related Report
      2012 Research-status Report
  • [Remarks] 阪大化学熱学レポート

    • URL

      http://www.chem.sci.osaka-u.ac.jp/lab/micro/report/rcst/index.html.ja

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2013-05-31   Modified: 2020-05-15  

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