Investigation on the genesis of clathrasil minerals containing natural gases

• Project/Area Number: 24740359
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Petrology/Mineralogy/Science of ore deposit
• Research Institution: National Museum of Nature and Science, Tokyo
• Principal Investigator: MOMMA Koichi 独立行政法人国立科学博物館, 地学研究部, 研究員 (30552781)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000); Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
• Keywords: シリカ鉱物 / クラスレート / 炭素循環 / クラスラシル / 結晶構造

Outline of Final Research Achievements

Clathrasil minerals are a very rare type of silica minerals that contain natural gases in their crystal structures. We aimed at elucidating crystal-chemical properties of natural clathrasil minerals and their genesis.
In addition to two species of clathrasil minerals, melanophlogite and chibaite, we found another new clathrasil mineral, bosoite, which was approved as a new mineral by the Commission on New Minerals, Nomenclature and Classification (CNMNC) of the International Mineralogical Association (IMA). We also discovered world's second occurrence of chibaite from Nagano Prefecture.

Research Products

• [Journal Article] Growth history and textures of quartz twinned in accordance with the Japan law (2015)
  • Author(s): K. Momma, T. Nagase, T. Kuribayashi, and Y. Kudoh
  • Journal Title: Eur. J. Mineral. Volume: 27 Issue: 1 Pages: 71-80
  • DOI: 10.1127/ejm/2014/0026-2411
  • Peer Reviewed / Open Access
• [Journal Article] Magnesiorowlandite–(Y), Y₄(Mg,Fe)(Si₂O₇)₂F₂, a new mineral in a pegmatite at Souri Valley, Komono, Mie Prefecture, central Japan (2014)
  • Author(s): S. Matsubara, R. Miyawaki, K. Yokoyama, M. Shigeoka, K. Momma and S. Yamamoto
  • Journal Title: Journal of Mineralogical and Petrological Sciences Volume: 109 Issue: 3 Pages: 109-117
  • DOI: 10.2465/jmps.131126
  • NAID: 130003392378
  • ISSN: 1345-6296, 1349-3825
  • Peer Reviewed
• [Journal Article] Crystal structure of suzukiite from the Mogurazawa mine, Gunma Prefecture, Japan (2014)
  • Author(s): Ito M., S. Matsubara, K. Yokoyama, K. Momma, R. Miyawaki, I. Nakai and A. Kato
  • Journal Title: Journal of Mineralogical and Petrological Sciences Volume: 109 Issue: 5 Pages: 222-227
  • DOI: 10.2465/jmps.140520
  • NAID: 130004704869
  • ISSN: 1345-6296, 1349-3825
  • Peer Reviewed
• [Journal Article] Encapsulation kinetics and dynamics of carbon monoxide in clathrate hydrate (2014)
  • Author(s): J. Zhu, S. Du, X. Yu, J. Zhang, H. Xu, S. C. Vogel, T. C. Germann, J. S. Francisco, F. Izumi, K. Momma, Y. Kawamura, C. Jin and Y. Zhao
  • Journal Title: Nature Communications Volume: 5 Issue: 1 Pages: 4128-4128
  • DOI: 10.1038/ncomms5128
  • Peer Reviewed / Open Access
• [Journal Article] Dissolution behavior of vaterite spherulite in solutions containing phosphate ions (2014)
  • Author(s): Y. Sugiura, K. Onuma, M. Nagao, K. Momma, and Y. Kimura
  • Journal Title: Journal of the Ceramic Society of Japan Volume: 122 Issue: 1428 Pages: 679-687
  • DOI: 10.2109/jcersj2.122.679
  • NAID: 130004951001
  • ISSN: 1348-6535, 1882-0743
  • Peer Reviewed
• [Journal Article] Clathrate compound of silica (2014)
  • Author(s): K. Momma
  • Journal Title: Journal of Physics: Condensed Matter Volume: 26 Issue: 10 Pages: 103203-103203
  • DOI: 10.1088/0953-8984/26/10/103203
  • Peer Reviewed
• [Journal Article] Dysnomia, a computer program for maximum-entropy method (MEM) analysis and its performance in the MEM-based pattern fitting (2013)
  • Author(s): K. Momma, T. Ikeda, A. A. Belik and F. Izumi
  • Journal Title: Powder Diffraction Volume: 28 Issue: 3 Pages: 184-193
  • DOI: 10.1017/s088571561300002x
  • Peer Reviewed
• [Journal Article] Nuclear and charge density distributions in ferroelectric PbTiO3: maximum entropy method analysis of neutron and X-ray diffraction data (2013)
  • Author(s): J. Zhu, W. Han, J. Zhang, H. Xu, S. C. Vogel, C. Jin, F. Izumi, K. Momma, Y. Kawamura and Y. Zhao
  • Journal Title: Powder Diffraction Volume: 28 Issue: 4 Pages: 276-280
  • DOI: 10.1017/s0885715613000675
  • Peer Reviewed
• [Journal Article] Texture of lutecite (2013)
  • Author(s): T. Nagase, K. Momma, T. Kuribayashi and M. Tanaka
  • Journal Title: Journal of Mineralogical and Petrological Sciences Volume: 108 Issue: 2 Pages: 87-93
  • DOI: 10.2465/jmps.111017
  • NAID: 10031158587
  • ISSN: 1345-6296, 1349-3825
  • Peer Reviewed
• [Journal Article] Minohlite, a new copper-zinc sulfate mineral from Minoh, Osaka, Japan. (2013)
  • Author(s): Ohnishi, M., Shimobayashi, N., Nishio-Hamane, D., Shinoda, K., Momma, K. and Ikeda, T.
  • Journal Title: Mineralogical Magazine Volume: 77 Issue: 3 Pages: 335-342
  • DOI: 10.1180/minmag.2013.077.3.07
  • Peer Reviewed
• [Journal Article] Anisotropic garnet from the Yamansu ore deposit, Xinjiang, China (2013)
  • Author(s): S. Kobayashi, R. Miyawaki, K. Monnma, A. Fujisawa and H. Kaneda
  • Journal Title: Journal of Mineralogical and Petrological Sciences Volume: 108 Issue: 5 Pages: 245-254
  • DOI: 10.2465/jmps.120927
  • NAID: 10031203394
  • ISSN: 1345-6296, 1349-3825
  • Peer Reviewed
• [Journal Article] Pyrochlore and microlite in a pegmatite at Atagoyama, Koriyama City, Fukushima Prefecture, Japan (2013)
  • Author(s): . Matsubara, R. Miyawaki, K. Yokoyama, K. Momma, M. Shigeoka and E. Hashimoto
  • Journal Title: Bulletin of the National Museum of Nature and Science, Series C Volume: 39 Pages: 1-6
  • Peer Reviewed
• [Journal Article] 粉末回折データのMEM解析・三次元可視化用ソフトウェアの開発 (2013)
  • Author(s): 河村幸彦, 門馬綱一, 泉富士夫
  • Journal Title: 波紋 Volume: 23 Pages: 66-71
  • NAID: 130007510497
  • Peer Reviewed
• [Journal Article] Shimazakiite-4M and shimazakiite-4O, Ca2B2O5, two polytypes of a new mineral from Fuka, Okayama Prefecture, Japan (2013)
  • Author(s): I.Kusahi, S.Kobayashi, Y.Takechi, Y.Nakamuta, T.Nagase, K.Yokoyama, K.Momma, R.Miyawaki, M.Shigeoka and S.Matsubara
  • Journal Title: Mineralogical Magazine Volume: 77 Issue: 1 Pages: 93-105
  • DOI: 10.1180/minmag.2013.077.1.09
  • Peer Reviewed
• [Journal Article] Chevkinite-(Ce) in tuff at Heguri, Boso Peninsula, Chiba Prefecture, Japan (2012)
  • Author(s): Miyawaki, R., S. Matsubara, K. Yokoyama, K. Momma, T. Sano, Y. Tsutsumi, M. Shigeoka and K. Nishikubo
  • Journal Title: Bulletin of the National Museum of Nature and Science, Series C Volume: 38 Pages: 7-13
  • Peer Reviewed
• [Journal Article] LA-ICP-MS and SHRIMP ages of zircons in chevkinite and monazite tuffs from the Boso Peninsula, Central Japan (2012)
  • Author(s): Tsutsumi, Y., K. Horie, T. Sano, R. Miyawaki, K. Momma, S. Matsubara, M. Shigeoka and K. Yokoyama
  • Journal Title: Bulletin of the National Museum of Nature and Science, Series C Volume: 38 Pages: 15-32
  • Peer Reviewed
• [Journal Article] Experimental visualization of lithium conduction pathways in garnet-type Li7La3Zr2O12 (2012)
  • Author(s): Han, J., J. Zhu, Y. Li, X. Yu, S. Wang, G. Wu, H. Xie, S. C. Vogel, F. Izumi, K. Momma, Y. Kawamura, Y. Huang, J. B. Goodenough and Y. Zhao
  • Journal Title: Chemical Communications Volume: 48 Issue: 79 Pages: 9840-9842
  • DOI: 10.1039/c2cc35089k
  • Peer Reviewed
• [Journal Article] シリカクラスレートの結晶構造 (2012)
  • Author(s): 門馬綱一
  • Journal Title: セラミックス Volume: 47 Pages: 361-366
  • NAID: 10031155545
• [Journal Article] 次世代三次元可視化プログラムVESTA 3 (2012)
  • Author(s): 門馬綱一, 泉富士夫
  • Journal Title: 日本結晶学会誌 Volume: 54 Pages: 119-120
  • NAID: 10030631996
• [Presentation] VESTAにおける磁気空間群への対応と磁気構造の可視化 (2014)
  • Author(s): 門馬綱一
  • Organizer: 平成26年度日本結晶学会年会
  • Place of Presentation: 東京大学（文京区）
  • Year and Date: 2014-11-01 – 2014-11-03
• [Presentation] 新鉱物 房総石(bosoite) (2014)
  • Author(s): 門馬 綱一・池田卓史・長瀬敏郎・栗林貴弘・本間 千舟・西久保勝己・高橋直樹・高田雅介・松下能孝・宮脇律郎・松原 聰
  • Organizer: 日本鉱物科学会2014年年会
  • Place of Presentation: 熊本大学（熊本）
  • Year and Date: 2014-09-17 – 2014-09-19
• [Presentation] 埼玉県小松鉱山産含バナジウムパンペリー石族鉱物 (2014)
  • Author(s): 山田 隆・門馬綱一・宮脇律郎・松原 聰・石橋 隆・藤原 卓・滝沢 実
  • Organizer: 日本鉱物科学会2014年年会
  • Place of Presentation: 熊本大学（熊本）
  • Year and Date: 2014-09-17 – 2014-09-19
• [Presentation] 新鉱物 伊予石/Iyoite & 三崎石/Misakiite (2014)
  • Author(s): 浜根大輔・門馬綱一・大西政之・下林典正・宮脇律郎・冨田宣光・皆川鉄雄
  • Organizer: 日本鉱物科学会2014年年会
  • Place of Presentation: 熊本大学（熊本）
  • Year and Date: 2014-09-17 – 2014-09-19
• [Presentation] 新鉱物 今吉石/Imayoshiite (2014)
  • Author(s): 浜根大輔・大西政之・門馬綱一・下林典正・宮脇律郎・皆川鉄雄・稲葉幸郎
  • Organizer: 日本鉱物科学会2014年年会
  • Place of Presentation: 熊本大学（熊本）
  • Year and Date: 2014-09-17 – 2014-09-19
• [Presentation] Crystal chemistry of a silica clathrate mineral that is isostructural with the structure H gas hydrate (2014)
  • Author(s): K. Momma, T. Ikeda, T. Nagase, T. Kuribayashi, C. Honma, K. Nishikubo, N. Takahashi, M. Takada, Y. Matsushita, R. Miyawaki, S. Matsubara
  • Organizer: 21st General Meeting of International Mineralogical Association
  • Place of Presentation: 南アフリカ ヨハネスブルク
  • Year and Date: 2014-09-01 – 2014-09-05
• [Presentation] CO3-bearing apatite-ellestadite series mineral from Japan (2014)
  • Author(s): Y. Banno, R. Miyawaki, K. Momma, M. Bunno
  • Organizer: 21st General Meeting of International Mineralogical Association
  • Place of Presentation: 南アフリカ ヨハネスブルク
  • Year and Date: 2014-09-01 – 2014-09-05
• [Presentation] The crystal structures of kimuraite-(Y) and lokkaite-(Y) (2014)
  • Author(s): R. Miyawaki, K. Momma, S. Matsubara, T. Tahara, I. Nakai
  • Organizer: 21st General Meeting of International Mineralogical Association
  • Place of Presentation: 南アフリカ ヨハネスブルク
  • Year and Date: 2014-09-01 – 2014-09-05
• [Presentation] Crystallographic examination of tsugaruite (2014)
  • Author(s): Y. Matsushita, K. Momma, R. Miyawaki, A. Sato, M. Kaise, H. Kitazawa
  • Organizer: 21st General Meeting of International Mineralogical Association
  • Place of Presentation: 南アフリカ ヨハネスブルク
  • Year and Date: 2014-09-01 – 2014-09-05
• [Presentation] シリカクラスレートの単結晶X線回折実験 (2013)
  • Author(s): 門馬綱一, 宮脇律郎, 栗林貴弘, 長瀬敏郎
  • Organizer: 第1回物構研サイエンスフェスタ
  • Place of Presentation: つくば
• [Presentation] The Crystal Structures of Potassium Tetra Silicic Fluoro Micas (K-TSFMs) (2013)
  • Author(s): R. Miyawaki, K. Momma, M. Shigeoka, K. Yokoyama, Y. Tsutsumi, S. Matsubara, M. Okubeb, A. Yoshiasa, S. Ohta
  • Organizer: 第1回物構研サイエンスフェスタ
  • Place of Presentation: つくば
• [Presentation] 希土類炭酸塩鉱物、木村石の結晶構造 (2013)
  • Author(s): 宮脇律郎・門馬綱一・田原岳史・中井 泉・松原 聰
  • Organizer: 第30回希土類討論会
  • Place of Presentation: 北九州
• [Presentation] Dysnomia と VESTA による電子密度の可視化 (2013)
  • Author(s): 門馬綱一
  • Organizer: 日本セラミックス協会第 26 回秋季シンポジウム
  • Place of Presentation: 長野
  • Invited
• [Presentation] 北部フォッサマグナ地域から産出した千葉石 (2013)
  • Author(s): 門馬綱一・宮島 宏・下林典正・石橋 隆・高山信之・長瀬敏郎・宮脇律郎・松原 聰
  • Organizer: 日本鉱物科学会2013年年会
  • Place of Presentation: つくば
• [Presentation] 鹿児島県大和鉱山産medaiteおよびsaneroite (2013)
  • Author(s): 松原 聰・宮脇律郎・門馬綱一・重岡昌子・伊藤 剛・高橋 秀介
  • Organizer: 日本鉱物科学会2013年年会
  • Place of Presentation: つくば
• [Presentation] 福島県多田野産のSiとSに富む燐灰石の化学組成 (2013)
  • Author(s): 坂野靖行・宮脇律郎・門馬綱一・豊 遙秋
  • Organizer: 日本鉱物科学会2013年年会
  • Place of Presentation: つくば
• [Presentation] 木村石とロッカ石の結晶構造 (2013)
  • Author(s): 宮脇律郎・門馬綱一・松原 聰・田原岳史・中井 泉
  • Organizer: 日本鉱物科学会2013年年会
  • Place of Presentation: つくば
• [Presentation] カリウム四ケイ素フッ素雲母(K-TSFM）の結晶構造（第2 報） (2013)
  • Author(s): 宮脇律郎・門馬綱一・奥部真樹・吉朝 朗・太田俊一
  • Organizer: 第57回粘土科学討論会
  • Place of Presentation: 高知
• [Presentation] Silica clathrate minerals from Boso Peninsula, Japan (2012)
  • Author(s): Momma, K., T. Ikeda, T. Nagase, N. Takahashi, M. Takada, K. Nishikubo, C. Honma, M. Koda, Y. Furukawa, R. Miyawaki and S. Matsubara
  • Organizer: 7th International Conference on Mineralogy and Museums
  • Place of Presentation: Dresden
• [Presentation] Mg-analogue of rowlandite-(Y) and yftisite from Suzuka granite, Mie Prefecture, Japan (2012)
  • Author(s): Matsubara, S., R. Miyawaki, K. Momma, K. Yokoyama and S. Yamamoto
  • Organizer: 7th International Conference on Mineralogy and Museums
  • Place of Presentation: Dresden
• [Presentation] We, NMNS, have moved! (2012)
  • Author(s): Uchio, Y., R. Miyawaki, K. Momma and S. Matsubara
  • Organizer: 7th International Conference on Mineralogy and Museums
  • Place of Presentation: Dresden
• [Presentation] The crystal structures of potassium tetra silicic fluoro micas (K-TSFMs) (2012)
  • Author(s): Miyawaki, R., K. Momma, M. Shigeoka, K. Yokoyama, Y. Tsutsumi, M. Okube, A. Yoshiasa, S. Ohta and S. Matsubara
  • Organizer: 2nd Asian Clay
  • Place of Presentation: Seoul
• [Presentation] Temperature dependence of local structure change in lithium peroxide (2012)
  • Author(s): Y. Matsushita, K. Momma, Y. Kubo, Y. Katsuya, and M. Tanaka
  • Organizer: The 27th European Crystallographic Meeting
  • Place of Presentation: Bergen
• [Presentation] 天然ガスを含むシリカ鉱物「千葉石」：Chibaite, a new silica mineral containing natural gas molecules (2012)
  • Author(s): 門馬綱一
  • Organizer: 第25回DV-Xα研究会
  • Place of Presentation: 福岡
  • Invited
• [Presentation] 島崎石(shimazakiite)のポリタイプの結晶構造 (2012)
  • Author(s): 門馬綱一・草地功・小林祥一・武智泰史・中牟田義博・長瀬敏郎・横山一己・宮脇律郎・重岡昌子・松原聰
  • Organizer: 日本鉱物科学会2012年年会
  • Place of Presentation: 京都
• [Presentation] DOH 型シリカクラスレート鉱物の結晶構造 (2012)
  • Author(s): 門馬綱一・池田卓史・長瀬敏郎・栗林貴弘・高橋直樹・本間千舟・西久保勝己・宮脇律郎・松原聰
  • Organizer: 平成24年度日本結晶学会年会
  • Place of Presentation: 仙台
• [Presentation] 三重県菰野町産rowlandite-(Y)のMg 置換体とyftisite (2012)
  • Author(s): 松原聰・宮脇律郎・門馬綱一・横山一己・重岡昌子・山本貞興
  • Organizer: 第29 回希土類討論会
  • Place of Presentation: 札幌
• [Presentation] 福島県郡山市愛宕山産花崗岩ペグマタイト中の含ウラン・トリウム鉱物 (2012)
  • Author(s): 松原聰・宮脇律郎・横山一己・門馬綱一・重岡昌子・橋本悦雄
  • Organizer: 日本鉱物科学会2012年年会
  • Place of Presentation: 仙台
• [Presentation] 三重県菰野町産、苦土ローランド石とイフティス石の結晶構造 (2012)
  • Author(s): 宮脇律郎・門馬綱一・松原聰・横山一己・重岡昌子・山本貞興，2012.
  • Organizer: 日本鉱物科学会2012年年会
  • Place of Presentation: 京都
• [Presentation] 群馬県茂倉沢産の鈴木石の結晶構造 (2012)
  • Author(s): 伊藤美久・中井泉・宮脇律郎・門馬綱一・松原聰・横山一己・加藤昭
  • Organizer: 日本鉱物科学会2012年年会
  • Place of Presentation: 京都
• [Book] 教授を魅了した大地の結晶―北川隆司鉱物コレクション200選 (2013)
  • Author(s): 北川ふさえ，地下まゆみ，吉富健一，小笠原洋，門馬綱一，宮脇律郎. 松原聰監修
  • Total Pages: 118
  • Publisher: 東海大出版会
• [Book] KOUBUTSU BOOK: 飾って、眺めて、知って。鉱物のあるインテリア (2013)
  • Author(s): 門馬綱一 監修
  • Total Pages: 126
  • Publisher: ビー・エヌ・エヌ新社