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Intrinsic mechanism of electronic/ionic conduction at the electrolyte/electrode by epitaxial films

Research Project

Project/Area Number 24750005
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Physical chemistry
Research InstitutionTohoku University

Principal Investigator

KUMATANI Akichika  東北大学, 大学院環境科学研究科, 産官学連携研究員 (50568433)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2012: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywords物理化学 / エピタキシャル薄膜 / 薄膜電池 / リチウムイオン二次電池 / イオン伝導 / 電気化学 / 固体イオニクス / リチウムイオン電池
Research Abstract

The studies on the intrinsic electron/ion transport at the electrode/electrolyte in the lithium-ion batteries were carried out by using epitaxial thin films. Epitaxial growth was an ideal fabrication technique, which allows us to control the crystal orientation and grain boundaries precisely, for revealing those transport. It is unveiled that one of bottlenecks in the practical electronic and ionic transport was grain boundaries by elucidation of electrical / electrochemical measurements for each transport in the epitaxial films independently. The information obtained in this study will become an important feedback for electrodes and electrolytes, leading the creation of high performance lithium-ion batteries.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (31 results)

All 2014 2013 2012 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (26 results) Remarks (3 results)

  • [Journal Article] Epitaxial growth of Li4Ti5O12 thin films using RF magnetron sputtering2014

    • Author(s)
      A. Kumatani, S. Shiraki, Y. Takagi, T. Suzuki, T. Ohsawa, X. Gao, Y. Ikuhara, T. Hitosugi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 5 Pages: 123103-123103

    • DOI

      10.7567/jjap.53.058001

    • NAID

      210000143760

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Design of an effective vibration isolation system for measurements sensitive to low-frequency vibrations2012

    • Author(s)
      Katsuya Iwaya, Ryota Shimizu, Akira Teramura, Seiji Sasaki, Toru Itagaki, and Taro Hitosugi
    • Journal Title

      Applied physics Letters

      Volume: 101 Issue: 12 Pages: 123103-123106

    • DOI

      10.1063/1.4752466

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 界面イオン伝導顕微鏡による多結晶電極表面の結晶構造とLi挿入脱離の相関性の検討2014

    • Author(s)
      熊谷明哉, 高橋康史, 猪又宏貴, 白木将, 山本邦子, 春田正和, 伊野浩介, 珠玖仁, 一杉太郎, 末永智一
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西大学
    • Related Report
      2013 Final Research Report
  • [Presentation] 界面イオン伝導顕微鏡の創製とLiイオン電池電極材料への応用2014

    • Author(s)
      熊谷明哉, 高橋康史, 猪又宏貴, 棟方裕一, 伊野浩介, 珠玖仁, 金村聖志, 末永智一
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学
    • Related Report
      2013 Final Research Report
  • [Presentation] 界面イオン伝導顕微鏡の創製とLiイオン電池電極材料への応用2014

    • Author(s)
      熊谷明哉, 高橋康史, 猪又宏貴, 棟方裕一, 伊野浩介, 珠玖仁, 金村聖志, 末永智一
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学(神奈川)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 界面イオン伝導顕微鏡による多結晶電極表面の結晶構造とLi挿入脱離の相関性の検討2014

    • Author(s)
      熊谷明哉, 高橋康史, 猪又宏貴, 白木将, 山本邦子, 春田正和, 伊野浩介, 珠玖仁, 一杉太郎, 末永智一
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西学院大学(大阪)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 界面イオン伝導顕微鏡による電極材料表面におけるLi挿入脱離の可視化2013

    • Author(s)
      熊谷明哉, 高橋康史, 棟方裕一, 猪又宏貴, 伊野浩介, 珠玖仁, 金村聖志, 末永智一
    • Organizer
      第54回電池討論会
    • Place of Presentation
      大阪
    • Related Report
      2013 Final Research Report
  • [Presentation] In-situ characterization and mapping of lithium-ion transport at the electrolyte/cathode interface by high resolution ion-conductance microscopy2013

    • Author(s)
      A. Kumatani, Y. Takahashi, H. Munakata, H. Inomata, K. Ino, H. Shiku, K. Kanamura, T. Matsue
    • Organizer
      EMRS fall meeting 2013
    • Place of Presentation
      Warsaw, Poland
    • Related Report
      2013 Final Research Report
  • [Presentation] 固体電解質Li3PO4-xNx(LiPON)薄膜作製条件の検討2013

    • Author(s)
      熊谷明哉, 清水亮太, 大澤健男, 鈴木竜, 白木将, 一杉太郎
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Related Report
      2013 Final Research Report
  • [Presentation] PLD法を用いたリチウムイオン電池正極・負極材料のエピタキシャル薄膜作製に関する考察2013

    • Author(s)
      白木将, 熊谷明哉, 高木由貴, 大木栄幹, 清水亮太, 鈴木竜, 大澤健男, 一杉太郎
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Related Report
      2013 Final Research Report
  • [Presentation] LiTi2O4透明超伝導エピタキシャル薄膜の電子状態評価2013

    • Author(s)
      大澤健男, 熊谷明哉, 清水亮太, 高木由貴, 鈴木竜, 白木将, 一杉太郎
    • Organizer
      第60回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Related Report
      2013 Final Research Report
  • [Presentation] LiTi2O4 epitaxial thin films : A transparent superconductor2013

    • Author(s)
      A. Kumatani, T. Ohsawa, R. Shimizu, Y. Takagi, S. Shiraki, T. Hitosugi
    • Organizer
      The AIMR International Symposium 2013 (AMIS2013)
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] In-situ characterization and mapping of lithium-ion transport at the electrolyte/cathode interface by high resolution ion-conductance microscopy2013

    • Author(s)
      A. Kumatani, Y. Takahashi, H. Munakata, H. Inomata, K. Ino, H. Shiku, K. Kanamura, T. Matsue
    • Organizer
      E-MRS 2013 Fall Meeting
    • Place of Presentation
      ワルシャワ(ポーランド)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 界面イオン伝導顕微鏡による電極材料表面におけるLi挿入脱離の可視化2013

    • Author(s)
      熊谷明哉, 高橋康史, 棟方裕一, 猪又宏貴, 伊野浩介, 珠玖仁, 金村聖志, 末永智一
    • Organizer
      第54回電池討論会
    • Place of Presentation
      大阪国際会議場(大阪)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 固体電解質Li3PO4-xNx(LiPON)薄膜作製条件の検討2013

    • Author(s)
      熊谷明哉,清水亮太,大澤健男,鈴木竜,白木将,一杉太郎
    • Organizer
      第60回応用物理学春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Research-status Report
  • [Presentation] LiTi2O4 epitaxial films: A transparent superconductor2013

    • Author(s)
      A. Kumatani, T. Ohsawa, R. Shimizu, Y. Takagi, S. Shiraki, T. Hitosugi
    • Organizer
      The AIMR International Symposium 2013 (AMIS2013)
    • Place of Presentation
      Sendai, Miyagi, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] LiTi2O4 透明超伝導エピタキシャル薄膜の電子状態評価2013

    • Author(s)
      大澤健男,熊谷明哉,清水亮太,高木由貴,鈴木竜,白木將,一杉太郎
    • Organizer
      第60回応用物理学春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Research-status Report
  • [Presentation] PLD法を用いたリチウムイオン電池正極・負極材料のエピタキシャル薄膜作製に関する考察2013

    • Author(s)
      白木将,熊谷明哉,高木由貴,大木栄幹,清水亮太,鈴木竜,大澤健男,一杉太郎
    • Organizer
      第60回応用物理学春季学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Research-status Report
  • [Presentation] LiCoO2エピタキシャル薄膜内の結晶粒界の界面抵抗の定量化2012

    • Author(s)
      熊谷明哉, 大澤健男, 清水亮太, 鈴木竜, 高木由貴, 白木将, 森分博紀, 幾原雄一, 一杉太郎
    • Organizer
      第38回固体イオニクス討論会
    • Place of Presentation
      京都
    • Related Report
      2013 Final Research Report
  • [Presentation] PLD法を用いたリチウムイオン電池正極・負極材料のエピタキシャル薄膜作製に関する考察2012

    • Author(s)
      白木将, 熊谷明哉, 高木由貴, 大木栄幹, 清水亮太, 鈴木竜, 大澤健男, 一杉太郎
    • Organizer
      第53回電池討論会
    • Place of Presentation
      福岡
    • Related Report
      2013 Final Research Report
  • [Presentation] チタン酸リチウムエピタキシャル薄膜作製条件の検討2012

    • Author(s)
      熊谷明哉, 清水亮太, 高木由貴, 大澤健男, 鈴木竜, 白木将, 一杉太郎
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛
    • Related Report
      2013 Final Research Report
  • [Presentation] Interface resistance at the single grain boundary of LiCoO2 epitaxial thin films2012

    • Author(s)
      A. Kumatani, T. Ohsawa, R. Shimizu, T. Suzuki, Y. Takagi, S. Shiraki, H. Oki, H. Moriwake, Y. Ikuhara, T. Hitosugi
    • Organizer
      13th Asian Conference on Solid State Ionics
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Deposition of lithium taitanate epitaxial thin films using pulsed laser deposition2012

    • Author(s)
      S. Shiraki, A. Kumatani, Y. Takagi, T. Suzuki, H. Oki, T. Ohsawa, T. Hitosugi
    • Organizer
      13th Asian Conference on Solid State Ionics
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] LiCoO2エピタキシャル薄膜内の結晶粒界の界面抵抗の定量化2012

    • Author(s)
      熊谷明哉、大澤健男、清水亮太、鈴木竜、高木由貴、白木将、森分博紀、幾原 雄一、一杉太郎
    • Organizer
      第38回固体イオニクス討論会
    • Place of Presentation
      京都テルサ
    • Related Report
      2012 Research-status Report
  • [Presentation] チタン酸リチウムエピタキシャル薄膜作製条件の検討2012

    • Author(s)
      熊谷明哉、清水亮太、高木由貴、大澤健男、鈴木竜、白木将、一杉太郎
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Interface resistance at the single grain boundary of LiCoO2 epitaxial thin films2012

    • Author(s)
      A. Kumatani, T. Ohsawa, R. Shimizu, T. Suzuki, Y. Takagi, S. Shiraki, H. Oki, H. Moriwake, Y. Ikuhara, T. Hitosugi
    • Organizer
      13th Asian Conference on Solid State Ionics (ACSSI-2012)
    • Place of Presentation
      東北大学
    • Related Report
      2012 Research-status Report
  • [Presentation] PLD法を用いたリチウムイオン電池正極・負極材料のエピタキシャル薄膜作製に関する考察2012

    • Author(s)
      白木将,熊谷明哉,高木由貴,大木栄幹,清水亮太,鈴木竜,大澤健男,一杉太郎
    • Organizer
      第53回電池討論会
    • Place of Presentation
      ヒルトン福岡シーホーク
    • Related Report
      2012 Research-status Report
  • [Presentation] Deposition of lithium taitanate epitaxial thin flims using pulsed laser deposition2012

    • Author(s)
      S. Shiraki, A. Kumatani, Y. Takagi, T. Suzuki, H. Oki, T. Ohsawa, T. Hitosugi
    • Organizer
      13th Asian Conference on Solid State Ionics (ACSSI-2012)
    • Place of Presentation
      東北大学
    • Related Report
      2012 Research-status Report
  • [Remarks] 研究室ホームページ

    • URL

      http://www.che.tohoku.ac.jp/~bioinfo/

    • Related Report
      2013 Final Research Report
  • [Remarks] 熊谷明哉研究員と一杉太郎准教授の研究グループ 透明超伝導体の転移温度で、世界記録を更新

    • URL

      http://www.wpi-aimr.tohoku.ac.jp/jp/news/press/2012/20120919_000300.html

    • Related Report
      2012 Research-status Report
  • [Remarks] 透明超伝導体の転移温度で、世界記録を更新

    • URL

      http://www.tohoku.ac.jp/japanese/2012/09/press20120914-01.html

    • Related Report
      2012 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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