| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Outline of Final Research Achievements |
The basic principles and experimental techniques of two-dimensional analysis by NMR relaxation and diffusion are develped. A compulational program for Laplace-Laplace inversion using singular value decomposition was newly released, and verified stability on various NMR experimental parameters such as signal-to-noise ratio and sampling points. We applied relaxation-diffusion methodology to charcterize water in polymer exchange membranes with different relative humidity. At 30% RH, the diffusion coefficient of water in small-sized channels is greater than that in large-sized channels. On the other hand, the diffusion coefficients of protons with smaller and larger water channels are almost the same at 50, 70, and 90% RH.
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