| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Outline of Final Research Achievements |
This work is a development of transformations by oxidation of inorganic halide ( particularly alkali metal halides), and a halonium ion intermediate generated via oxidation of halide ion promotes the halogenation and oxidation of organic compounds. It is known that the transformation proceeds by the enzyme in the marine algae, therefore this methodology develops as an enzyme-mimic transformation. We found out various reaction via oxidation of halides can be applied as an organic halogen reagent- and heavy metal-substituted reactions.
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