Development of Rare-Earth Catalyzed Regioselective Functionalization of C-H Bonds
Project/Area Number |
24750046
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Multi-year Fund |
Research Field |
Organic chemistry
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Research Institution | Institute of Physical and Chemical Research |
Principal Investigator |
OYAMADA Juzo 独立行政法人理化学研究所, 環境資源科学研究センター, 特別研究員 (60525393)
|
Project Period (FY) |
2012-04-01 – 2014-03-31
|
Project Status |
Completed (Fiscal Year 2013)
|
Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
|
Keywords | 希土類錯体 / C-H結合活性化 / アルキル化 / アニソール / アニリン / N,N-ジアルキルアニリン / オレフィン / 希土類アルキル錯体 |
Research Abstract |
Ortho-selective alkylation of anisoles has been achieved by use of cationic rare-earth alkyl complexes as catalysts. Similarly, 2-methylanisoles underwent ortho-selective benzylic alkylation. These catalysts could also be applied to ortho-selective alkyaltion of N,N-dialkylanilines, alkylation at a N-methyl group of N-methylamines and benzylic alkylation of methylbenzenes.
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Report
(3 results)
Research Products
(3 results)