Research on a nano-size effect of luminescent metal-complex assembly
| Project/Area Number |
24750049
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Hokkaido University |
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Principal Investigator |
KOBAYASHI Atsushi 北海道大学, 理学(系)研究科(研究院), 講師 (50437753)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Keywords | ナノ材料 / 配位高分子 / 発光 / 光化学 / 光物性 / クロミズム |
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| Research Abstract |
The purpose of this project is to create a new photofunctional coordination polymer system composed of luminescent metalloligand in mesoscopic region where several unique properties based on the quantum confinement effect are well known. We successfully synthesized new coordination polymers composed of well-known photosensitizer, Ru(bpy)3 moiety, and found that the photosensitizing ability of the coordination polymer with ca. 100 nm diameter is remarkably higher than that of Ru(bpy)3 in the solution state or the bulk of coordination polymer.
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Report
(3 results)
Research Products
(24 results)
