| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Research Abstract |
The purpose of this project is to create a new photofunctional coordination polymer system composed of luminescent metalloligand in mesoscopic region where several unique properties based on the quantum confinement effect are well known. We successfully synthesized new coordination polymers composed of well-known photosensitizer, Ru(bpy)3 moiety, and found that the photosensitizing ability of the coordination polymer with ca. 100 nm diameter is remarkably higher than that of Ru(bpy)3 in the solution state or the bulk of coordination polymer.
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