Synthesis of pi-Coordinating Ligands and Development of Their Functionalities
| Project/Area Number |
24750085
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
OKAMOTO Kazuhiro 京都大学, 工学(系)研究科(研究院), 助教 (30552658)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | キレート配位子 / π配位 / アルキン / ホスフィン / 白金 / ロジウム / パラジウム / ルテニウム |
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| Research Abstract |
In this study, we have synthesized the dialkylplatinum(II) complexes from diarylacetylene molecules bearing a chelating unit in order to investigate the influence of the metal coordinationon the optical properties of them. As a result, the formation of the chelating complex without the coordination of the alkyne moiety and the zwitterionic platinacycle was observed. The optical response of them was also examined. These results obtained in this study have an opportunity for the creation of novel type of sensing molecules, and moreover, will become a basis for the materials fusing the pi-conjugate molecules and the metal complexes in a new manner.
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Report
(3 results)
Research Products
(6 results)
