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Synthesis of pi-Coordinating Ligands and Development of Their Functionalities

Research Project

Project/Area Number 24750085
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Synthetic chemistry
Research InstitutionKyoto University

Principal Investigator

OKAMOTO Kazuhiro  京都大学, 工学(系)研究科(研究院), 助教 (30552658)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2012: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsキレート配位子 / π配位 / アルキン / ホスフィン / 白金 / ロジウム / パラジウム / ルテニウム
Research Abstract

In this study, we have synthesized the dialkylplatinum(II) complexes from diarylacetylene molecules bearing a chelating unit in order to investigate the influence of the metal coordinationon the optical properties of them. As a result, the formation of the chelating complex without the coordination of the alkyne moiety and the zwitterionic platinacycle was observed. The optical response of them was also examined. These results obtained in this study have an opportunity for the creation of novel type of sensing molecules, and moreover, will become a basis for the materials fusing the pi-conjugate molecules and the metal complexes in a new manner.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (6 results)

All 2014 2012 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (3 results) Remarks (2 results)

  • [Journal Article] Alkyne-Coordinating Tridentate Ligands : Structural Properties and Reactivity of Their Rhodium Complexes2012

    • Author(s)
      Kazuhiro Okamoto, Yusuke Omoto, Hayato Sano, and Kouichi Ohe
    • Journal Title

      Dalton Trans.

      Volume: 41 Issue: 36 Pages: 10926-10929

    • DOI

      10.1039/c2dt31322g

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] アルキン含有キレート型配位子の白金(II)錯体の構造的/光学的特性2014

    • Author(s)
      岡本和紘, 舩坂怜司, 大江浩一
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] アルキンのπ配位を含むキレート型白金族錯体の構造と反応性2012

    • Author(s)
      岡本和紘, 佐野隼人, 尾本勇祐, 大江浩一
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山大学
    • Year and Date
      2012-09-21
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] アルキン含有キレート型配位子の白金(II)錯体の構造的/光学的特性

    • Author(s)
      岡本和紘・舩坂怜司・大江浩一
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.ehcc.kyoto-u.ac.jp/eh31/home/index-j.html

    • Related Report
      2013 Final Research Report
  • [Remarks] 大江研究室

    • URL

      http://www.ehcc.kyoto-u.ac.jp/eh31/home/index-j.html

    • Related Report
      2013 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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