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Development of liquid zwitterion-type lithium ion conductive polymers with controlled nano-structure

Research Project

Project/Area Number 24750112
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Polymer chemistry
Research InstitutionSophia University

Principal Investigator

FUJITA Masahiro  上智大学, 理工学部, 准教授 (50433793)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords機能性高分子 / 導電性高分子 / 双性イオン / 高分子電解質 / イオン液体 / リチウムイオン電池 / イオン伝導性高分子 / リチウムイオン伝導体 / ポリベタイン
Research Abstract

In order to develop novel lithium ion conductive polymers with high ion conductivity, copolymers composed of an oligoether monomer and a zwitterionic monomer were synthesized. In addition, the properties of liquid zwitteion/lithium salt composites were evaluated, and their lithium ion conductivity was investigated. The zwitterion moiety is a high polarity matrix that can dissociate a large amount of lithium salts into ion species. The electrochemical window of liquid zwitterion was about 5 V, which was enough value to be electrolytes for lithium ion batteries. Charge/discharge tests were conducted for the lithium ion batteries that were fabricated with polyether/liquid-zwitterion/lithium-salt composites, and a stable performance was observed.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (17 results)

All 2014 2013 2012 Other

All Presentation (16 results) (of which Invited: 2 results) Remarks (1 results)

  • [Presentation] 双性イオンの合成と電解質としての評価(I)-シアノ基の影響-2014

    • Author(s)
      山口征太郎, 藤田正博, 竹岡裕子, 陸川政弘
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2014-05-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 双性イオン液体の合成と評価(VI)-伝導機構の解析-2014

    • Author(s)
      末松三豪, 藤田正博, 竹岡裕子, 陸川政弘
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2014-05-29
    • Related Report
      2013 Final Research Report
  • [Presentation] Design of soft electrolytes as lithium ion transport materials2014

    • Author(s)
      M.Yoshizawa-Fujita
    • Organizer
      14^<th> International Symposium on Polymer Electrolytes
    • Place of Presentation
      Geelong, Australia
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Design of soft electrolytes as lithium ion transport materials2014

    • Author(s)
      Masahiro Yoshizawa-Fujita
    • Organizer
      14th International Symposium on Polymer Electrolytes
    • Place of Presentation
      Geelong, Australia
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 双性イオン液体の合成と評価(V)-添加剤としての効果-2013

    • Author(s)
      末松三豪, 藤田正博, 竹岡裕子, 陸川政弘
    • Organizer
      第4回イオン液体討論会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Year and Date
      2013-11-20
    • Related Report
      2013 Final Research Report
  • [Presentation] 双性イオン液体の合成と評価(IV)-PEOの効果-2013

    • Author(s)
      末松三豪, 藤田正博, 竹岡裕子, 陸川政弘
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学角間キャンパス
    • Year and Date
      2013-09-13
    • Related Report
      2013 Final Research Report
  • [Presentation] 双性イオン液体の合成と評価(III)-リチウム塩種の効果-2013

    • Author(s)
      末松三豪, 藤田正博, 竹岡裕子, 陸川政弘
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館
    • Year and Date
      2013-05-31
    • Related Report
      2013 Final Research Report
  • [Presentation] Effect of lithium salt species on electrochemical properties of liquid zwitterion2013

    • Author(s)
      M.Suematsu, M.Yoshizawa-Fujita, Y.Takeoka, and M.Rikuakwa
    • Organizer
      5^<th> International Congress on Ionic Liquids
    • Place of Presentation
      Algarve, Portugal
    • Year and Date
      2013-04-22
    • Related Report
      2013 Final Research Report
  • [Presentation] 双性イオン型高分子電解質の合成と評価(I)2012

    • Author(s)
      島田健佑, 藤田正博, 竹岡裕子, 陸川政弘
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2012-09-20
    • Related Report
      2013 Final Research Report
  • [Presentation] Effect of lithium salt species on electrochemical properties of liquid zwitterion

    • Author(s)
      Mitsutake Suematsu, Masahiro Yoshizawa-Fujita, Yuko Takeoka, Masahiro Rikukawa
    • Organizer
      5th Congress on Ionic Liquids
    • Place of Presentation
      Algarve, Portugal
    • Related Report
      2013 Annual Research Report 2012 Research-status Report
  • [Presentation] 双性イオン液体の合成と評価(III)-リチウム塩種の効果-

    • Author(s)
      末松三豪、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館
    • Related Report
      2013 Annual Research Report
  • [Presentation] 双性イオン液体の合成と評価(IV)-PEOの効果-

    • Author(s)
      末松三豪、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学角間キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] 双性イオン液体の合成と評価(V)-添加剤としての効果-

    • Author(s)
      末松三豪、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第4回イオン液体討論会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] 双性イオン液体の合成と評価(VI)-伝導機構の解析-

    • Author(s)
      末松三豪、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] 双性イオンの合成と電解質としての評価(I)-シアノ基の影響-

    • Author(s)
      山口征太郎、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] 双性イオン型高分子電解質の合成と評価(I)

    • Author(s)
      島田健佑、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://www.mls.sophia.ac.jp/~polymer/index.html

    • Related Report
      2013 Final Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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