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Development of zero-gap materials based on unsymmetrical metal complexes under ambient pressure

Research Project

Project/Area Number 24750118
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionHokkaido University

Principal Investigator

KUBO Kazuya  北海道大学, 電子科学研究所, 助教 (90391937)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords機能性材料 / 有機電子材料 / 複合材料・物性 / 分子性導体 / ゼロギャップ半導体
Research Abstract

Zero-gap materials such as a graphene are intensively studied because of their potentials for development of new electric devices. However, synthesis and physical measurements of the thin film of graphene are difficult. The zero gap material based on the bulk compound is realized by applying pressure to an organic conductor. Dirac corn type electronic states are observed in the zero-gap materials. In this work, the electronic state of the organic conductor crystals based on unsymmetrical metal-dhithiolene complexes, exhibiting the Dirac corn like electronic state were investigated by crystal structures and their physical properties.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (71 results)

All 2014 2013 2012 Other

All Journal Article (18 results) (of which Peer Reviewed: 18 results) Presentation (47 results) (of which Invited: 1 results) Book (3 results) Remarks (3 results)

  • [Journal Article] Design of Crystalline Spaces for Molecular Rotations in Crystals2014

    • Author(s)
      Zun-qi Liu, Kazuya Kubo, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Crystal Growth & Design

      Volume: 14 Pages: 537-543

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Finite Winding (H<sub>2</sub>O)<sub>12</sub> Chain Stabilized by One-Dimensional Coordination Polymer2014

    • Author(s)
      Shin-ichiro Noro, Kei Hasegawa, Kazuya Kubo, and Takayoshi Nakamura
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 87 Issue: 5 Pages: 623-625

    • DOI

      10.1246/bcsj.20140005

    • NAID

      130004153293

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure and Physical Property of Dithiolene Complex Crystal with Adamantane Supramolecular Rotator2013

    • Author(s)
      Yin-Nan Yan, Kazuya Kubo, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Bulletin of Chemical Society of Japan

      Volume: 87 Pages: 417-419

    • NAID

      40020012781

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecule-displacive ferroelectricity in organic supramolecular solids2013

    • Author(s)
      Heng-Yun Ye, Yi Zhang, Shin-ichiro Noro, Kazuya Kubo, Masashi Yoshitake, Zun-Qi Liu, Hong-Ling Cai, Da-Wei Fu, Hirofumi Yoshikawa, Kunio Awaga, Ren-Gen Xiong, Takayoshi Nakamura
    • Journal Title

      Scientific Reports

      Volume: 3, 2249 Pages: 6-6

    • NAID

      120006795651

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure of a Supramolecular Cation Salt (adamantylammonium^+)2(benzo[18]crown- 6)2- [Pd(dmit)2]^<2->(acetone)22013

    • Author(s)
      Kazuya Kubo, Yin-Nan Yan, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Inorg. Chim. Acta

      Volume: 404 Pages: 206-209

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] (3-Fluoro-4-methoxyanilinium)^+([18]Crown -6) Supramolecular Cation Salt of Ferromagnetic [Mn^<II>Cr^<III>(oxalate)3]^−2013

    • Author(s)
      Toru Endo, Kazuya Kubo, Masashi Yoshitake, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Chem. Lett.

      Volume: 42 Pages: 137-139

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular motion in pyridazinium/crown ether supramolecular cation salts of a nickel dithiolene complex2013

    • Author(s)
      Zun-Qi Liu, Kazuya Kubo, Li Lin, Norihisa Hoshino, Shin-Ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Dalton trans.

      Volume: 42 Pages: 2930-2939

    • NAID

      120005350087

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure of a Supramolecular Cation Salt: (adamantylammonium+)2(benzo[18]crown-6)2[Pd(dmit)2]2-(acetone)22013

    • Author(s)
      Kazuya Kubo, Yin-Nan Yan, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Inorganica Chimica Acta

      Volume: 404 Pages: 206-209

    • DOI

      10.1016/j.ica.2013.02.018

    • Related Report
      2013 Annual Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Porous Coordination Polymer Polymorphs with Different Flexible Pores Using a Structurally Flexible and Bent 1, 3-Bis(4-pyridyl)propane Ligand2013

    • Author(s)
      K. Fukuhara, S. Noro, K. Sugimoto, T. Akutagawa, K. Kubo and T. Nakamura
    • Journal Title

      Inorg. Chem.

      Volume: 52 Issue: 8 Pages: 4229-4237

    • DOI

      10.1021/ic301949n

    • Related Report
      2013 Annual Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Rational Synthesis of a Porous Copper(II) Coordination Polymer Bridged by Weak Lewis-Base Inorganic Monoanions Using an Anion-Mixing Method2013

    • Author(s)
      S. Noro, K. Fukuhara, Y. Hijikata, K. Kubo and T. Nakamura
    • Journal Title

      Inorg. Chem.

      Volume: 52 Issue: 10 Pages: 5630-5635

    • DOI

      10.1021/ic400276c

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anion-Dependent Host-Guest Properties of Porous Assemblies of Coordination Complexes (PACs), [Cu(A)2(py)4] (A = PF6, BF4, CF3SO3, and CH3SO3; py = pyridine), based on Werner-Type Copper(II) Complexes in the Solid State2013

    • Author(s)
      S. Noro, K. Fukuhara, K, Sugimoto, Y. Hijikata, K. Kubo and T. Nakamura
    • Journal Title

      Dalton Trans

      Volume: 42 Issue: 31 Pages: 11100-11110

    • DOI

      10.1039/c3dt51104a

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Ordering of Spin Systems Having Fractal Dimensions Experimental Study2013

    • Author(s)
      T. Naito, H. Yamamoto, K. Okuda. K. Konishi, H. Mayama, D. Yamaguchi, S. Koizumi, K. Kubo, T. Nakamura, T. Yamada, H. Kitagawa, and S. Hayami
    • Journal Title

      Eur. Phys. J. B

      Volume: 86 Issue: 10 Pages: 410-410

    • DOI

      10.1140/epjb/e2013-40353-3

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] (3-Fluoro-4-methoxy-anilinium+)([18]Crown-6) Supramolecular Cation Salt of Ferromagnetic [MnIICrIII (oxalate)3]2013

    • Author(s)
      Toru Endo, Kazuya Kubo, Masashi Yoshitake, Shin-ichiro Noro, Tomoyuki Akutagawa, and Takayoshi Nakamura
    • Journal Title

      Chemistry Letters

      Volume: 42 Issue: 2 Pages: 137-139

    • DOI

      10.1246/cl.2013.137

    • NAID

      130004426850

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] New BDH-TTP/[MIII(C5O5)3]3 (M = Fe, Ga) isostructural Molecular Metals2013

    • Author(s)
      L. Pilia et al.
    • Journal Title

      Inorg. Chem.

      Volume: 52 Issue: 1 Pages: 423-430

    • DOI

      10.1021/ic302234j

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Cation-Anion Packing and Molecular Motion in (m-Fluoroanilinium)(dibenzo[18]crown-6)[Ni(mnt)2]-(CH3CN)0.25 Crystals2012

    • Author(s)
      Kiyonori Takahashi, Norihisa Hoshino, Kazuya Kubo, Takayoshi Nakamura, Tomoyuki Akutagawa
    • Journal Title

      CrystEngComm.

      Volume: 14 Issue: 16 Pages: 5235-5241

    • DOI

      10.1039/c2ce25493j

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Crystal Structure of a One-dimensional Cu(II) Coordination Polymer Bridged by Inorganic CH3SO3- Anions Using Werner-type Cu(II) Complexes as Building Blocks2012

    • Author(s)
      S. Noro, K. Kubo and T. Nakamura
    • Journal Title

      Chem. Lett. 41

      Volume: 41 Issue: 8 Pages: 772-773

    • DOI

      10.1246/cl.2012.772

    • NAID

      130004426636

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Crystal Structure, and Adsorption Properties of Werner-type Cu(II) Complex [Cu(CF3SO3)2(4-methylpyridine)4]2012

    • Author(s)
      S. Noro, K. Fukuhara, K. Kubo and T. Nakamura
    • Journal Title

      Chem. Lett.

      Volume: 41 Issue: 10 Pages: 1314-1316

    • DOI

      10.1246/cl.2012.1314

    • NAID

      130004426366

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Supramolecular Rotators of (Aniliniums)([18]crown-6) in Electrically Conducting [Ni(dmit)2] Crystals,2012

    • Author(s)
      Norihisa Hoshino, Yuuya Yoshii, Kazuya Kubo, Masaki Aonuma, Takayoshi Nakamura, Tomoyuki Akutagawa
    • Journal Title

      Inorganic Chemistr

      Volume: 51 Issue: 23 Pages: 12968-12975

    • DOI

      10.1021/ic302093b

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 複数の水素結合部位を有する超分子カチオン結晶の構造と物性2014

    • Author(s)
      山田晃弘, 久保和也, 星野哲久, 芥川智行, 野呂真一郎, 中村貴義
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] trans-anti-trans-dicyclohexano[18]crown -6/4-aminopyridinium超分子カチオンを導入した[Ni(dmit)_2]結晶の構造と誘電性2014

    • Author(s)
      渡辺大樹, 久保和也, 星野哲久, 芥川智行, 野呂真一郎, 中村貴義
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] Crystal structure and physical properties of (4-aminopyridinium)(crown ether derivative) supramolecular cations in [Ni(dmit)_2] salts2014

    • Author(s)
      Ohshima Yu, Kubo Kazuya, Noro Shin-ichiro, Akutagawa Tomoyuki, Nakamura Takayoshi
    • Organizer
      The Sixth Hokkaido-Southeast University Bilateral Symposium on Material Science
    • Place of Presentation
      札幌
    • Year and Date
      2014-03-26
    • Related Report
      2013 Final Research Report
  • [Presentation] 結晶内分子回転により誘起される誘電応答に対する置換基効果2014

    • Author(s)
      中川翔太, 久保和也, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      日本化学会北海道支部会2014年冬季研究発表会
    • Place of Presentation
      札幌
    • Year and Date
      2014-01-28
    • Related Report
      2013 Final Research Report
  • [Presentation] (4-aminopyridinium)(クラウンエーテル誘導体)超分子カチオンを有する[Ni(dmit)_2]塩の結晶構造と誘電性2014

    • Author(s)
      大島雄, 久保和也, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      化学系学協会北海道支部2014年冬季研究発表会
    • Place of Presentation
      札幌
    • Year and Date
      2014-01-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Crystal structure and physical properties of (4-aminopyridinium)(crown ether derivative) supramolecular cations in [Ni(dmit)_2] salts2013

    • Author(s)
      Ohshima Yu, Kubo Kazuya, Noro Shin-ichiro, Akutagawa Tomoyuki, Nakamura Takayoshi
    • Organizer
      4th Asian Conference on Coordination Chemistry
    • Place of Presentation
      韓国
    • Year and Date
      2013-11-04
    • Related Report
      2013 Final Research Report
  • [Presentation] 超分子ローターを有する強磁性MnCr(oxalate) 3錯体結晶の構造と誘電物性2013

    • Author(s)
      吉竹理, 久保和也, 杉原寛之, 鈴木康孝, 川俣純, 芥川智行, 野呂真一郎, 中村貴義
    • Organizer
      錯体化学第63回討論会
    • Place of Presentation
      沖縄
    • Year and Date
      2013-11-02
    • Related Report
      2013 Final Research Report
  • [Presentation] アニリニウム/クラウンエーテル誘導体超分子カチオンとジチオレン錯体[Ni(dmit)_2]^<n-> (0 < n≦1)から構築される新規金属錯体結晶の構造と物性評価2013

    • Author(s)
      久保和也, 大島雄, 渡辺大樹, 山田晃弘, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      沖縄
    • Year and Date
      2013-11-02
    • Related Report
      2013 Final Research Report
  • [Presentation] Structure and Dielectric Properties of Protonated DABCO/[Ni(dmit)_2]^- Crystals2013

    • Author(s)
      Miyahara Masaki, Kubo Kazuya, Noro Shin-ichiro, Akutagawa Tomoyuki and Nakamura Takayoshi
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      仙台
    • Year and Date
      2013-09-30
    • Related Report
      2013 Final Research Report
  • [Presentation] Structure and Adsorption Properties of Two-Dimensional Copper(II) Complexes with Methanesulfonate Anions2013

    • Author(s)
      Ishibashi Hidenori, Noro Shin-ichiro, Kubo Kazuya, Nakamura Takayoshi
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      仙台
    • Year and Date
      2013-09-30
    • Related Report
      2013 Final Research Report
  • [Presentation] (naphthalene-1-aminium)(dibenzo[18]crow n-6)[Ni(dmit)_2]結晶の構造と物性2013

    • Author(s)
      厳寅男, 芥川智行, 久保和也, 野呂真一郎, 中村貴義
    • Organizer
      第7回分子科学討論会
    • Place of Presentation
      京都
    • Year and Date
      2013-09-27
    • Related Report
      2013 Final Research Report
  • [Presentation] (m-halogenoanilium^+)(dibenzo[18]crown-6) [Ni(dmit)_2]^-結晶の構造と物性2013

    • Author(s)
      中川翔太, 久保和也, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      第7回分子科学討論会
    • Place of Presentation
      京都
    • Year and Date
      2013-09-24
    • Related Report
      2013 Final Research Report
  • [Presentation] Naphthalene-1-aminium–crown ether supramolecular cations in [Ni(dmit)_2] salts2013

    • Author(s)
      Yan Yin-Nan, Akutagwa Tomoyuki, Kubo Kazuya, Noro Shin-ichiro, Nakamura Takayoshi
    • Organizer
      11th International Conference on Materials Chemistry (MC11)
    • Place of Presentation
      イギリス
    • Year and Date
      2013-07-08
    • Related Report
      2013 Final Research Report
  • [Presentation] Supramolecuolar cations of (4-aminopyridinium)(dicyclohexano[18]cr own-6) in [Ni(dmit)_2] salt2013

    • Author(s)
      Ohshima Yu, Kubo Kazuya, Noro Shin-ichiro, Akutagawa Tomoyuki, Nakamura Takayoshi
    • Organizer
      11th International Conference on Materials Chemistry (MC11)
    • Place of Presentation
      イギリス
    • Year and Date
      2013-07-08
    • Related Report
      2013 Final Research Report
  • [Presentation] Structures and Physical Properties of Supramolecular Cation Salts (m-bromoanilinium^+)(crown ether derivative)[Ni(dmit)_2]^-2013

    • Author(s)
      Nakagawa Shota, Kubo Kazuya, Noro Shin-ichiro, Akutagawa Tomoyuki, Nakamura Takayoshi
    • Organizer
      11th International Conference on Materials Chemistry (MC11)
    • Place of Presentation
      イギリス
    • Year and Date
      2013-07-08
    • Related Report
      2013 Final Research Report
  • [Presentation] 有機アンモニウム系カチオン/クラウンエーテル誘導体からなる超分子カチオンをもつ[Pd(dmit)2]^<n-> (0< n < 2)アニオン塩の構造と物性2013

    • Author(s)
      久保和也, 厳寅男, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Year and Date
      2013-03-25
    • Related Report
      2013 Final Research Report
  • [Presentation] Crystal structure and physical properties of (4-aminopyridinium)(crown ether derivative) supramolecular cations in [Ni(dmit)2] salts2013

    • Author(s)
      Yu Ohshima, Kazuya Kubo, Shin-ichiro Noro, Takayoshi Nakamura,
    • Organizer
      4th Asian Conference on Coordination Chemistry
    • Place of Presentation
      International Convention Center, Cheju (Korea)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 有機アンモニウム系カチオン/クラウンエーテル誘導体からなる超分子カチオンをもつ[Pd(dmit)2]n- (0 < n < 2)アニオン塩の構造と物性2013

    • Author(s)
      久保和也、厳寅男、野呂真一郎、芥川智行、中村貴義
    • Organizer
      日本化学会第93春季年会(2013)
    • Place of Presentation
      立命館大学(滋賀)
    • Related Report
      2012 Research-status Report
  • [Presentation] 非対称金属ジチオレン錯体[(ppy or bpy)M(dithiolene)]n (M = Pt, Au; n = 0 or -1)による分子性導体構築とその物性評価2012

    • Author(s)
      久保和也, 川椙義高, 加藤礼三, 野呂真一郎, 中村貴義
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山
    • Year and Date
      2012-09-22
    • Related Report
      2013 Final Research Report
  • [Presentation] (adamantylammonium)_2(benzo[18]crown-6)_2[ Pd(dmit)_2](acetone)_2の構造と物性2012

    • Author(s)
      久保和也, 厳寅男, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-09-18
    • Related Report
      2013 Final Research Report
  • [Presentation] Crystal Structure and Physical Properties of (3-Fluoro-4-Methoxy-Anilinium+)([18]Crown-6)- [MnIICrIII(oxalate)3]- Salt2012

    • Author(s)
      Kazuya Kubo, Toru Endo, Masashi Yoshitake, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Organizer
      IUPAC 8th International Conference on Novel Materials and Synthesis
    • Place of Presentation
      Grand New World Hotel, Xi’An (中国)
    • Related Report
      2012 Research-status Report
  • [Presentation] Conducting and Magnetic Properties of Assemblies of Gold Nano-Particles Stabilized by2012

    • Author(s)
      Kazuya Kubo, Araki Mizuki, Yuki Noda, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Organizer
      The 13th Interanatinonal Comference on Molecule-based Magnets
    • Place of Presentation
      Rosen Centre Hotel Orland (USA)
    • Related Report
      2012 Research-status Report
  • [Presentation] Crystal Structures and Physical Properties of [MnIICrIII(oxalate)3]- Salts with Supramolecular Rotators2012

    • Author(s)
      Kazuya Kubo, Toru Endo, Masashi Yoshitake, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Organizer
      IUMRS-ICEM 2012
    • Place of Presentation
      パシフィコ横浜(神奈川)
    • Related Report
      2012 Research-status Report
  • [Presentation] 非対称金属ジチオレン錯体 [(ppy or bpy)M(dithiolene)]n (M = Pt, Au; n = 0 or -1)による分子性導体構築とその物性評価2012

    • Author(s)
      久保和也、川椙義高、加藤礼三、野呂真一郎、中村貴義
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学(富山)
    • Related Report
      2012 Research-status Report
  • [Presentation] (adamantylammonium)2(benzo[18]crown-6)2[Pd(dmit)2](acetone)2の構造と物性2012

    • Author(s)
      久保和也、厳寅男、野呂真一郎、芥川智行、中村貴義
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学(東京)
    • Related Report
      2012 Research-status Report
  • [Presentation] Dielectric Properties Associated with Molecular Motions in (anilinium)(benzo[18]crown-6) [MnIICrIII(oxalate)3]- Ferromagnetic Complex2012

    • Author(s)
      Kazuya Kubo, Toru Endo, Masashi Yoshitake, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Organizer
      40 International Comference on Coordination Chemistry
    • Place of Presentation
      Valencia Conference Centre (Spain)
    • Related Report
      2012 Research-status Report
  • [Presentation] Metal-Organic Frameworks Based on [MnIICrIII(oxalate)3]- Toward Multifunctional materials

    • Author(s)
      Kazuya Kubo, Masashi Yoshitake, Toru Endo, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Organizer
      Workshop on Organic Electronics of Highly Correlated Molecular Systems (Core-toCore Program)
    • Place of Presentation
      University of London (U.K.)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Crystal structure and physical properties of a supramolecular rotator in (m-fluoroanilinium+)(dicyclohexano[18]crown-6)[MnIICrIII(oxalate)3]-

    • Author(s)
      Kazuya Kubo, Masashi Yoshitake, Toru Endo, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Organizer
      The 10th International Symposium on Crystalline Organic Metals Superconductors and Ferromagnets (ISCOM2013)
    • Place of Presentation
      Hotel Delta Centre-Ville (Canada)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structures and Physical Properties of Supramolecular Cation Salts (m-bromoanilinium+)(crown ether derivative)[Ni(dmit)2]-

    • Author(s)
      Shota Nakagawa, Kazuya Kubo, Shin-ichiro Noro, Tomoyuki Akutagwa, Takayoshi Nakamura.
    • Organizer
      11th International Conference on Materials Chemistry (MC 11)
    • Place of Presentation
      University of Warwick (U.K.)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Crystal structure and physical properties of DABCO cations with a magnetic [Ni(dmit)2] anion

    • Author(s)
      Masaki Miyahara, Kazuya Kubo, Shin-ichiro Noro, Tomoyuki Akutagawa and Takayoshi Nakamura
    • Organizer
      11th International Conference on Materials Chemistry (MC 11)
    • Place of Presentation
      University of Warwick (U.K.)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Supramolecuolar cations of (4-aminopyridinium)(dicyclohexano[18]crown-6) in [Ni(dmit)2] salt

    • Author(s)
      Yu Ohshima, Kazuya Kubo, Shin-ichiro Noro, Tomoyuki Akutagawa and Takayoshi Nakamura
    • Organizer
      11th International Conference on Materials Chemistry (MC 11)
    • Place of Presentation
      University of Warwick (U.K.)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Supramolecular rotator in a ferromagnetic [MnCr(oxalate)3]- crystal

    • Author(s)
      Masashi Yoshitake, Kazuya Kubo, Hiroyuki Sugihara, Yasutaka Suzuki, Jun Kawamata, Tomoyuki Akutagawa, Shin-ichiro Noro and Takayoshi Nakamura
    • Organizer
      11th International Conference on Materials Chemistry (MC 11)
    • Place of Presentation
      University of Warwick (U.K.)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Naphthalene-1-aminium / crown ether supramolecular cations in [Ni(dmit)2] salts

    • Author(s)
      Yin-Nan Yan, Tomoyuki Akutagwa, Kazuya Kubo, Shin-ichiro Noro, Takayoshi Nakamura
    • Organizer
      11th International Conference on Materials Chemistry (MC 11)
    • Place of Presentation
      University of Warwick (U.K.)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structure and physical properties of (supramolecular cation)[Ni(dmit)2] salts with benzylammonium and its fluorinated derivatives

    • Author(s)
      Daigoro Endo, Kazuya Kubo, Shin-ichiro Noro, Takayoshi Nakamura
    • Organizer
      11th International Conference on Materials Chemistry (MC 11)
    • Place of Presentation
      University of Warwick (U.K.)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structure and Dielectric Properties of Protonated DABCO/[Ni(dmit)2]- Crystals

    • Author(s)
      Masaki Miyahara, Kazuya Kubo, Shin-ichiro Noro, Tomoyuki Akutagawa and Takayoshi Nakamura
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      Tohoku University (Sendai)
    • Related Report
      2013 Annual Research Report
  • [Presentation] (4-aminopyridinium)(クラウンエーテル誘導体)超分子カチオンを有する[Ni(dmit)2]塩の結晶構造と誘電性

    • Author(s)
      大島雄、久保和也、野呂真一郎、芥川智行、中村貴義
    • Organizer
      日本化学会北海道支部会 2014年冬季研究発表会
    • Place of Presentation
      北海道大学、札幌
    • Related Report
      2013 Annual Research Report
  • [Presentation] 超分子ローターを有する強磁性MnCr(oxalate)3錯体結晶の構造と誘電物性

    • Author(s)
      吉竹 理・久保 和也・杉原 寛之・鈴木 康孝・川俣 純・芥川 智行・野呂 真一郎・中村 貴義
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学、沖縄
    • Related Report
      2013 Annual Research Report
  • [Presentation] 超分子ローター/分子磁性体結晶を利用したマルチフェロイック性の開拓

    • Author(s)
      吉竹理、久保和也、杉原寛之、鈴木康孝、川俣純、芥川智行、野呂真一郎、中村貴義
    • Organizer
      日本化学会北海道支部 2013年 夏季研究発表会
    • Place of Presentation
      北見工業大学、北見
    • Related Report
      2013 Annual Research Report
  • [Presentation] (naphthalene-1-aminium)(dibenzo[18]crown-6)[Ni(dmit)2]結晶の構造と物性

    • Author(s)
      厳寅男、芥川智行、久保和也、野呂真一郎、中村貴義
    • Organizer
      第7回分子科学討論会
    • Place of Presentation
      京都テルサ、京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] 電荷分極型中性配位子を用いた多孔性軽金属錯体の合成と吸着・分離機能

    • Author(s)
      野呂 真一郎、水谷 純也、土方 優、久保 和也、中村 貴義
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学、名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] trans-anti-trans-dicyclohexano[18]crown-6/4-aminopyridinium超分子カチオンを導入した[Ni(dmit)2]結晶の構造と誘電性

    • Author(s)
      渡辺 大樹、久保 和也、星野 哲久、芥川 智行、野呂 真一郎、中村 貴義
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学、名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] 複数の水素結合部位を有する超分子カチオン結晶の構造と物性

    • Author(s)
      山田 晃弘・久保 和也・星野 哲久・芥川 智行・野呂 真一郎・中村 貴義
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学、名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] アニリニウム/クラウンエーテル誘導体超分子カチオンとジチオレン錯体[Ni(dmit)2]n- (0 < n ≦ 1)から構築される新規金属錯体結晶の構造と物性評価

    • Author(s)
      久保和也、大島 雄、渡辺大樹、山田晃弘、野呂真一郎、芥川智行、中村貴義
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学、沖縄
    • Related Report
      2013 Annual Research Report
  • [Presentation] プロトン化状態を制御したDABCO-[Ni(dmit)2]-結晶の構造と誘電性

    • Author(s)
      宮原 正樹、久保 和也、野呂 真一郎、芥川 智行、中村 貴義
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学、沖縄
    • Related Report
      2013 Annual Research Report
  • [Presentation] Structures and Magnetic Properties of [Ln(Mo8O26)2]5- (Ln = Gd, Tb, Dy, Ho, Er), as Counter Cations for Supramolecular Rotators

    • Author(s)
      Jun Xiong, Daigoro Endo, Kazuya Kubo, Shin-Ichiro Noro, Takayoshi Nakamura
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学、沖縄
    • Related Report
      2013 Annual Research Report
  • [Presentation] (m-halogenoanilium+)(dibenzo[18]crown-6)[Ni(dmit)2]-結晶の構造と物性

    • Author(s)
      中川翔太、久保和也、野呂真一郎、芥川智行、中村貴義
    • Organizer
      第7回分子科学討論会
    • Place of Presentation
      京都テルサ、京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] 結晶内分子回転により誘起される誘電応答に対する置換基効果

    • Author(s)
      中川翔太・久保和也・野呂真一郎・芥川智行・中村貴義
    • Organizer
      日本化学会北海道支部会 2014年冬季研究発表会
    • Place of Presentation
      北海道大学、札幌
    • Related Report
      2013 Annual Research Report
  • [Book] Conducting Single-Molecule Magnets(Handbook of Multifunctional Molecular Materials, Chapter 2)2013

    • Author(s)
      Kazuya Kubo, Hiroki Hiraga, Hitoshi Miyasaka, Masahiro Yamashita
    • Publisher
      Pan Stanford Publishing
    • Related Report
      2013 Final Research Report
  • [Book] Handbook of Multifunctional Molecular Materials2013

    • Author(s)
      Kazuya Kubo, Hiroki Hiraga, Hitoshi Miyasaka, Masahiro Yamashita
    • Total Pages
      289
    • Publisher
      Pan Stanford Publishing
    • Related Report
      2013 Annual Research Report
  • [Book] Functional Molecular Materials2013

    • Author(s)
      Kazuya Kubo, Hiroki Hiraga, Hitoshi Miyasaka, Masahiro Yamashita
    • Total Pages
      43
    • Publisher
      Pan Stanford Publishing
    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://org-com.es.hokudai.ac.jp/

    • Related Report
      2013 Final Research Report
  • [Remarks] 北海道大学電子科学研究所 附属グリーンナノテクノロジー研究センター ナノアセンブリ材料研究分野

    • URL

      http://org-com.es.hokudai.ac.jp/

    • Related Report
      2013 Annual Research Report
  • [Remarks] 北海道大学電子科学研究所 ナノアセンブリ材料研究分野

    • URL

      http://org-com.es.hokudai.ac.jp/

    • Related Report
      2012 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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