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Preparation of phase segregated bcc-iron/iron-oxide nanoparitcle and their magnetic properties

Research Project

Project/Area Number 24750121
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionTohoku University

Principal Investigator

NAKAYA Masafumi  東北大学, 多元物質科学研究所, 助教 (80451681)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywordsナノ粒子 / 酸化鉄 / 構造制御 / ナノコンポジット磁石 / 鉄基機能性材料 / 強磁性 / 磁性ナノ粒子 / イプシロン相 / 粒径制御 / 結晶構造変態 / 単磁区 / コアシェル
Outline of Final Research Achievements

In order to prepare the high performance permanent magnet, we had prepared the following materials as the precursor of nanocomposite magnet by using core-shell structure with Fe phase as soft phase and ε-Fe2O3 phase as hard phase. In order to prepare air-stable metallic Fe nanoparticles, iron-oxide nanoparticles as precursors were reduced in a hydrogen atmosphere and then their surfaces were oxidized under low concentration of oxygen. To obtain Fe2O3 phase, we treated iron oxide nanoparticles with silica shell at several temperature. The size of magnetic nanoparticles affects their magnetism. We had also controlled the particle size and crystal structure. By using SiO2 coated iron oxide nanoparticles as a precursor, we suceeded to obtain mono-phase ε-Fe2O3 nanoparticles.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (56 results)

All 2015 2014 2013 2012 Other

All Journal Article (7 results) (of which Peer Reviewed: 4 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (48 results) (of which Invited: 4 results) Book (1 results)

  • [Journal Article] Size Control of Magnetite Nanoparticles in Excess Ligands as a Function of Reaction Temperature and Time2014

    • Author(s)
      Masafumi Nakaya, Ryo Nishida, Atsushi Muramatsu
    • Journal Title

      Molecules

      Volume: 19 Issue: 8 Pages: 11395-11403

    • DOI

      10.3390/molecules190811395

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Preparation of Wustite Nanoparticles by a Solventless Synthetic Procedure2013

    • Author(s)
      Masafumi Nakaya, Ryo Nishida, Atsushi Muramatsu
    • Journal Title

      Chemistry Letters

      Volume: 42 Issue: 8 Pages: 863-865

    • DOI

      10.1246/cl.130233

    • NAID

      10031189276

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation of Air-Stable Iron-Oxide-Coated Metallic Iron Nanoparticles2013

    • Author(s)
      Masafumi Nakaya, Ryo Nishida, Atsushi Muramatsu
    • Journal Title

      Journal of Chemistry and Chemical Engineering

      Volume: 7 Pages: 1050-1053

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 配位子が結晶化度を決める -既製パラジウムナノ粒子の結晶化度制御-2013

    • Author(s)
      中谷 昌史
    • Journal Title

      化学

      Volume: 68(9) Pages: 59-60

    • Related Report
      2013 Research-status Report
  • [Journal Article] ITO ナノインク向け高結晶性単分散 ITO ナノ粒子のソルボサーマル合成と今後の展望2013

    • Author(s)
      蟹江澄志,佐々木隆史,中谷昌史,村松淳司
    • Journal Title

      ディスプレイ

      Volume: 19 Pages: 68-72

    • Related Report
      2012 Research-status Report
  • [Journal Article] Preparation of Manganese Doped Cadmium Sulfide Nanoparticles in Zincblende Phase and Their Magnetic Properties2012

    • Author(s)
      Masafumi Nakaya, Itaru Tanaka, Atsushi Muramatsu
    • Journal Title

      Journal of Nanoscience and Nanotechnology

      Volume: 12 Issue: 12 Pages: 9003-9006

    • DOI

      10.1166/jnn.2012.6706

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] 共役ジエン酸化的アシルオキシ化反応のためのRh-Teナノ粒子調製2012

    • Author(s)
      中谷昌史
    • Journal Title

      触媒

      Volume: 54 Pages: 220-220

    • NAID

      10030518737

    • Related Report
      2012 Research-status Report
  • [Presentation] 酸化鉄ナノ粒子の結晶構造変態によるイプシロン相形成とその磁気特性2015

    • Author(s)
      中谷昌史, 西田怜, 村松淳司
    • Organizer
      日本化学会 第95春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 酸化鉄ナノ粒子を出発物質としたε-Fe2O3ナノ粒子の調製とその磁気特性2014

    • Author(s)
      西田怜, 中谷昌史, 村松淳司
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] ε-Fe2O3ナノ粒子の調製とその磁気特性2014

    • Author(s)
      西田怜, 中谷昌史, 村松淳司
    • Organizer
      材料フェスタ
    • Place of Presentation
      仙台
    • Year and Date
      2014-07-28 – 2014-07-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 不動態化α-Fe ナノ粒子の粒径制御とその磁気特性2014

    • Author(s)
      中谷昌史, 西田怜, 村松淳司
    • Organizer
      ナノ学会第12回大会
    • Place of Presentation
      京都
    • Year and Date
      2014-05-22 – 2014-05-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 酸化鉄ナノ粒子を出発物質としたε-Fe2O3相形成とその磁気特性2014

    • Author(s)
      西田怜, 中谷昌史, 村松淳司
    • Organizer
      ナノ学会第12回大会
    • Place of Presentation
      京都
    • Year and Date
      2014-05-22 – 2014-05-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] Preparation of Iron-Oxide-Coated Metallic Iron Nanoparticles and their Oxidation Resistance2014

    • Author(s)
      Masafumi Nakaya, Ryo Nishida, Atsushi Muramatsu
    • Organizer
      IEEE International Magnetics Conference
    • Place of Presentation
      Dresden, Germany
    • Year and Date
      2014-05-04 – 2014-05-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] 耐酸化処理された鉄ナノ粒子の調製とその磁気特性2014

    • Author(s)
      中谷昌史, 西田怜, 村松淳司
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
  • [Presentation] 耐酸化処理された鉄ナノ粒子の調製とその安定性2013

    • Author(s)
      中谷昌史
    • Organizer
      日本薬学会九州支部主催特別講演会
    • Place of Presentation
      長崎
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Preparation of Air-Stable Iron-Oxide-Coated Metallic Iron Nanoparticles with Tunable Size2013

    • Author(s)
      Masafumi Nakaya
    • Organizer
      The 3rd Dalian University of Technology - Tohoku University Joint Symposium in Chemistry
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Passivation of α-Fe nanoparticles and their oxidation resistivity2013

    • Author(s)
      Ryo Nishida, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      8th International Conference on Fine Particle Magnetism
    • Place of Presentation
      Perpignan, France
    • Related Report
      2013 Research-status Report
  • [Presentation] Preparation of Iron Oxide Nanoparticles and Control of their Structure2013

    • Author(s)
      Masafumi Nakaya, Ryo Nishida, Atsushi Muramatsu
    • Organizer
      8th International Conference on Fine Particle Magnetism
    • Place of Presentation
      Perpignan, France
    • Related Report
      2013 Research-status Report
  • [Presentation] Passivation of α-Fe nanoparticles with oxide layer and their oxidation resistance2013

    • Author(s)
      Ryo Nishida, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      TOHOKU University's Chemistry Summer School 2013
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Dendron Modification of Monodispersed Fe3O4@SiO2 Core/Shell Nanosphere2013

    • Author(s)
      Mitsuki Hinode., Masaki Matsubara, Ryo Nishida, Kiyoshi Kanie, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Preparation of Fe3O4-coated α-Fe Nanoparticles and their Oxidation Resistivity2013

    • Author(s)
      Ryo Nishida, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Preparation of Air-Stable Metallic Iron nanoparticles and their Oxidation Resistance2013

    • Author(s)
      Masafumi Nakaya, Ryo Nishida, Atsushi Muramatsu
    • Organizer
      5th PCGMR-NCKU Symposium on "Nano-Technology/-Materials for Electronics and Others"
    • Place of Presentation
      Tainan, Taiwan
    • Related Report
      2013 Research-status Report
  • [Presentation] Preparation of ε-Fe2O3 nanoparticles and their magnetic properties2013

    • Author(s)
      Ryo Nishida, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      5th PCGMR-NCKU Symposium on "Nano-Technology/-Materials for Electronics and Others"
    • Place of Presentation
      Tainan, Taiwan
    • Related Report
      2013 Research-status Report
  • [Presentation] 酸化鉄ナノ粒子の調製と構造制御2013

    • Author(s)
      中谷昌史, 西田怜, 村松淳司
    • Organizer
      ナノ学会第11回大会
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Presentation] 鉄ナノ粒子の表面酸化処理とその耐酸化性能2013

    • Author(s)
      西田怜, 中谷昌史, 村松淳司
    • Organizer
      ナノ学会第11回大会
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Presentation] α-Feナノ粒子の耐酸化処理とその安定性2013

    • Author(s)
      西田怜, 中谷昌史, 村松淳司
    • Organizer
      第64回コロイドおよび界面化学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
  • [Presentation] 表面酸化処理α-Feナノ粒子の調製とその安定性2013

    • Author(s)
      西田怜, 中谷昌史, 村松淳司
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Presentation] 酸化鉄ナノ粒子の結晶構造制御とその磁気特性2013

    • Author(s)
      中谷昌史, 西田怜, 村松淳
    • Organizer
      第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 磁性ナノ粒子の合成とその構造制御2012

    • Author(s)
      中谷昌史
    • Organizer
      化学系学協会東北大会
    • Place of Presentation
      秋田大学
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 鉄ナノ粒子の表面構造制御とその特性2012

    • Author(s)
      中谷昌史, 西田怜, 村松淳司
    • Organizer
      ナノ学会第10回大会
    • Place of Presentation
      大阪大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Rh-Te合金ナノ粒子の合成と構造解析2012

    • Author(s)
      柳橋宣利, 中谷昌史, 朝倉清高, 村松淳司
    • Organizer
      第110回触媒討論会,
    • Place of Presentation
      九州大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 液相還元法によるRh-Te合金ナノ粒子の調製2012

    • Author(s)
      柳橋宣利, 中谷昌史, 朝倉清高, 村松淳司
    • Organizer
      化学系学協会東北大会
    • Place of Presentation
      秋田大学
    • Related Report
      2012 Research-status Report
  • [Presentation] サイズ・形態制御されたチタン系酸 化物ナノ粒子の液相合成とその光触媒能2012

    • Author(s)
      君島健之, 蟹江澄志, 中谷昌史, 村松淳司
    • Organizer
      セラミックス協会 第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 形態制御 BaZrO3 微粒子の水熱合成と Eu ドープによる蛍光特性評価2012

    • Author(s)
      制野友樹,蟹江澄志,中谷昌史,村松淳司
    • Organizer
      化学系学協会東北大会
    • Place of Presentation
      秋田大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 鉄ナノ粒子の表面構造制御とその磁気特性2012

    • Author(s)
      西田 怜, 中谷 昌史, 村松 淳司
    • Organizer
      化学系学協会東北大会
    • Place of Presentation
      秋田大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Rh-Te合金ナノ粒子触媒の調製と共役ジエンのアセトキシ化反応2012

    • Author(s)
      柳橋宣利, 中谷昌史, 朝倉清高, 村松淳司
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田
    • Related Report
      2012 Research-status Report
  • [Presentation] 金属カチオンドーパントがチタン酸 カルシウム微粒子の光触媒活性に与える影響2012

    • Author(s)
      君島健之, 蟹江澄志, 中谷昌史, 村松淳司
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田
    • Related Report
      2012 Research-status Report
  • [Presentation] 金属カチオンドーピングによるチタ ン酸カルシウム微粒子の欠陥構造制御と光触媒活性に与える影響2012

    • Author(s)
      君島健之, 蟹江澄志, 中谷昌史, 村松淳司
    • Organizer
      第2回CSJ化学 フェスタ2012
    • Place of Presentation
      東京
    • Related Report
      2012 Research-status Report
  • [Presentation] 選択的オレフィン合成のためのMFI型フェリシリケート触媒の開発2012

    • Author(s)
      小林裕季, 中谷昌史, 蟹江澄志, 村松淳司
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田
    • Related Report
      2012 Research-status Report
  • [Presentation] チタン系酸化物の形態・結晶露出面 が光触媒活性に与える効果2012

    • Author(s)
      君島健之, 蟹江澄志, 中谷昌史, 村松淳司
    • Organizer
      第31回固体・表面光化学討論会
    • Place of Presentation
      大阪
    • Related Report
      2012 Research-status Report
  • [Presentation] Shape-Controlled Hydrothermal Synthesis of BaZrO3 Fine Particles and Fluorescence Properties by Europium Doping2012

    • Author(s)
      Yuki Seino, Kiyoshi Kanie, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      International Association of Colloid and Interface Scientists
    • Place of Presentation
      Sendai
    • Related Report
      2012 Research-status Report
  • [Presentation] Synthesis of nanosized MFI-type Ferrisilicate catalysts2012

    • Author(s)
      Hiroki Kobayashi, Yuichiro Yamazaki, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      International Association of Colloid and Interface Scientists
    • Place of Presentation
      Sendai
    • Related Report
      2012 Research-status Report
  • [Presentation] Synthesis of well-crystallized Rh-Te alloy nanoparticles by liquid phase reduction method2012

    • Author(s)
      Noritoshi Yagihashi, Masafumi Nakaya, Kiyotaka Asakura, Atsushi Muramatsu
    • Organizer
      nternational Association of Colloid and Interface Scientists
    • Place of Presentation
      Sendai
    • Related Report
      2012 Research-status Report
  • [Presentation] Introduction of Self-Organization Properties into CdS Nanoparticles by Surface Dendron-Modification2012

    • Author(s)
      Jun Yabuki, Kiyoshi Kanie, Masaki Matsubara, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      International Association of Colloid and Interface Scientists
    • Place of Presentation
      Sendai
    • Related Report
      2012 Research-status Report
  • [Presentation] Photocatalytic Activity of SrTiO3 Nanoparticles Precisely Controlled in Size and Shape2012

    • Author(s)
      Kimijima Takeshi, Nakaya Masafumi, Kanie Kiyoshi, Muramatsu Atsushi
    • Organizer
      International Association of Colloid and Interface Scientists
    • Place of Presentation
      Sendai
    • Related Report
      2012 Research-status Report
  • [Presentation] Synthesis of the passivated α-Fe nanoparticles and its stabilyty2012

    • Author(s)
      Ryo Nishida, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      International Association of Colloid and Interface Scientists
    • Place of Presentation
      Sendai
    • Related Report
      2012 Research-status Report
  • [Presentation] Synthesis and Photocatalytic Activity of Ti-based Oxides with Various Sizes and Shapes2012

    • Author(s)
      Kimijima Takeshi, Nakaya Masafumi, Kanie Kiyoshi, Muramatsu Atsushi
    • Organizer
      ICC2012
    • Place of Presentation
      Germany, Munich
    • Related Report
      2012 Research-status Report
  • [Presentation] Introduction of Liquid-Crystallinity into CdS Nanoparticles by Surface Dendron-Modification and their Luminescence Property2012

    • Author(s)
      Jun Yabuki, Kiyoshi Kanie, Masaki Matsubara, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      24th International Liquid Crystal Conference
    • Place of Presentation
      Germany,Mainz
    • Related Report
      2012 Research-status Report
  • [Presentation] Nanosized MFI-type Ferrisilicate catalysts for light olefin synthesis2012

    • Author(s)
      Hiroki Kobayashi, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      The 4th China-Japan Symposium on Ferroelectric Materials and their Applications
    • Place of Presentation
      Miyagi
    • Related Report
      2012 Research-status Report
  • [Presentation] Hydrothermally Prepared Sodium Potassium Niobate Fine Particles Using Niobium Pentachloride and their Piezoelectric Properties2012

    • Author(s)
      Kiyoshi Kanie, Hideto Mizutani, Atsuki Terabe, Yoshiki Numamoto, Shintaro Tsukamoto, Hirofumi Takahashi, Masafumi Nakaya, Junji Tani, AtsushiMuramatsu
    • Organizer
      The 4th China-Japan Symposium on Ferroelectric Materials and Their Applications
    • Place of Presentation
      Miyagi
    • Related Report
      2012 Research-status Report
  • [Presentation] Hydrothermal Synthesis of Shape-Controlled BaZrO3 Fine Particles and Photoluminescence Property by Eu-Dopin2012

    • Author(s)
      Yuki Seino, Kiyoshi Kanie, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      5th International Symposium on Functional Materials
    • Place of Presentation
      Australia, Perth
    • Related Report
      2012 Research-status Report
  • [Presentation] Size control of MFI-type Ferrisilicate and its catalytic activity2012

    • Author(s)
      Hiroki Kobayashi, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      5th International Symposium on Functional Materials
    • Place of Presentation
      Australia, Perth
    • Related Report
      2012 Research-status Report
  • [Presentation] Preparation of passivated Fe nanoparticle and its stability2012

    • Author(s)
      Ryo Nishida, Masafumi Nakaya, Atsushi Muramatsu
    • Organizer
      5th International Symposium on Functional Materials
    • Place of Presentation
      Australia, Perth
    • Related Report
      2012 Research-status Report
  • [Presentation] 鉄含有MFI型ゼオライトの合成及びその触媒活性評価

    • Author(s)
      小林裕季, 中谷昌史, 蟹江澄志, 村松淳司
    • Organizer
      東北大学多元物質科学研究所研究発表会
    • Place of Presentation
      仙台
    • Related Report
      2012 Research-status Report
  • [Presentation] Nanosized MFI-type Ferrisilicate catalysts for light olefin synthesis from dimethyl ether

    • Author(s)
      Hiroki Kobayashi, Yuichiro Yamazaki, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
    • Organizer
      International Symposium on Zeolite and Microporous Crystals
    • Place of Presentation
      Hiroshima
    • Related Report
      2012 Research-status Report
  • [Book] 透明導電膜 有力材料の実力と各種プロセス技術, 実用・製品化,高結晶性ITOナノ粒子の液相合成と低抵抗ITOナノインク開発への取り組み2012

    • Author(s)
      蟹江澄志,中谷昌史,村松淳司
    • Publisher
      情報機構
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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