| Project/Area Number |
24750128
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Functional materials chemistry
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| Research Institution | Kyoto University (2013)
Okayama University (2012) |
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Principal Investigator |
ITADANI Atsushi 京都大学, 物質-細胞統合システム拠点, 研究員 (60379708)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | セラミックス / ゼオライト / 細孔 / 窒素 / 吸着 / 活性化 / エタン |
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| Research Abstract |
When the pores of ceramics materials such as zeolite and mesoporous silica are utilized as the reaction field, the gaseous molecules which are originally known as the inert gases are activated. In this work, we established the preparation method of copper ion-exchanged zeolite having the irreversible adsorption property of dinitrogen gas at room temperature. Taking account of nitrogenase enzyme exhibiting the fixation of dinitrogen, we examined the state of dual copper site formed in zeolite pore by using ethane as a probe molecule. The result gave the important information for the understanding of the state of active center for the fixation of dinitrogen in the copper ion-exchanged zeolite.
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