Exploring template reaction of polyoxometalates
| Project/Area Number |
24750129
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Functional materials chemistry
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| Research Institution | Yamaguchi University |
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Principal Investigator |
TSUNASHIMA Ryo 山口大学, 理工学研究科, 准教授 (70466431)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | ポリ酸 / ポリオキソメタレート / 巨大分子 / テンプレート合成 / 電気泳動 / テンプレート反応 |
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| Outline of Final Research Achievements |
This project aimed to realize rational synthesis of metal-oxide nanoclusters. For the purpose, template reaction become unique if molecular understandings of template molecules or ions are cleared. We investigated several controlled reactions with reaction parameters of pH and molar ratio of reactants. The relationships between reaction and the Lewis basicity of the anionic species, the extent of the reduction and the polarity of the solvent were revealed.
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Report
(4 results)
Research Products
(23 results)
