Photochemical control of organic ferroelectric crystals by using hydrogen-bonding photochromic molecules
| Project/Area Number |
24750136
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Functional materials chemistry
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| Research Institution | Rikkyo University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Keywords | 分子性固体 / 誘電体物性 / フォトクロミズム / 水素結合 / 有機強誘電体 |
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| Research Abstract |
In order to create photoresponsive organic ferroelectrics that change their physical properties arising from intermolecular proton transfer upon structural transformation of photochromic molecules, we designed and synthesized new photochromic diarylethene derivatives bearing an imidazole ring with hydrogen-bonding ability. Most of the derivatives formed one-dimensional chain structures by intermolecular hydrogen-bonding interactions and underwent photochromic reactions in the single-crystalline phase. In addition, we observed enantioselective photochemical reactions in hydrogen-bonding cocrystals composed of photochromic molecules and other chiral molecules.
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Report
(3 results)
Research Products
(11 results)
