Light-responsive molecular conductor
Project/Area Number |
24750142
|
Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Multi-year Fund |
Research Field |
Functional materials chemistry
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Research Institution | The University of Tokyo |
Principal Investigator |
Kusamoto Tetsuro 東京大学, 理学(系)研究科(研究院), 助教 (90585192)
|
Project Period (FY) |
2012-04-01 – 2016-03-31
|
Project Status |
Completed (Fiscal Year 2015)
|
Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
|
Keywords | ラジカル / 物性 / 制御 / 発光 / 電子状態 / 電子移動 / スピン / 発光特性 / 分子性導体 / TTF / フェロセン / レドックス / 電荷移動錯体 / ジチオレン金属錯体 |
Outline of Final Research Achievements |
The control of the properties of molecular solids using precisely tunable external stimuli is an important issue for developing future nanoscale devices or molecular devises. The achievements for realizing this issue in this study are as follows: (1) Spin-reconstructed proton-coupled electron transfer in a ferrocene-nickeladithiolene hybrid molecule. (2) Intramolecular charge transfer and intramolecular spin-spin interaction based on a ferrocene-tetrathiafulvalene hybrid. (3) Preparation of a rare luminescent radical with high photostability, and (4) the development of a luminescent gold complex and a ferromagnetic cupper complex based on the luminescent radical as ligands.
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Report
(5 results)
Research Products
(50 results)
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[Journal Article] Synthesis, Characterization, and Physical Properties of Oligo(1-(N,N-dimethylamino)pyrrole)s and Their Doped Forms, Precursors of Candidates for Molecular Flat-band Ferromagnets2015
Author(s)
Y. Yamanoi, K. Takahashi, T. Hamada, N. Ohshima, M. Kurashina, Y. Hattori, T. Kusamoto, R. Sakamoto, M. Miyachi, and H. Nishihara
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Journal Title
Journal of Materials Chemistry C
Volume: 3
Issue: 17
Pages: 1-1
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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[Journal Article] Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π–Nanosheet: A Potential Organic Two-Dimensional Topological Insulator2014
Author(s)
T. Kambe, R. Sakamoto, T. Kusamoto, T. Pal, N. Fukui, K. Hoshiko, T. Shimojima, Z. Wang, K. Ishizaka, S. Hasegawa, F. Liu, and H. Nishihara
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Journal Title
Journal of the American Chemical Society
Volume: 136
Issue: 41
Pages: 14357-14360
DOI
Related Report
Peer Reviewed
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