Construction of Photo-Catalytic System Based on Light-Harvesting Antenna Functions of Dye-Organized Nanotubes

• Project/Area Number: 24750143
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Functional materials chemistry
• Research Institution: National Institute of Advanced Industrial Science and Technology
• Principal Investigator: KAMETA Naohiro 独立行政法人産業技術総合研究所, ナノシステム研究部門, 研究員 (20517297)
• Project Period (FY): 2012-04-01 – 2014-03-31
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000); Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
• Keywords: 自己組織化 / ナノチューブ / ナノチャンネル / ホスト－ゲスト / エネルギー移動 / 光捕集アンテナ / 光触媒 / 人工光合成

Research Abstract

Well-designed amphiphilic monomers having dye moieties self-organized in solvents to form tubular nanostructures (nanotubes). Light energy absorbed by the dye moieties densely and regularly organized in the membrane wall of the nanotubes was effectively transferred into acceptors encapsulated in the nanochannel. Such light-harvesting antenna function of the nanotubes enabled us to enhance the photo-catalytic activities of metal complexes encapsulated in the nanochannel.

Research Products

• [Journal Article] Soft Nanotube Hosts for Capsulation and Release of Molecules, Macromolecules, and Nanomaterials (2014)
  • Author(s): Naohiro Kameta
  • Journal Title: Journal of Inclusion Phenomena and Macrocyclic Chemistry Volume: vol.79 Pages: 1-22
  • Peer Reviewed
• [Journal Article] Boroxine Nanotubes : Moisture-Sensitive Morphological Transformation and Guest Release (2014)
  • Author(s): Kazuyuki Ishikawa, Naohiro Kameta, Mitsutoshi Masuda, Masumi Asakawa, Toshimi Shimizu
  • Journal Title: Advanced Functional Materials Volume: vol.24 Pages: 603-609
  • Peer Reviewed
• [Journal Article] Boroxine Nanotubes: Moisture-Sensitive Morphological Transformation and Guest Release (2014)
  • Author(s): Kazuyuki Ishikawa, Naohiro Kameta (CA), Mitsutoshi Masuda, Masumi Asakawa, Toshimi Shimizu
  • Journal Title: Advanced Functional Materials Volume: 24 Issue: 5 Pages: 603-609
  • DOI: 10.1002/adfm.201302005
  • Peer Reviewed
• [Journal Article] Soft nanotube hosts for capsulation and release of molecules, macromolecules, and nanomaterials (2014)
  • Author(s): Naohiro Kameta
  • Journal Title: Journal of Inclusion Phenomena and Macrocyclic Chemistry Volume: 79 Issue: 1-2 Pages: 1-22
  • DOI: 10.1007/s10847-014-0397-3
  • Peer Reviewed
• [Journal Article] Control of Self-Assembled Morphology and Molecular Packing of Asymmetric Glycolipids by Association/Dissociation with Poly(thiopheneboronic acid) (2013)
  • Author(s): Naohiro Kameta, Kazuyuki Ishikawa, Mitsutoshi Masuda, Toshimi Shimizu
  • Journal Title: Langmuir Volume: vol.29 Pages: 13291-13298
  • Peer Reviewed
• [Journal Article] Biologically Responsive, Sustainable Release form Metallo-Drug 1D Nanostructures (2013)
  • Author(s): Naohiro Kameta, Soo Jin Lee, Mitsutoshi Masuda
  • Journal Title: Journal of Materials Chemistry B Volume: vol.1 Pages: 276-283
  • Peer Reviewed
• [Journal Article] Soft Nanotubes with a Hydrophobic Channel Hybridized with Au Nanoparticles : Photothermal Dispersion/Aggregation Control of C60 in water (2013)
  • Author(s): Kazuyuki Ishikawa, Naohiro Kameta, Masaru Aoyagi, Masumi Asakawa, Toshimi Shimizu
  • Journal Title: Advanced Functional Materials Volume: vol.23 Pages: 1677-1683
  • Peer Reviewed
• [Journal Article] Control of Self-assembled Morphology and Molecular Packing of Asymmetric Glycolipids by Association/Dissociation with Poly(thiopheneboronic acid) (2013)
  • Author(s): Naohiro Kameta, Kazuyuki Ishikawa, Mitsutoshi Masuda, Toshimi Shimizu
  • Journal Title: Langmuir Volume: 29 Issue: 43 Pages: 13291-13298
  • DOI: 10.1021/la4028018
  • Peer Reviewed
• [Journal Article] Biologically Responsive, Sustainable Release from Metallo-Drug Coordinated 1D Nanostructures (2013)
  • Author(s): Naohiro Kameta (CA), Soo Jin Lee, Mitsutoshi Masuda, Toshimi Shimizu
  • Journal Title: Journal of Materials Chemistry B Volume: 1 Issue: 3 Pages: 276-283
  • DOI: 10.1039/c2tb00101b
  • Peer Reviewed
• [Journal Article] Soft Nanotubes with a Hydrophobic Channel Hybridized with Au Nanoparticles: Photothermal Dispersion/Aggregation Control of C60 in Water (2013)
  • Author(s): Kazuyuki Ishikawa, Naohiro Kameta (CA), Masaru Aoyagi, Masumi Asakawa, Toshimi Shimizu
  • Journal Title: Advanced Functional Materials Volume: 23 Issue: 13 Pages: 1677-1683
  • DOI: 10.1002/adfm.201202160
  • Peer Reviewed
• [Presentation] 機能性有機ナノチューブの創製とナノバイオ利用技術 (2014)
  • Author(s): 亀田直弘
  • Organizer: 超分子研究会
  • Place of Presentation: 東京
  • Year and Date: 2014-01-16
• [Presentation] Self-Organized Organic Nanotubes with Soft Namospace Functions (2013)
  • Author(s): Naohiro Kameta, Kazuyuki Ishikawa, Masaru Aoyagi, Mitsutoshi Masuda, Masumi Asakawa, Toshimi Shimizu
  • Organizer: The 13^<th> Pacific Polymer Conference
  • Place of Presentation: 台湾
  • Year and Date: 2013-11-20
• [Presentation] バイオ応用を目指した有機ナノチューブ材料の開発 (2013)
  • Author(s): 亀田直弘,佐藤一彦
  • Organizer: 創造機能化学第116委員会
  • Place of Presentation: 東京
  • Year and Date: 2013-10-07
• [Presentation] ボロン酸エステルの自己組織化によるソフトナノチューブ形成とその機能 (2013)
  • Author(s): 亀田直弘,増田光俊,清水敏美
  • Organizer: 第64回コロイドおよび界面化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2013-09-19
• [Presentation] 有機ナノチューブのソフトナノ空間を利用したバイオ機能 (2013)
  • Author(s): 亀田直弘,増田光俊,清水敏美
  • Organizer: 第62回高分子討論会
  • Place of Presentation: 金沢
  • Year and Date: 2013-09-11
• [Presentation] チオフェン結合糖脂質の自己集合による有機ナノチューブ形成と酸化重合 (2013)
  • Author(s): 石川和孝,亀田直弘,青柳将,増田光俊,浅川真澄,清水敏美
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都
  • Year and Date: 2013-05-29
• [Presentation] チオフェン結合糖脂質の自己集合による有機ナノチューブ形成と酸化重合 (2013)
  • Author(s): 石川和孝,亀田直弘,青柳将,増田光俊,浅川真澄,清水敏美
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 滋賀
  • Year and Date: 2013-03-24
• [Presentation] 分子組織化ナノチューブの創製とそのソフトナノ空間機能開拓 (2013)
  • Author(s): 亀田直弘
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 滋賀
  • Year and Date: 2013-03-24
• [Presentation] ソフトナノチューブ材料の開発 (2013)
  • Author(s): 亀田直弘
  • Organizer: つくばソフトマター研究会2013
  • Place of Presentation: つくば
  • Year and Date: 2013-03-11
• [Presentation] Supramolecular Bionanotubes Acting as a Light-Harvesting Antenna System (2013)
  • Author(s): Naohiro Kameta, Kazuyuki Ishikawa, Mitsutoshi Masuda, Masumi Asakawa, Toshimi Shimizu
  • Organizer: Third International Conference on Multifunctional, Hybrid and Nanomaterials
  • Place of Presentation: イタリア
  • Year and Date: 2013-03-05
• [Presentation] 光でほどける有機・無機複合化ナノチューブ (2013)
  • Author(s): 亀田直弘,石川和孝,青柳将,増田光俊,浅川真澄,清水敏美
  • Organizer: 平成24年度産業技術連携推進会議ナノテクノロジー・材料部会、製造プロセス部会合同研究発表会
  • Place of Presentation: つくば
  • Year and Date: 2013-02-06
• [Presentation] 光機能性有機ナノチューブ (2013)
  • Author(s): 石川和孝,亀田直弘,青柳将,増田光俊,清水敏美
  • Organizer: SATテクノロジー・ショーケース2013
  • Place of Presentation: つくば
  • Year and Date: 2013-01-22
• [Presentation] Functional Soft Nanotubes Self-Organized from Organic Molecules (2012)
  • Author(s): Naohiro Kameta, Mitsutoshi Masuda, Toshimi Shimizu
  • Organizer: International Workshop on Soft Interface Sciences for Young Scientists 2012(SISYS)
  • Place of Presentation: つくば
  • Year and Date: 2012-11-22
• [Presentation] チオフェン結合糖脂質の自己集合による有機ナノチューブ形成とポリマー化 (2012)
  • Author(s): 石川和孝,亀田直弘,青柳将,小木曽真樹,浅川真澄,清水敏美
  • Organizer: 第61回高分子討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2012-09-21
• [Presentation] 分子組織化ソフトナノチューブの創製と光機能 (2012)
  • Author(s): 亀田直弘,石川和孝,増田光俊,浅川真澄,清水敏美
  • Organizer: 第61回高分子討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2012-09-19
• [Presentation] 糖脂質系有機ナノチューブの芳香族ボロン酸による機能化 (2012)
  • Author(s): 石川和孝,亀田直弘,青柳将,小木曽真樹,浅川真澄,清水敏美
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜
  • Year and Date: 2012-05-30
• [Presentation] 疎水性有機ナノチューブの構築とその水分散化挙動 (2012)
  • Author(s): 亀田直弘,青柳将,石川和孝,南川博之,増田光俊,浅川真澄,清水敏美
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜
  • Year and Date: 2012-05-29
• [Presentation] 色素分子組織化ソフトナノチューブの創製とその機能 (2012)
  • Author(s): 亀田直弘,浅川真澄,増田光俊,清水敏美
  • Organizer: 第9回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 札幌
  • Year and Date: 2012-05-26
• [Presentation] Supramolecular Nanotubes with Functionalizable Liquid-Phase Nanospace (2012)
  • Author(s): Naohiro Kameta, Mitsutoshi Masuda, Hiroyuki Minamikawa, Toshimi Shimizu
  • Organizer: International Association of Colloid and Interface Scientists(IACIS2012)
  • Place of Presentation: 仙台
  • Year and Date: 2012-05-16
• [Presentation] Supramolecular Nanotubes Composed of Glycolipids and aromatic-Boronic Acids (2012)
  • Author(s): Kazuyuki Ishikawa, Naohiro Kameta, Masaru Aoyagi, Masaki Kogiso, Masumi Asakawa, Toshimi Shimizu
  • Organizer: International Association of Colloid and Interface Scientists(IACIS2012)
  • Place of Presentation: 仙台
  • Year and Date: 2012-05-15
• [Presentation] チオフェン結合糖脂質の自己集合による有機ナノチューブ形成と酸化重合
  • Author(s): 石川和孝、亀田直弘、青柳将、増田光俊、浅川真澄、清水敏美
  • Organizer: 第62回高分子学会年次大会
  • Place of Presentation: 京都
• [Presentation] 有機ナノチューブのソフトナノ空間を利用したバイオ機能
  • Author(s): 亀田直弘、増田光俊、清水敏美
  • Organizer: 第６２回高分子討論会
  • Place of Presentation: 金沢
  • Invited
• [Presentation] ボロン酸エステルの自己組織化によるソフトナノチューブ形成とその機能
  • Author(s): 亀田直弘、増田光俊、清水敏美
  • Organizer: 第64回コロイドおよび界面化学討論会
  • Place of Presentation: 名古屋
• [Presentation] バイオ応用を目指した有機ナノチューブ材料の開発
  • Author(s): 亀田直弘、佐藤一彦
  • Organizer: 創造機能化学第１１６委員会
  • Place of Presentation: 東京
  • Invited
• [Presentation] Self-Organized Organic Nanotubes with Soft Nanospace Functions
  • Author(s): Naohiro Kameta, Kazuyuki Ishikawa, Masaru Aoyagi, Mitsutoshi Masuda, Masumi Asakawa, Toshimi Shimizu
  • Organizer: The 13th Pacific Polymer Conference
  • Place of Presentation: 台湾
• [Presentation] Supramolecular Nanotubes with Functionalizable Liquid-Phase Nanospace
  • Author(s): Naohiro Kameta, Mitsutoshi Masuda, Hiroyuki Minamikawa, Toshimi Shimizu
  • Organizer: International Association of Colloid and Interface Scientists (IACIS2012)
  • Place of Presentation: 仙台
• [Presentation] Supramolecular Nanotubes Composed of Glycolipids and Aromatic-Boronic Acids
  • Author(s): Kazuyuki Ishikawa, Naohiro Kameta, Masaru Aoyagi, Masaki Kogiso, Masumi Asakawa, Toshimi Shimizu
  • Organizer: International Association of Colloid and Interface Scientists (IACIS2012)
  • Place of Presentation: 仙台
• [Presentation] 色素分子組織化ソフトナノチューブの創製とその機能
  • Author(s): 亀田直弘、浅川真澄、増田光俊、清水敏美
  • Organizer: 第9回ホスト・ゲスト化学シンポジウム
  • Place of Presentation: 札幌
• [Presentation] 疎水性有機ナノチューブの構築とその水分散化挙動
  • Author(s): 亀田直弘、青柳将、石川和孝、南川博之、増田光俊、浅川真澄、清水敏美
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜
• [Presentation] 糖脂質系有機ナノチューブの芳香族ボロン酸による機能化
  • Author(s): 石川和孝、亀田直弘、青柳将、小木曽真樹、浅川真澄、清水敏美
  • Organizer: 第61回高分子学会年次大会
  • Place of Presentation: 横浜
• [Presentation] 分子組織化ソフトナノチューブの創製と光機能
  • Author(s): 亀田直弘、石川和孝、増田光俊、浅川真澄、清水敏美
  • Organizer: 第61回高分子討論会
  • Place of Presentation: 名古屋
  • Invited
• [Presentation] チオフェン結合糖脂質の自己集合による有機ナノチューブ形成とポリマー化
  • Author(s): 石川和孝、亀田直弘、青柳将、小木曽真樹、浅川真澄、清水敏美
  • Organizer: 第61回高分子討論会
  • Place of Presentation: 名古屋
• [Presentation] Functional Soft Nanotubes Self-Organized from Organic Molecules
  • Author(s): Naohiro Kameta, Mitsutoshi Masuda, Toshimi Shimizu
  • Organizer: International Workshop on Soft Interface Sciences for Young Scientists 2012 (SISYS)
  • Place of Presentation: つくば
• [Presentation] 光機能性有機ナノチューブの開発
  • Author(s): 石川和孝、亀田直弘、青柳将、増田光俊、清水敏美
  • Organizer: SATテクノロジー・ショーケース２０１３
  • Place of Presentation: つくば
• [Presentation] 光でほどける有機・無機複合化ナノチューブ
  • Author(s): 亀田直弘、石川和孝、青柳将、増田光俊、浅川真澄、清水敏美
  • Organizer: 平成２４年度産業技術連携推進会議 ナノテクノロジー・材料部会、製造プロセス部会 合同研究発表会
  • Place of Presentation: つくば
• [Presentation] チオフェン結合糖脂質の自己集合による有機ナノチューブ形成と酸化重合
  • Author(s): 石川和孝、亀田直弘、青柳将、増田光俊、浅川真澄、清水敏美
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 滋賀
• [Book] "分子組織化ナノチューブの創製とそのソフトナノ空間機能開拓", Colloid & Interface Communication (2014)
  • Author(s): 亀田直弘
  • Publisher: 日本化学会コロイドおよび界面化学部会
• [Book] Colloid & Interface Communication (2014)
  • Author(s): 亀田直弘
  • Total Pages: 4
  • Publisher: 日本化学会コロイドおよび界面化学部会
• [Book] "分子の自己組織化を利用したソフトナノ空間材料の創製", 化学と工業 (2013)
  • Author(s): 亀田直弘
  • Publisher: 日本化学会
• [Book] 化学と工業 (2013)
  • Author(s): 亀田直弘
  • Total Pages: 2
  • Publisher: 日本化学会
• [Remarks]
  • URL: https://unit.aist.go.jp/nri/index_j.html
• [Remarks] 産業技術総合研究所ナノシステム研究部門
  • URL: https://unit.aist.go.jp/nri/index_j.html
• [Remarks] 産業技術総合研究所ナノチューブ応用研究センター
  • URL: http://unit.aist.go.jp/ntrc/ci/index.html