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Development of high-capacity porous carbon adsorbent for water adsorption heat pump

Research Project

Project/Area Number 24750146
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental chemistry
Research InstitutionThe University of Tokushima

Principal Investigator

HORIKAWA Toshihide  徳島大学, ソシオテクノサイエンス研究部, 講師 (90380112)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords低環境負荷物質 / 水蒸気吸着 / 含窒素多孔質炭素 / 吸着式ヒートポンプ / 吸着剤 / 窒素ドープ
Research Abstract

Recently, it is required to develop the technologies of creating, buildup, and saving of energy. One of the possible system for the utilization of low waste heat is the water adsorption heat pump (WAHP). In this study, we aimed to develop a high-capacity porous carbon adsorbent for WAHP, on which the water adsorption isotherm shows steep and large uptake at low relative pressure where is the operation pressure range of WAHP. The prepared porous carbon materials were controlled the pore properties and doped the nitrogen atoms into the carbon matrices. It was successful to develop the prepared N-doped porous carbon materials which show five times higher water adsorbed amount difference at low relative pressure range comparing with the non-doped porous carbon materials, as an adsorbent for WAHP.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (32 results)

All 2014 2013 2012 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (26 results) Remarks (2 results)

  • [Journal Article] Water as a Potential Molecular Probe for Functional Groups on Carbon Surfaces2014

    • Author(s)
      Van T. Nguyen, Toshihide Horikawa, D. D. Do and D. Nicholson
    • Journal Title

      Carbon

      Volume: Vol.67 Pages: 72-78

    • DOI

      10.1016/j.carbon.2013.09.057

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] On the relative strength of adsorption of gases on carbon surfaces with functional groups: fluid-fluid, fluid-graphite and fluid-functional group interactions2013

    • Author(s)
      Van T. Nguyen, Toshihide Horikawa, D. D. Do, D. Nicholson
    • Journal Title

      Carbon

      Volume: 61 Pages: 551-557

    • DOI

      10.1016/j.carbon.2013.05.036

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of nitrogen-doped porous carbon and its water adsorption behavior2013

    • Author(s)
      Toshihide Horikawa, Noriyuki Sakao, Jun'ichi Hayashi, D.D. Do, Masahiro Katoh and Ken-Ichiro Sotowa
    • Journal Title

      Adsorption Science & Technology

      Volume: Vol.31, No.2+3 Issue: 2-3 Pages: 135-144

    • DOI

      10.1260/0263-6174.31.2-3.135

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effects of temperature on water adsorption on controlled microporous and mesoporous carbonaceous solids2013

    • Author(s)
      Toshihide Horikawa, Noriyuki Sakao and D.D. Do
    • Journal Title

      Carbon

      Volume: Vol.56 Pages: 183-192

    • DOI

      10.1016/j.carbon.2013.01.003

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Effects of surface chemistry and pore structure on the adsorption of polar molecules in carbonaceous solids2013

    • Author(s)
      Masanori Takenouchi, Toshihide Horikawa, D. D. Do and Ken-Ichiro Sotowa
    • Organizer
      Chemeca2013, Brisbane Convention & ExhibitionCentre
    • Place of Presentation
      Brisbane, Australia
    • Related Report
      2013 Final Research Report
  • [Presentation] グラファイト,ミクロ・メソポーラスカーボンへの水蒸気吸着の温度依存性2013

    • Author(s)
      六車岳洋, 堀河俊英, 竹ノ内雅典, 外輪健一郎, アルカンタラアビラヘスースラファエル
    • Organizer
      第7回中四国若手CE合宿
    • Place of Presentation
      ホテル常盤(山口県)
    • Related Report
      2013 Final Research Report
  • [Presentation] 活性炭繊維と黒鉛化カーボンブラックへの水蒸気吸着の温度依存性2013

    • Author(s)
      六車岳洋, 堀河俊英, 竹ノ内雅典, 外輪健一郎, アルカンタラアビラヘスースラファエル
    • Organizer
      化学工学会第45回秋季大会
    • Place of Presentation
      岡山大学(岡山県)
    • Related Report
      2013 Final Research Report
  • [Presentation] A new approach in the modeling and characterization of porous carbon2013

    • Author(s)
      D. D. Do, C. Fan, P. Nguyen, V. Nguyen, Z. Nickmand, Y. Zeng and Toshihide Horikawa
    • Organizer
      The Annual World Conference on Carbon (Carbon2013)
    • Place of Presentation
      Windsor Atlantica Hotel (Rio de Janeiro, Brazil)
    • Related Report
      2013 Final Research Report
  • [Presentation] Effects of Temperature on Water Adsorption on ACFs2013

    • Author(s)
      Toshihide Horikawa, Masanori Takenouchi, Takahiro Muguruma, D. D. Do and Ken-Ichiro Sotowa
    • Organizer
      11th International Conference on the Fundamentals of Adsorption(FOA11)
    • Place of Presentation
      Hyatt Regency Hotel on the Inner Harbor (Baltimore, USA)
    • Related Report
      2013 Final Research Report
  • [Presentation] 窒素ドープ炭素吸着剤の調製とその水蒸気吸着挙動2013

    • Author(s)
      堀河俊英, 坂尾倫幸, 林順一, 加藤雅裕, 外輪健一郎
    • Organizer
      化学工学会第78年会
    • Place of Presentation
      大阪大学(大阪府)
    • Related Report
      2013 Final Research Report
  • [Presentation] Effects of surface chemistry and pore structure on the adsorption of polar molecules in carbonaceous solids2013

    • Author(s)
      Masanori Takenouchi, Toshihide Horikawa, D. D. Do, Ken-Ichiro Sotowa
    • Organizer
      Chemeca2013
    • Place of Presentation
      Brisbane Convention & Exhibition Centre (Brisbane, Australia)
    • Related Report
      2013 Annual Research Report
  • [Presentation] A new approach in the modeling and characterization of porous carbon2013

    • Author(s)
      D. D. Do, C. Fan, P. Nguyen, V. Nguyen, Z. Nickmand, Y. Zeng, Toshihide Horikawa
    • Organizer
      Carbon2013
    • Place of Presentation
      Windsor Atlantica Hotel (Rio de Janeiro, Brazil)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effects of Temperature on Water Adsorption on ACFs2013

    • Author(s)
      Toshihide Horikawa, Masanori Takenouchi, Takahiro Muguruma, D. D. Do, Ken-Ichiro Sotowa
    • Organizer
      FOA11
    • Place of Presentation
      Hyatt Regency Hotel on the Inner Harbor (Baltimore, USA)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 活性炭繊維と黒鉛化カーボンブラックへの水蒸気吸着の温度依存性2013

    • Author(s)
      六車 岳洋, 堀河 俊英, 竹ノ内 雅典, 外輪 健一郎, アルカンタラ アビラ ヘスース ラファエル
    • Organizer
      化学工学会第45回秋季大会
    • Place of Presentation
      岡山大学 (岡山県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] グラファイト, ミクロ・メソポーラスカーボンへの水蒸気吸着の温度依存性2013

    • Author(s)
      六車 岳洋, 堀河 俊英, 竹ノ内 雅典, 外輪 健一郎, アルカンタラ アビラ ヘスース ラファエル
    • Organizer
      第7回 中四国若手CE合宿
    • Place of Presentation
      ホテル常盤 (山口県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 窒素ドープ炭素吸着剤の調製とその水蒸気吸着挙動2013

    • Author(s)
      堀河 俊英, 他
    • Organizer
      化学工学会 第78年会
    • Place of Presentation
      大阪大学(大阪府)
    • Related Report
      2012 Research-status Report
  • [Presentation] Effects of Temperature on Water Adsorption on ACFs2013

    • Author(s)
      Toshihide Horikawa, et al.
    • Organizer
      11th International Conference on the Fundamentals of Adsorption (FOA11)
    • Place of Presentation
      Hyatt Regency Hotel (Baltimore, USA)
    • Related Report
      2012 Research-status Report
  • [Presentation] Preparation of size controllability spherical mesoporous carbon with magnetite nanoparticles2013

    • Author(s)
      Toshihide Horikawa, et al.
    • Organizer
      The Annual World Conference on Carbon (Carbon2013)
    • Place of Presentation
      Windsor Atlantica Hotel (Rio de Janeiro, Brazil)
    • Related Report
      2012 Research-status Report
  • [Presentation] 磁性ナノ粒子複合球状炭化物の製造とその細孔特性2012

    • Author(s)
      長谷川拓磨, 堀河俊英, 外輪健一郎
    • Organizer
      化学工学会高松大会
    • Place of Presentation
      サンポートホール高松(香川県)
    • Related Report
      2013 Final Research Report
  • [Presentation] 細孔構造の異なる多孔質炭素への水蒸気吸着の温度依存性2012

    • Author(s)
      竹ノ内雅典, 堀河俊英,坂尾倫幸, 外輪健一郎, Do D. D.
    • Organizer
      化学工学会高松大会
    • Place of Presentation
      サンポートホール高松(香川県)
    • Related Report
      2013 Final Research Report
  • [Presentation] Preparation of N-doped porous carbon and its water adsorpiton behavior2012

    • Author(s)
      Toshihide Horikawa, Noriyuki Sakao, Masahiro Katoh, Jun'ichi Hayashi, D. D. Do and Ken-Ichiro Sotowa
    • Organizer
      International Conference on Emerging Advanced Nanomaterials(ICEAN-2012)
    • Place of Presentation
      Mercure Hotel(Brisbane, Australia)
    • Related Report
      2013 Final Research Report
  • [Presentation] Preparation of nitrogen-doped porous carbon using N-source additive and its water adsorption behavior2012

    • Author(s)
      Toshihide Horikawa, Noriyuki Sakao, Masahiro Katoh, Jun'ichi Hayashi and D. D. Do
    • Organizer
      Chemeca2012
    • Place of Presentation
      Museum of New Zealand(Wellington, NZ)
    • Related Report
      2013 Final Research Report
  • [Presentation] Temperature dependence of water adsorpon in porous carbons2012

    • Author(s)
      Toshihide Horikawa, Noriyuki Sakao and D. D. Do
    • Organizer
      The Annual World Conference on Carbon(Carbon2012)
    • Place of Presentation
      Auditorium Maximum(Cracow, Poland)
    • Related Report
      2013 Final Research Report
  • [Presentation] Effects of Temperature on Water Adsorption in Carbons of Different Porous Structure2012

    • Author(s)
      Toshihide Horikawa, Noriyuki Sakao and D. D. Do
    • Organizer
      The 6th Pacific Basin Conference on Adsorption Science and Technology(PBAST-6)
    • Place of Presentation
      NTUH International Convention Center(Taipei, Taiwan)
    • Related Report
      2013 Final Research Report
  • [Presentation] Preparation of N-doped porous carbon and its water adsorpiton behavior2012

    • Author(s)
      Toshihide Horikawa, et al.
    • Organizer
      International Conference on Emerging Advanced Nanomaterials (ICEAN-2012)
    • Place of Presentation
      Mercure Hotel (Brisbane, Australia)
    • Related Report
      2012 Research-status Report
  • [Presentation] Preparation of nitrogen-doped porous carbon using N-source additive and its water adsorption behavior2012

    • Author(s)
      Toshihide Horikawa, et al.
    • Organizer
      Chemeca2012
    • Place of Presentation
      Museum of New Zealand Te Papa Tongarewa (Wellington, New Zealand)
    • Related Report
      2012 Research-status Report
  • [Presentation] Temperature dependence of water adsorption in porous carbons2012

    • Author(s)
      Toshihide Horikawa, et al.
    • Organizer
      The Annual World Conference on Carbon (Carbon2012)
    • Place of Presentation
      Auditorium Maximum (Krakow, Poland)
    • Related Report
      2012 Research-status Report
  • [Presentation] Effects of Temperature on Water Adsorption in Carbons of Different Porous Structure2012

    • Author(s)
      Toshihide Horikawa, et al.
    • Organizer
      The 6th Pacific Basin Conference on Adsorption Science and Technology (PBAST-6)
    • Place of Presentation
      NTUH International Convention Center (Taipei, Taiwan)
    • Related Report
      2012 Research-status Report
  • [Presentation] 磁性ナノ粒子複合球状炭化物の製造とその細孔特性2012

    • Author(s)
      長谷川 拓磨, 他
    • Organizer
      化学工学会 高松大会
    • Place of Presentation
      高松サンポート(香川県)
    • Related Report
      2012 Research-status Report
  • [Presentation] 細孔構造の異なる多孔質炭素への水蒸気吸着の温度依存性2012

    • Author(s)
      竹ノ内 雅典, 他
    • Organizer
      化学工学会 高松大会
    • Place of Presentation
      高松サンポート(香川県)
    • Related Report
      2012 Research-status Report
  • [Remarks]

    • URL

      http://www.chem.tokushima-u.ac.jp/C2/

    • Related Report
      2013 Final Research Report
  • [Remarks] 徳島大学大学院ソシオテクノサイエンス研究部 化学C-2講座HP

    • URL

      http://www.chem.tokushima-u.ac.jp/C2/

    • Related Report
      2012 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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