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Development of a new treatment method of ammonia-containing wastewater with photocatalyst

Research Project

Project/Area Number 24750149
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental chemistry
Research InstitutionTokai University

Principal Investigator

MIKAMI IKKO  東海大学, 理学部, 講師 (80433902)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords水処理 / 光触媒 / アンモニア / 排水処理 / 窒素生成 / 酸化チタン / パラジウム / 水質汚濁防止 / グリーンケミストリー
Research Abstract

The oxidation of aqueous ammonia over a metal-loaded TiO2 photocatalyst was investigated as a noble method for purification of ammonia-containing wastewater. It was found that the reaction proceeded with high decomposition rate at pH 10 under air flow. The use of a high initial concentration of ammonia and adjusting the pH to 10 with NaOH(aq) promote decomposition of ammonia with high selectivity for dinitrogen that is favorite product. The treatment of ammonia with higher decomposition rate and selectivity for dinitrogen was achieved when palladium was used as a co-catalyst on TiO2.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (23 results)

All 2014 2013 2012

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (20 results)

  • [Journal Article] Photocatalytic Oxidation of Aqueous Ammonia in the Presence of Oxygen over Palladium-loaded TiO22013

    • Author(s)
      Satoshi Shibuya, Daisuke Yokoyama, Yoshika Sekine, Ikko Mikami
    • Journal Title

      Chem. Lett.

      Volume: Vol.42 Issue: 9 Pages: 1082-1083

    • DOI

      10.1246/cl.130474

    • NAID

      10031194349

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Influence of Oxygen Addition on Photocatalytic Oxidation of Aqueous Ammonia over Platinum-loaded TiO_22013

    • Author(s)
      Satoshi Shibuya, Satoshi Aoki, Yoshika Sekine, Ikko Mikami
    • Journal Title

      Appl. Cat. B

      Volume: Vol.138–139 Pages: 294-298

    • DOI

      10.1016/j.apcatb.2013.03.003

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic Oxidation of Aqueous Ammonia in the Presence of Oxygen over Palladium-loaded TiO22013

    • Author(s)
      Satoshi Shibuya, Daisuke Yokoyama, Yoshika Sekine, Ikko Mikami
    • Journal Title

      Chemistry Letters

      Volume: 42 Pages: 1082-1083

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 金属担持酸化チタンによる酸素共存下での水中アンモニアの光触媒的分解に対する過酸化水素の影響2014

    • Author(s)
      渋谷智史, 相沢純一, 関根嘉香, 三上一行
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] 金属担持酸化チタンによる酸素共存下での水中アンモニアの光触媒的分解に対する過酸化水素の影響2014

    • Author(s)
      渋谷智史,相沢純一,関根嘉香,三上一行
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水中アンモニアの光触媒的酸化分解に及ぼすTiO_2光触媒と無機吸着材の複合効果の検討2013

    • Author(s)
      渋谷智史, 大杉あやめ, 阿部真理子, 関根嘉香, 三上一行
    • Organizer
      第三回化学フェスタ
    • Place of Presentation
      東京
    • Year and Date
      2013-10-22
    • Related Report
      2013 Final Research Report
  • [Presentation] Pd-TiO_2光触媒を用いた水中アンモニアの酸化分解においてPdの存在状態が分解速度や選択率に与える影響2013

    • Author(s)
      星川健, 渋谷智史, 石原良美, 三上一行
    • Organizer
      第三回化学フェスタ
    • Place of Presentation
      東京
    • Year and Date
      2013-10-22
    • Related Report
      2013 Final Research Report
  • [Presentation] Photocatalytic oxidation of aqueous ammonia in the presence of oxygen over Palladium-loaded TiO_22013

    • Author(s)
      Satoshi Shibuya, Daisuke Yokoyama, Ken Hoshikawa, Yoshika Sekine, Ikko Mikami
    • Organizer
      6th Asia-Pacific Congress on Catalysis
    • Place of Presentation
      台北
    • Year and Date
      2013-10-14
    • Related Report
      2013 Final Research Report
  • [Presentation] Pt-TiO_2およびPd-TiO_2を用いた酸素共存下での水中アンモニアの光触媒的酸化特性の比較2013

    • Author(s)
      渋谷智史, 関根嘉香, 三上一行
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田
    • Year and Date
      2013-09-18
    • Related Report
      2013 Final Research Report
  • [Presentation] Influence of adsorption amount of ammonia on Pt-loaded TiO_2 on photocatalytic oxidation of aqueous ammonia in the presence of oxygen2013

    • Author(s)
      Satoshi Shibuya, Yoshika Sekine, Ikko Mikami
    • Organizer
      14th Japan-Korea Symposium on Catalysis
    • Place of Presentation
      名古屋
    • Year and Date
      2013-07-01
    • Related Report
      2013 Final Research Report
  • [Presentation] Influence of adsorption amount of ammonia on Pt-loaded TiO2 on photocatalytic oxidation of aqueous ammonia in the presence of oxygen2013

    • Author(s)
      Satoshi Shibuya, Yoshika Sekine, Ikko Mikami
    • Organizer
      14th Japan-Korea Symposium on Catalysis
    • Place of Presentation
      愛知県産業労働センター
    • Related Report
      2013 Annual Research Report
  • [Presentation] Pt-TiO2およびPd-TiO2を用いた酸素共存下での水中アンモニアの光触媒的酸化特性の比較2013

    • Author(s)
      渋谷智史,関根嘉香,三上一行
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Photocatalytic oxidation of aqueous ammonia in the presence of oxygen over Palladium-loaded TiO22013

    • Author(s)
      Satoshi Shibuya, Daisuke Yokoyama, Ken Hoshikawa, Yoshika Sekine, Ikko Mikami
    • Organizer
      6th Asia-Pacific Congress on Catalysis
    • Place of Presentation
      Taipei International Convention Center (中華民国)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Pd-TiO2光触媒を用いた水中アンモニアの酸化分解においてPdの存在状態が分解 速度や選択率に与える影響2013

    • Author(s)
      星川 健, 渋谷智史, 石原良美, 三上一行
    • Organizer
      第三回化学フェスタ
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水中アンモニアの光触媒的酸化分解に及ぼすTiO2光触媒と無機吸着材の複合効果の検討2013

    • Author(s)
      渋谷智史, 大杉あやめ, 阿部真理子, 関根嘉香, 三上一行
    • Organizer
      第三回化学フェスタ
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2013 Annual Research Report
  • [Presentation] 酸化チタンを用いた水中アンモニアの光触媒的分解における生成物選択性に影響する因子についての検討2012

    • Author(s)
      渋谷智史, 横山大輔, 関根嘉香, 三上一行
    • Organizer
      第二回化学フェスタ
    • Place of Presentation
      東京
    • Year and Date
      2012-10-15
    • Related Report
      2013 Final Research Report
  • [Presentation] Ti系複合酸化物による水中アンモニアの光触媒的酸化分解2012

    • Author(s)
      星川健, 渋谷智史, 石原良美, 三上一行
    • Organizer
      第二回化学フェスタ
    • Place of Presentation
      東京
    • Year and Date
      2012-10-15
    • Related Report
      2013 Final Research Report
  • [Presentation] パラジウム担持酸化チタン光触媒による酸素共存下での水中アンモニアの酸化分解2012

    • Author(s)
      渋谷智史, 横山大輔, 関根嘉香, 三上一行
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      福岡
    • Year and Date
      2012-09-24
    • Related Report
      2013 Final Research Report
  • [Presentation] Photocatalytic oxidation of aqueous ammonia over Pt-TiO_2 in the presense of oxygen2012

    • Author(s)
      Ikko Mikami, Satoshi Shibuya, Yoshika Sekine
    • Organizer
      7^<th> International Conference on Environmental Catalysis
    • Place of Presentation
      リヨン
    • Year and Date
      2012-09-03
    • Related Report
      2013 Final Research Report
  • [Presentation] Photocatalytic oxidation of aqueous ammonia over Pt-TiO2 in the presense of oxygen2012

    • Author(s)
      Ikko Mikami, Satoshi Shibuya, Yoshika Sekine
    • Organizer
      7th International Conference on Environmental Catalysis
    • Place of Presentation
      Lyon, France
    • Related Report
      2012 Research-status Report
  • [Presentation] パラジウム担持酸化チタン光触媒による酸素共存下での水中アンモニアの酸化分解2012

    • Author(s)
      渋谷智史,横山大輔,関根嘉香,三上一行
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      九州大学 (伊都キャンパス、福岡)
    • Related Report
      2012 Research-status Report
  • [Presentation] Ti系複合酸化物による 水中 アンモニアの光触媒的酸化分解2012

    • Author(s)
      星川 健,渋谷智史,石原良美,三上 一行
    • Organizer
      第二回化学フェスタ
    • Place of Presentation
      東京工業大学 (大岡山キャンパス、東京)
    • Related Report
      2012 Research-status Report
  • [Presentation] 酸化チタンを用いた水中アンモニアの光触媒的分解における生成物選択性に影響する因子についての検討2012

    • Author(s)
      渋谷智史,横山大輔,関根嘉香,三上一行
    • Organizer
      第二回化学フェスタ
    • Place of Presentation
      東京工業大学 (大岡山キャンパス、東京)
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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