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Thermal annealing effect of organic solar cells using organofullerene/solvent co-crystals

Research Project

Project/Area Number 24750177
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials/Devices
Research InstitutionThe University of Tokyo

Principal Investigator

TANAKA HIDEYUKI  東京大学, 理学(系)研究科(研究院), 特任助教 (10585821)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords有機太陽電池 / フラーレン / 溶媒和 / 自己組織化 / 有機半導体 / ナノ構造 / 有機エレクトロニクス / 有機トランジスタ / 電子受容体 / 電荷移動度 / 有機ラジカル / 柔粘性結晶 / アニール効果
Research Abstract

We examined a thermal annealing effect of organic solar cells by using organo/solvent co-crystals. Electron mobility of the co-crystal of fullerene was decreased by the phase transition to amorphous mesophase under the heating, and it was then, increased by the thermal crystallization at the high temperature annealing. The changes of the electron mobility, however, did not correlated with the photovoltaic performance. Rather, performance was maximized when the mobility was minimized at the amorphous mesophase. The result suggesting that the molecular level contact at interface between the donor and acceptor become a crucial factor for the solar cells.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (14 results)

All 2014 2013 2012 Other

All Journal Article (6 results) (of which Peer Reviewed: 4 results) Presentation (8 results) (of which Invited: 1 results)

  • [Journal Article] Mobility of Long-Lived Fullerene Radical in Solid State and Nonlinear Temperature Dependence2014

    • Author(s)
      Y. Abe, H. Tanaka, Y. Guo, Y. Matsuo, E. Nakamura
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Issue: 9 Pages: 3366-3369

    • DOI

      10.1021/ja500340f

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of a Polycrystalline Film of Donor Material on PEDOT : PSS Buffer Induced by Crystal Nucleation2014

    • Author(s)
      K. Harano, S. Okada, S. Furukawa, H. Tanaka, E. Nakamura
    • Journal Title

      J. Polym. Sci. Part B : Polym. Phys.

      Volume: 52 Issue: 12 Pages: 833-841

    • DOI

      10.1002/polb.23493

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Empirical evidence for identical band gaps in substituted C60 and C70 based fullerenes2014

    • Author(s)
      Lars Mattias Andersson, Hideyuki Tanak
    • Journal Title

      Appl. Phys. Lett.

      Volume: 104 Issue: 4 Pages: 43304-43304

    • DOI

      10.1063/1.4863438

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] An Amorphous Mesophase Generated by Thermal Annealing for High-Performance Organic Photovoltaic Devices2012

    • Author(s)
      H. Tanaka, Y. Abe, Y. Matsuo, J. Kawai, I. Soga, Y. Sato, E. Nakamura
    • Journal Title

      Adv. Mater.

      Volume: 24 Issue: 26 Pages: 3521-3525

    • DOI

      10.1002/adma.201200490

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] 塗布型低分子薄膜を用いた有機デバイスにおける溶媒和効果2012

    • Author(s)
      田中秀幸,松尾豊,中村栄一
    • Journal Title

      応用物理学会有機分子・バイオエレクトロニクス分科会会誌

      Volume: 24 Pages: 3521-3521

    • NAID

      10030156261

    • Related Report
      2013 Final Research Report
  • [Journal Article] 塗布型低分子薄膜を用いた有機デバイスにおける溶媒和効果2012

    • Author(s)
      田中秀幸,松尾豊,中村栄一
    • Journal Title

      Molecular Electronics and Bioelectronics

      Volume: 23 Pages: 17-22

    • NAID

      10030156261

    • Related Report
      2012 Research-status Report
  • [Presentation] Enhanced Nucleation in Thin Films of Organic Donor Materials on PEDOT : PSS2014

    • Author(s)
      Satoshi OKADA, Syunsuke FURUKAWA, Hideyuki TANAKA, Koji HARANO, Eiichi NAKAMURA
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(名古屋)
    • Related Report
      2013 Final Research Report
  • [Presentation] Enhanced Nucleation in Thin Films of Organic Donor Materials on PEDOT:PSS2014

    • Author(s)
      Satoshi OKADA, Syunsuke FURUKAWA, Hideyuki TANAKA, Koji HARANO, Eiichi NAKAMURA
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 光捕集に向けた分子アロイの創製と塗布型有機太陽電池の高効率化2013

    • Author(s)
      田中秀幸,Yonggang Zhen,岡田賢,原野幸治,松尾豊,中村栄一
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学(京都)
    • Related Report
      2013 Final Research Report
  • [Presentation] 自己組織化分子によるナノ構造の構築と有機デバイスへの応用2013

    • Author(s)
      田中秀幸
    • Organizer
      情報科学用有機材料第142委員会C部会(有機光エレクトロニクス)第55回
    • Place of Presentation
      PORUTA神楽坂(新宿区)
    • Related Report
      2013 Final Research Report
  • [Presentation] 光捕集に向けた分子アロイの創製と塗布型有機太陽電池の高効率化2013

    • Author(s)
      田中秀幸,Yonggang Zhen,岡田賢,原野幸治,松尾豊,中村栄一
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学(京都府京田辺市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Solution-processable crystalline tetrabenzoporphyrin for small molecules photovoltaic cells2012

    • Author(s)
      Hideyuki Tanaka, Yoshiharu Sato, Naoki Obata, Iwao Soga, Eiichi Nakamura
    • Organizer
      The 2012 International Conference on Flexible and Printed Electronics
    • Place of Presentation
      The Univ. of Tokyo (Tokyo)
    • Related Report
      2013 Final Research Report
  • [Presentation] Solution-processable crystalline tetrabenzoporphyrin for small molecules photovoltaic cells2012

    • Author(s)
      H. Tanaka, Y. Sato, N. Obata, I. Soga, E. Nakamura
    • Organizer
      The 2012 International Conference on Flexible and Printed Electronics
    • Place of Presentation
      The Univ. of Tokyo
    • Related Report
      2012 Research-status Report
  • [Presentation] 自己組織化分子によるナノ構造の構築と有機デバイスへの応用

    • Author(s)
      田中秀幸
    • Organizer
      情報科学用有機材料第142委員会 C部会(有機光エレクトロニクス)第55回
    • Place of Presentation
      PORUTA神楽坂(東京都新宿区)
    • Related Report
      2013 Annual Research Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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