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Development of quality organic transistors fabricated by solution process at room temperature using supercooled liquid crystal phase

Research Project

Project/Area Number 24750178
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials/Devices
Research InstitutionTokyo Institute of Technology

Principal Investigator

IINO Hiroaki  東京工業大学, 像情報工学研究所, 准教授 (50432000)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords過冷却液晶相 / アニール / 高移動度 / 有機トランジスタ / 多結晶薄膜 / 溶液プロセス / 耐熱性 / 液晶性 / ボトムコンタクト / コンタクト抵抗 / 過冷却 / 熱アニール / バイレイヤー構造
Outline of Final Research Achievements

I have investigated the organic transistor materials having supercooled liquid crystal phase in order to realize both high solution processability and high thermal durability of polycrystalline thin films. The developed materials having a supercooled liquid crystal phase show high solution processability at room temperature and high FET mobility over 10cm2/Vs after thermal annealing at 120 oC for 5minutes, despite of polycrystalline thin films. Furthermore, the high mobility is hardly changed after thermal stress up to 140 oC because the materials have an asymmetric phase transition behavior in cooling and heating process. I succeeded the development of quality organic transistors materials having high solution processability, high thermal durability, and high mobility.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (42 results)

All 2015 2014 2013 2012

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (33 results) (of which Invited: 5 results)

  • [Journal Article] Liquid crystals for organic thin-film transistors2015

    • Author(s)
      Hiroaki Iino, Takayuki Usui, and Jun-ichi Hanna
    • Journal Title

      NATURE COMMUNICATIONS

      Volume: 6 Issue: 1 Pages: 6828-6828

    • DOI

      10.1038/ncomms7828

    • NAID

      120006582416

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 液晶物質の結晶性有機半導体材料としての有用性とその有機トランジスター応用2014

    • Author(s)
      飯野裕明
    • Journal Title

      液晶

      Volume: 18 Pages: 90-99

    • NAID

      130005434686

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 液晶物質の結晶性有機半導体材料としての有用性とその有機トランジスタ応用2014

    • Author(s)
      飯野裕明
    • Journal Title

      液晶

      Volume: 18 Pages: 90-99

    • NAID

      130005434686

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Charge carrier transport in liquid crystals2014

    • Author(s)
      J. Hanna, A. Ohno, and H. Iino
    • Journal Title

      Thin Solid Films

      Volume: 554 Pages: 58-63

    • DOI

      10.1016/j.tsf.2013.10.051

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Organic Light Emitting Diode with Highly Ordered Polycrystalline Thin Film2013

    • Author(s)
      K. Nakano, T. Kobori, Y. Takayashiki, H. Iino, J. Hanna
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 5S1 Pages: 05DC14-05DC14

    • DOI

      10.7567/jjap.52.05dc14

    • NAID

      210000142240

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 液晶性有機半導体/ 電極界面の電子構造IV:液晶状態でのイオン化エネルギーの測定2013

    • Author(s)
      谷忠昭、飯野裕明、大野玲、半那純一
    • Journal Title

      日本写真学会誌

      Volume: 76 Pages: 119-124

    • NAID

      130004567223

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 電極/ 液晶性有機半導体界面の電子構造V:電極の仕事関数の変化の分析2013

    • Author(s)
      谷忠昭、飯野裕明、内田孝幸、半那純一
    • Journal Title

      日本写真学会誌

      Volume: 76 Pages: 318-323

    • NAID

      130004685711

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] High Uniformity and High Thermal Stability of Solution-Processed Polycrystalline Thin Films by Utilizing Highly Ordered Smectic Liquid Crystals2012

    • Author(s)
      H. Iino, T. Kobori, and J. Hanna
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 51 Issue: 11S Pages: 11PD02-11PD02

    • DOI

      10.1143/jjap.51.11pd02

    • NAID

      210000141619

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Improved thermal stability in organic FET fabricated with a soluble BTBT derivative2012

    • Author(s)
      Hiroaki Iino, Takeo Kobori, Jun-ichi Hanna
    • Journal Title

      Journal of Non crystalline solid

      Volume: (印刷中) Issue: 17 Pages: 2516-2519

    • DOI

      10.1016/j.jnoncrysol.2012.03.021

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 液晶性フェニルBTBT誘導体を用いた有機トランジスタ-アルキル鎖長依存性-2015

    • Author(s)
      飯野裕明、臼井孝之、半那純一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機トランジスタ用材料が液晶物質であるべき12の理由2015

    • Author(s)
      飯野裕明、半那純一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] モノアルキル置換Ph-BTBT誘導体を用いたFETの作製と特性評価―アルキル鎖長依存性―2015

    • Author(s)
      飯野裕明、岡村寿、臼井孝之、半那純一
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Ph-BTBT-10多結晶薄膜を用いたBottom-gate Bottom-contact型FETの作製と特性評価2015

    • Author(s)
      飯野裕明、臼井孝之、半那純一
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Availability of liquid crystallinity as organic transistor materials2014

    • Author(s)
      Hiroaki Iino and Jun-ichi Hanna
    • Organizer
      11th International Conference on Nano-Molecular Electronics
    • Place of Presentation
      Kobe(Japan)
    • Year and Date
      2014-12-17 – 2014-12-19
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Printed Electronics 用有機半導体材料における高次配向秩序液晶相の重要性-有機トランジスタ用材料がSmE 相を示す液晶物質であるべき12 の理由-2014

    • Author(s)
      飯野裕明、岡村寿、臼井孝之、半那純一
    • Organizer
      画像関連学会連合会第一回秋季合同大会
    • Place of Presentation
      京都
    • Year and Date
      2014-11-20 – 2014-11-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] Ph-BTBT-10 有機トランジスタのソースドレインコンタクト特性の改善2014

    • Author(s)
      飯野裕明、臼井孝之、半那純一
    • Organizer
      画像関連学会連合会第一回秋季合同大会
    • Place of Presentation
      京都
    • Year and Date
      2014-11-20 – 2014-11-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 液晶性を活用した多結晶有機半導体とその有機トランジスタ応用2014

    • Author(s)
      飯野裕明
    • Organizer
      電気学会調査専門委員会(ADEI1141)
    • Place of Presentation
      東京
    • Year and Date
      2014-11-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 液晶性有機半導体Ph-BTBT誘導体の多結晶薄膜トランジスタの特性評価2014

    • Author(s)
      飯野裕明、岡村寿、臼井孝之、半那純一
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] ボトムゲート・ボトムコンタクト型Ph-BTBT-10 FET の低電圧駆動特性2014

    • Author(s)
      國井正文、飯野裕明、半那純一
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 液晶物質の結晶性半導体材料としての有用性とその有機トランジスタ応用2014

    • Author(s)
      飯野裕明
    • Organizer
      2014年 日本液晶学会 討論会
    • Place of Presentation
      島根
    • Year and Date
      2014-09-08 – 2014-09-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] スメクチックE 相薄膜を活性層とする室温動作・高移動度の有機トランジスタの特性評価2014

    • Author(s)
      飯野裕明、岡村寿、半那純一
    • Organizer
      2014年 日本液晶学会 討論会
    • Place of Presentation
      島根
    • Year and Date
      2014-09-08 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] 液晶性有機半導体Ph-BTBT-10 を用いた溶液プロセスによるボトムゲートボトムコンタクト型FET の作製2014

    • Author(s)
      佐藤大気、飯野裕明、半那純一
    • Organizer
      Imaging Conference JAPAN 2014
    • Place of Presentation
      神奈川
    • Year and Date
      2014-06-11 – 2014-06-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] マイクロコンタクトプリンティング法を用いた液晶性有機半導体薄膜のパターニング手法の開発とTFT応用2014

    • Author(s)
      小池雄太、飯野裕明、半那純一
    • Organizer
      Imaging Conference JAPAN 2014
    • Place of Presentation
      神奈川
    • Year and Date
      2014-06-11 – 2014-06-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] 移動度10cm2/Vs を超す多結晶有機トランジスタ材料の開発2014

    • Author(s)
      飯野裕明、岡村寿、臼井孝之、半那純一
    • Organizer
      Imaging Conference JAPAN 2014
    • Place of Presentation
      神奈川
    • Year and Date
      2014-06-11 – 2014-06-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] 液晶性有機半導体Ph-BTBT-10の熱アニールによる高移動度化と結晶構造変化2014

    • Author(s)
      飯野裕明、臼井孝之、半那純一
    • Organizer
      2014年度日本写真学会年次大会
    • Place of Presentation
      千葉
    • Year and Date
      2014-05-26 – 2014-05-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 溶液プロセスによる高移動度Ph-BTBT-10ボトムゲート・ボトムコンタクト型FETの作製2014

    • Author(s)
      佐藤大気、飯野裕明、半那純一
    • Organizer
      2014年度日本写真学会年次大会
    • Place of Presentation
      千葉
    • Year and Date
      2014-05-26 – 2014-05-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] High FET mobilities in organic field effect transistors with highly ordered smectic liquid crystals2014

    • Author(s)
      H. Iino, H. Okamura, T. Usui, J. Hanna
    • Organizer
      2nd international symposium on self-organizing molecular semiconductors
    • Place of Presentation
      Tokyo (Japan)
    • Related Report
      2013 Research-status Report
  • [Presentation] 液晶性を活用した高品質・高耐熱性を有する有機薄膜トランジスタの実現2014

    • Author(s)
      飯野裕明, 臼井孝之, 半那純一
    • Organizer
      映像情報メディア学会 ディスプレイ材料・製造技術シンポジウム
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Ph-BTBT-10の単結晶構造解析と多結晶薄膜の分子配向2014

    • Author(s)
      飯野裕明, 臼井孝之, 半那 純一
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Related Report
      2013 Research-status Report
  • [Presentation] 後処理による有機トランジスタの高移動度化-フェニルBTBT誘導体-2014

    • Author(s)
      飯野裕明, 臼井孝之, 半那 純一
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      愛知
    • Related Report
      2013 Research-status Report
  • [Presentation] High performance liquid crystalline organic field effect transistor materials: How does the liquid crystallinity solve problems in conventional soluble OFET materials?2013

    • Author(s)
      H. Iino, T. Usui, J. Hanna
    • Organizer
      SPIE Optics + Photonics 2013
    • Place of Presentation
      San Diego (USA)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 液晶性有機半導体材料を用いた実用的な有機トランジスタの開発 -プロセスの改良による低温製膜化と高移動度の実現-2013

    • Author(s)
      飯野裕明, 臼井孝之, 半那 純一
    • Organizer
      Imaging Conference JAPAN 2013
    • Place of Presentation
      横浜
    • Related Report
      2013 Research-status Report
  • [Presentation] 液晶性有機半導体を用いたトランジスタ材料の高品質化2013

    • Author(s)
      飯野裕明, 臼井孝之, 半那 純一
    • Organizer
      2013年度 日本写真学会年次大会
    • Place of Presentation
      千葉
    • Related Report
      2013 Research-status Report
  • [Presentation] 液晶性有機半導体を用いたトランジスタ材料の製膜温度の低温化2013

    • Author(s)
      飯野裕明, 臼井孝之, 半那 純一
    • Organizer
      2013年度 日本写真学会年次大会
    • Place of Presentation
      千葉
    • Related Report
      2013 Research-status Report
  • [Presentation] 液晶性有機半導体材料を用いた移動度10cm2/Vsを超える有機多結晶トランジスタの実現2013

    • Author(s)
      飯野裕明, 臼井孝之, 半那 純一
    • Organizer
      2013年日本液晶学会討論会
    • Place of Presentation
      大阪
    • Related Report
      2013 Research-status Report
  • [Presentation] Ph-BTBT-10 多結晶薄膜の熱アニールによる移動度向上と結晶構造変化2013

    • Author(s)
      飯野裕明, 臼井孝之, 半那 純一
    • Organizer
      第74回応用物理学会学術講演会
    • Place of Presentation
      京都
    • Related Report
      2013 Research-status Report
  • [Presentation] Improved fabrication of polycrystalline thin films of liquid crystalline organic semiconductors for FET applications2013

    • Author(s)
      Hiroaki Iino, Takayuki Usui, Jun-ichi Hanna
    • Organizer
      Seventh International Conference on Molecular Electronics and Bioelectronics
    • Place of Presentation
      Fukuoka (Japan)
    • Related Report
      2012 Research-status Report
  • [Presentation] High FET mobility and high thermal stability in solution-processed liquid crystals2012

    • Author(s)
      Hiroaki Iino, Takayuki Usui, Takeo Kobori, Jun-ichi Hanna
    • Organizer
      24th International Liquid Crystal Conference
    • Place of Presentation
      Mainz (Germany)
    • Related Report
      2012 Research-status Report
  • [Presentation] Highly Thermally-Stable OFETs Fabricated with Liquid Crystalline2012

    • Author(s)
      Hiroaki Iino, Takayuki Usui, Takeo Kobori, Jun-ichi Hanna
    • Organizer
      Society for infomation display, Display Week 2012
    • Place of Presentation
      Boston (USA)
    • Related Report
      2012 Research-status Report
  • [Presentation] New Strategy for Molecular Design of Solution-processable OFET Materials with High Mobility and High Thermal Stability2012

    • Author(s)
      Hiroaki Iino, Takayuki Usui, Takeo Kobori, Jun-ichi Hanna
    • Organizer
      2012 Materials Research Society Spring Meeting
    • Place of Presentation
      San Francisco (USA)
    • Related Report
      2012 Research-status Report
  • [Presentation] Solution Processability of Highly Ordered Smectic Liquid Crystals for FET Applications2012

    • Author(s)
      Hiroaki Iino, Takayuki Usui, Takeo Kobori, Jun-ichi Hanna
    • Organizer
      The 2012 International Conference on Flexible and Printed Electronics
    • Place of Presentation
      Tokyo (Japan)
    • Related Report
      2012 Research-status Report
  • [Presentation] High mobility in solution-processed polycrystalline thin films of highly ordered smectic liquid crystals at 65 oC2012

    • Author(s)
      Hiroaki Iino, Takayuki Usui, Takeo Kobori, Jun-ichi Hanna
    • Organizer
      10th International Conference on Nano-Molecular Electronics
    • Place of Presentation
      Awaji (Japan)
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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