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Orientation Control of Both p-type and n-type Rod-shape Molecules in Films and Anisotropic Electronic Properties of Organic Photovoltaics Based on These Films

Research Project

Project/Area Number 24750189
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials/Devices
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

MIZOKURO Toshiko  独立行政法人産業技術総合研究所, ユビキタスエネルギー研究部門, 主任研究員 (90358101)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords分子配向制御 / 摩擦転写 / 導電性高分子 / 鎖状分子 / 有機薄膜太陽電池 / 構造解析 / 導電性オリゴマー / 薄膜プロセス
Outline of Final Research Achievements

P-type lod-shape molecules were deposited in vacuum on conductive polymer films, in which polymer chains were oriented parallel to the substrate planes formed by the friction transfer method, resulting in the formation of the oriented lod-shape molecular films parallel to the direction of the oriented polymer chains. Then, n-type lod-shape molecules were deposited on the oriented p-type lod-shape molecules, p-n and p-i junction layers, in which both n-type and p-type lod-shape molecules were oriented parallel to the substrate planes, were fabricated. Organic photovoltaic device performance based on these oriented layers as active layers was higher than that based on non-oriented layers parallel to the substrate planes, showing that orientation control of both p-type and n-type lod-shape molecules in these layers parallel to the substrate planes leads to anisotropic electronic physical properties of these layers.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (13 results)

All 2015 2014 2013

All Journal Article (2 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 2 results) Presentation (11 results) (of which Invited: 3 results)

  • [Journal Article] Orientation of rod-shape molecule, 2,2’-Bis[4-(trifluoromethyl)phenyl]-5,5’-bithiazole films deposited in a vacuum on oriented α-sexithiophene films2015

    • Author(s)
      溝黒 登志子、Heck Claire、谷垣 宣孝
    • Journal Title

      Molecular Crystals and Liquid Crystals

      Volume: 印刷中

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 摩擦転写膜による棒状有機半導体分子の配向誘起-光電変換素子応用を目指して-2015

    • Author(s)
      谷垣 宣孝、藤澤 拓平、竹内 啓祐、溝黒 登志子、Heck Claire、青田 浩幸
    • Journal Title

      電子情報通信学会技術研究報告

      Volume: 印刷中

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Presentation] 摩擦転写膜による棒状有機半導体分子の配向誘起-光電変換素子応用を目指して-2015

    • Author(s)
      谷垣 宣孝、藤澤 拓平、竹内 啓祐、溝黒 登志子、Heck Claire、青田 浩幸
    • Organizer
      有機エレクトロニクス研究会
    • Place of Presentation
      分子科学研究所(岡崎市)
    • Year and Date
      2015-01-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Oriented Films of n-type Semiconducting Rod-like Molecules on Friction-Transferred Polymer Films2014

    • Author(s)
      溝黒 登志子、竹内 啓祐、Heck Claire、青田 浩幸、谷垣 宣孝
    • Organizer
      The 14th International Symposium on Advanced Organic Photonics (ISAOP-14)
    • Place of Presentation
      大阪大学吹田キャンパス(大阪府吹田市)
    • Year and Date
      2014-11-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Orientation of rod-shape molecule, 2,2’-Bis[4-(trifluoromethyl)phenyl]-5,5’-bithiazole films deposited in a vacuum on oriented α-sexithiophene films2014

    • Author(s)
      溝黒 登志子、Heck Claire、谷垣 宣孝
    • Organizer
      KJF International Conference on Organic Materials for Electronics and Photonics
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Year and Date
      2014-09-22
    • Related Report
      2014 Annual Research Report
  • [Presentation] テトラデカフルオロ-α-セキシチオフェン薄膜の配向評価および有機薄膜太陽電池への応用2014

    • Author(s)
      竹内 啓祐、溝黒 登志子、Heck Claire、青田 浩幸、谷垣 宣孝
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場(名古屋市)
    • Year and Date
      2014-05-28
    • Related Report
      2014 Annual Research Report 2013 Research-status Report
  • [Presentation] 摩擦転写膜を利用した棒状半導体分子の配向制御2014

    • Author(s)
      谷垣 宣孝、竹内 啓祐、藤澤 拓平、溝黒 登志子、Heck Claire、青田 浩幸、柴田 陽生、小金澤 智之、吉田 郵司
    • Organizer
      2014年 第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス (神奈川県)
    • Related Report
      2013 Research-status Report
  • [Presentation] 一軸配向したポリチオフェンおよびα-セキシチオフェン膜上に真空蒸着したビチアゾール系鎖状オリゴマー薄膜の配向評価2013

    • Author(s)
      溝黒 登志子、Heck Claire、谷垣 宣孝
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会議場(京都市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 有機薄膜太陽電池への応用を目指したフッ素化オリゴマーの配向制御2013

    • Author(s)
      竹内 啓祐、溝黒 登志子、Heck Claire、青田 浩幸、谷垣 宣孝
    • Organizer
      第59回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県民会館(神戸市中央区)
    • Related Report
      2013 Research-status Report
  • [Presentation] Orientation of rod-shape molecule, 2,2’-Bis[4-(trifluoromethyl)phenyl]-5,5’-bithiazole films deposited in a vacuum on oriented polythiophene and α-sexithiophene films2013

    • Author(s)
      溝黒 登志子、Heck Claire、谷垣 宣孝
    • Organizer
      6th East Asia Symposium on Functional Dyes and Advanced Materials
    • Place of Presentation
      Hsinchu, Taiwan
    • Related Report
      2013 Research-status Report
  • [Presentation] 配向したポリチオフェンおよびα-セキシチオフェン膜上に真空蒸着したn型鎖状分子薄膜の配向制御(1):テトラデカフルオロ-α-セキシチオフェン2013

    • Author(s)
      竹内 啓祐、溝黒 登志子、Heck Claire、青田 浩幸、谷垣 宣孝
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学 角間キャンパス (金沢市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 配向したポリチオフェンおよびα-セキシチオフェン膜上に真空蒸着したn型鎖状分子薄膜の配向制御(2):パーフルオロペンタセン2013

    • Author(s)
      溝黒 登志子、竹内 啓祐、Heck Claire、青田 浩幸、谷垣 宣孝
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学 角間キャンパス (金沢市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Control of Semiconducting Oligomer Orientation on Oriented Polythiophene films for Photovoltaic Application2013

    • Author(s)
      溝黒 登志子、竹内 啓祐、Heck Claire、青田 浩幸、谷垣 宣孝
    • Organizer
      The 13th International Symposium on Advanced Organic Photonics (ISAOP-13)
    • Place of Presentation
      The Univ. Club at Queen's, Kingston, Ontario, Canada
    • Related Report
      2013 Research-status Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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