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Fine control of specific molecular adsorptivity on a porous coordination polymer by surface modification

Research Project

Project/Area Number 24750200
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

KONDO Atsushi  東京農工大学, 工学(系)研究科(研究院), 助教 (60533619)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2012: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords多孔体 / 吸着 / 配位高分子 / 表面 / MOF
Research Abstract

Focused on the unique function of a crystalline porous coordination polymer, which is selective CO2 adsorption accompanied with structural change, modification of the material by secondary organic ligands was performed for fine control of the adsorptivity. Based on the several analytical experiments, the modified materials contain quite small amount of the secondary organic ligands, and however they surprisingly adsorb a hydrocarbon at near room temperature that the pristine material cannot adsorb at the same condition. Evaluation of the modified materials with gas molecules clearly indicated structural change of the materials through the adsorption, indicating a success to give a new function on the materials.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (5 results)

All 2014 2013

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (4 results) (of which Invited: 1 results)

  • [Journal Article] Tuning of Gate Adsorption: Modification of a Flexible Metal-Organic Framework by Secondary Organic Lignads2014

    • Author(s)
      Atsushi Kondo, Takuro Fujii, Kazuyuki Maeda
    • Journal Title

      Dalton Transactions

      Volume: 43 Issue: 22 Pages: 8174-8177

    • DOI

      10.1039/c4dt00116h

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Presentation] 柔軟な高分子状金属錯体の特異的吸着挙動2014

    • Author(s)
      近藤篤
    • Organizer
      分子科学研究所研究会、金属クラスター錯体・高分子状金属錯体を舞台とした構造・機能の最前線
    • Place of Presentation
      愛知・分子科学研究所
    • Related Report
      2013 Final Research Report
  • [Presentation] 柔軟な高分子状金属錯体の特異的吸着現象2014

    • Author(s)
      近藤篤
    • Organizer
      分子研研究会、金属クラスター錯体・高分子状金属錯体を舞台とした構造・機能の最前線
    • Place of Presentation
      分子科学研究所
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 第二異種配位子を用いた柔軟性二次元配位高分子の吸着特性制御2013

    • Author(s)
      藤井拓郎、近藤篤、前田和之
    • Organizer
      第64回コロイドおよび界面化学討論会
    • Place of Presentation
      愛知・名古屋工業大学
    • Related Report
      2013 Final Research Report
  • [Presentation] 第二異種配位子を用いた柔軟性2次元配位高分子の吸着特性制御2013

    • Author(s)
      藤井卓郎、近藤篤、前田和之
    • Organizer
      第64回コロイドおよび界面化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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