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Photochemical reaction induced by enzymes intercalated into layered semiconductors

Research Project

Project/Area Number 24750205
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionNagasaki University

Principal Investigator

KAMADA Kai  長崎大学, 工学(系)研究科(研究院), 准教授 (90315284)

Co-Investigator(Renkei-kenkyūsha) SOH Nobuaki  佐賀大学, 農学部, 准教授 (90336008)
Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords固定化酵素 / 層状物質 / 酸化物半導体 / インターカレーション / 光触媒
Research Abstract

In the present study, enzyme biocatalysts were intercalated into two-dimensional space composed of layered semiconductors, and a novel photo-induced enzymatic reaction of the hybrids was investigated. The layered semiconductors interstratified the enzyme molecules through electrostatic interaction in a solution with an appropriate pH. Ultraviolet light irradiation to the obtained hybrids caused activation of enzymes in the interlayer by photoabsorption of semiconductor and subsequent energy transfer. Moreover, the enzymatic activity could be easily adjusted by UV light intensity and wavelength.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (21 results)

All 2014 2013 2012

All Journal Article (9 results) (of which Peer Reviewed: 8 results) Presentation (12 results)

  • [Journal Article] Temperature Controlled Reversible Exfoliation - Stacking of Titanate Nanosheets in an Aqueous Solution Containing Tetraalkylammonium Ions2014

    • Author(s)
      Kai Kamada、Nobuaki Soh
    • Journal Title

      RSC Advances

      Volume: Vol.4、No.17 Pages: 8682-8685

    • NAID

      120006986723

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Protective Effective of Ceria Nanoparticles on Photo - Oxidative Damage of DNA2014

    • Author(s)
      Naoko Fujita、Kai Kamada
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: Vol.122、No.2 Pages: 141-145

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Temperature-Controlled Reversible Exfoliation-Stacking of Titanate Nanosheets in an Aqueous Solution Containing Tetraalkylammonium Ions2014

    • Author(s)
      Kai Kamada, Nobuaki Soh
    • Journal Title

      RSC Advances

      Volume: 4 Pages: 8682-8685

    • NAID

      120006986723

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ProtectiveEffective of Ceria Nanoparticles on Photo-oxidative Damage of DNA2014

    • Author(s)
      Naoko Fujita, Kai Kamada
    • Journal Title

      Journal of the Ceramics Society of Japan

      Volume: 122 Pages: 141-145

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visible–Light - Driven Enzymatic Reaction of Peroxidase Adsorbed on Doped Hematite Thin Films2012

    • Author(s)
      Kai Kamada、Ayano Moriyasu、Nobuaki Soh
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: Vol.116、No.39 Pages: 20694-20699

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Soft Surface Modification of Layered Titanate for Biorecognition2012

    • Author(s)
      Suguru Tsukahara、Nobuaki Soh、Kai Kamada
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: Vol.116、No.36 Pages: 19285-19289

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 酵素-層状セラミックス複合体の合成と融合機能2012

    • Author(s)
      鎌田海、宗伸明
    • Journal Title

      化学工業

      Volume: Vol.63、No.10 Pages: 39-42

    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Journal Article] Visible-light-driven enzymatic reaction of peroxidase adsorbed on doped hematite thin films2012

    • Author(s)
      Kai Kamada, Ayano Moriyasu, Nobuaki Soh
    • Journal Title

      J. Phys. Chem. C

      Volume: 116 Issue: 39 Pages: 20694-20699

    • DOI

      10.1021/jp3046559

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Soft surface modification of layered titanate for biorecognition2012

    • Author(s)
      Suguru Tsukahara, Nobuaki Soh, Kai Kamada
    • Journal Title

      J. Phys. Chem. C

      Volume: 116 Issue: 36 Pages: 19285-19289

    • DOI

      10.1021/jp304107b

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 酵素-半導体半導体複合材料を利用した酵素反応の光制御2013

    • Author(s)
      鎌田海、宗伸明
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学(長野県長野市)
    • Related Report
      2013 Final Research Report
  • [Presentation] 温度に依存した層状金属酸化物の積層-剥離挙動2013

    • Author(s)
      鎌田海、小林寿範、福田友
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学(長野県長野市)
    • Related Report
      2013 Final Research Report
  • [Presentation] Visible–light - induced Enzymatic Reaction of Peroxidase Adsorbed on Hematite Thin Films2013

    • Author(s)
      Kai Kamada、Nobuaki Soh
    • Organizer
      The 30th Japan–Korea International Seminar on Ceramics
    • Place of Presentation
      北九州国際会議場(北九州市小倉北区)
    • Related Report
      2013 Final Research Report
  • [Presentation] Temperature Dependent Reversible Exfoliation–Stacking of Layered Titanates2013

    • Author(s)
      Hisanori Kobayashi、Yu Fukuda、Kai Kamada
    • Organizer
      The 30th Japan–Korea International Seminar on Ceramics
    • Place of Presentation
      北九州国際会議場(北九州市小倉北区)
    • Related Report
      2013 Final Research Report
  • [Presentation] 酵素-半導体複合材料を利用した酵素反応の光制御2013

    • Author(s)
      鎌田 海、宗 伸明
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学(長野県長野市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 温度に依存した層状金属酸化物の積層-剥離挙動2013

    • Author(s)
      鎌田 海、小林寿範、福田 友
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学(長野県長野市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Visible-light-induced Enzymatic Reaction of Peroxidase Adsorbed on Hematite Thin Films2013

    • Author(s)
      Kai Kamada, Nobuaki Soh
    • Organizer
      The 30th Japan-Korea International Seminar on Ceramics
    • Place of Presentation
      北九州国際会議場(北九州市小倉北区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Temperature-Dependent Reversible Exfoliation-Restacking of Layered Titanates2013

    • Author(s)
      Hisanori Kobayashi, Yu Fukuda, Kai Kamada
    • Organizer
      The 30th Japan-Korea International Seminar on Ceramics
    • Place of Presentation
      北九州国際会議場(北九州市小倉北区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Layered Iron Titanate as a Physicochemically Stable Support for Hydrolase2012

    • Author(s)
      Takaharu Ikeda、Suguru Tsukahara、Nobuaki Soh、Kai Kamada
    • Organizer
      4th International Congress on Ceramics
    • Place of Presentation
      Sheraton Chicago Hotel & Towers, Chicago, USA
    • Related Report
      2013 Final Research Report
  • [Presentation] Fluorescent Inorganic Titanate Layers as Bioaffinity Reaction Markers2012

    • Author(s)
      Kai Kamada、Suguru Tsukahara、Nobuaki Soh
    • Organizer
      International Symposium on Rare Earths 2012 in Okinawa for the 30th Anniversary of The Rare Earth Society of Japan
    • Place of Presentation
      沖縄ハーバービューホテルクラウンプラザ(沖縄県那覇市)
    • Related Report
      2013 Final Research Report
  • [Presentation] Layered Iron-titanate as a Physicochemically Stable Support for Hydrolase2012

    • Author(s)
      Takaharu Ikeda, Suguru Tukahara, Nobuaki Soh, Kai Kamada
    • Organizer
      4th International Congress on Ceramics
    • Place of Presentation
      Sheraton Chicago Hotel & Towers, Chicago, USA
    • Related Report
      2012 Research-status Report
  • [Presentation] Fluorescent Inorganic Titanate Layers as Bioaffinity Reaction Markers2012

    • Author(s)
      Kai Kamada, Suguru Tsukahara, Nobuaki Soh
    • Organizer
      International Symposium on Rare Earths 2012 in Okinawa for the 30th Anniversary of The Rare Earth Society of Japan
    • Place of Presentation
      沖縄ハーバービューホテルクラウンプラザ
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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