Novel synthesis of sol-gel derived mesostructures for controlling their electro chemical behaviors

• Project/Area Number: 24750206
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Inorganic industrial materials
• Research Institution: Osaka Prefecture University
• Principal Investigator: TOKUDOME Yasuaki 大阪府立大学, 工学(系)研究科(研究院), 助教 (50613296)
• Project Period (FY): 2012-04-01 – 2014-03-31
• Project Status: Completed (Fiscal Year 2013)
• Budget Amount: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000); Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2012: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
• Keywords: ゾル－ゲル / 薄膜 / カーボン / メソポーラス / 親水化 / ナノ構造 / 多孔性材料 / カーボン系材料

Research Abstract

Mesoporous carbon films were prepared via a process that allows coating on various substrates, including metals. The mesomorphology can be controlled by changing starting composition in an appropriately-designed reaction system. Systematic characterizations have revealed that the obtained carbons exhibit structure-induced hydrophilization depending on the mesomorphology. Chemically-modified hydrophilic carbons are well known to facilitate an electrode reaction in a polar system. The materials obtained here potentially provide the similar effect.

Research Products

• [Journal Article] Responsive microstructures on organic-inorganic hybrid films (2014)
  • Author(s): Takahashi M., Suzuki K., Tokudome Y., Malfatti L., Innocenzi P.
  • Journal Title: J. Sol-Gel Sci. Technol. Volume: 未定 Issue: 2 Pages: 272-277
  • DOI: 10.1007/s10971-014-3301-0
  • Peer Reviewed / Open Access
• [Journal Article] Micropattern formation by molecular migration via UV-induced dehydration of block copolymer (2014)
  • Author(s): K. Okada, Y. Tokudome, R. Makiura, K. Konstas, L. Malfatti, P. Innocenzi, H. Ogawa, T. Kanaya, P. Falcaro, M. Takahashi
  • Journal Title: Advanced Functional Materials Volume: 24 Issue: 19 Pages: 2801-2809
  • DOI: 10.1002/adfm.201302812
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Layered double hydroxide composite monoliths with three-dimensional hierarchical channels: structural control and adsorption behavior (2014)
  • Author(s): Tarutani N., Tokudome Y., Nakanishi K., Takahashi M.
  • Journal Title: RSC Advances, Volume: ４ Issue: 31 Pages: 16075-16080
  • DOI: 10.1039/c4ra00873a
  • Peer Reviewed
• [Journal Article] Switchable and Reversible Water Adhesion on Superhydrophobic Titanate Nanostructures Fabricated on Soft Substrates : Photopatternable Wettability and Thermomodulatable Adhesivity (2013)
  • Author(s): Y. Tokudome, K. Okada, A. Nakahira, M. Takahashi
  • Journal Title: Journal of Materials Chemistry A Volume: 2 Issue: 1 Pages: 58-61
  • DOI: 10.1039/c3ta13536e
  • Peer Reviewed
• [Journal Article] Controlled Site Modification of Inorganic Networks in Hybrid Photocurable Resins for High Thermal Crack Resistance (2013)
  • Author(s): Tokudome Y., Sato T., Hidaka M., Takahashi M.
  • Journal Title: J. Sol-Gel Sci. Technol. Volume: 65 Issue: 3 Pages: 318-323
  • DOI: 10.1007/s10971-012-2938-9
  • Peer Reviewed
• [Journal Article] Layered Double Hydroxide (LDH)-based Monolith with Interconnected Hierarchical Channels : Enhanced Sorption Affinity for Anionic Species (2013)
  • Author(s): Tokudome Y., Tarutani N., Nakanishi K., Takahashi M.
  • Journal Title: J. Mater. Chem. A Volume: 1 Issue: 26 Pages: 7702-7708
  • DOI: 10.1039/c3ta11110e
  • Peer Reviewed
• [Journal Article] Hierarchical Nested Wrinkles on Silica-Polymer Hybrid Films : Stimuli-Responsive Micro Periodic Surface Architectures (2012)
  • Author(s): Tokudome Y., Suzuki K., Kitanaga T., Takahashi M.
  • Journal Title: Sci. Rep. Volume: 2 Issue: 1 Pages: 683-683
  • DOI: 10.1038/srep00683
  • Peer Reviewed
• [Presentation] Layered Double Hydroxide (LDH)-based Monolith with Interconnected Hierarchical Channels : Enhanced Sorption Affinity for Anionic Species (2014)
  • Author(s): Y. Tokudome, N. Tarutani, K. Nakanishi, M. Takahashi
  • Organizer: The 14th International Symposium on Biomimetic Materials Processing (BMMP-14)
  • Place of Presentation: Gifu, Japan
  • Year and Date: 2014-01-09
• [Presentation] Layered Double Hydroxide (LDH)-based Monolith with Interconnected Hierarchical Channels: Enhanced Sorption Affinity for Anionic Species (2014)
  • Author(s): Y. Tokudome, N. Tarutani, K. Nakanishi, M. Takahashi
  • Organizer: The 14th International Symposium on Biomimetic Materials Processing
  • Place of Presentation: Takayama, Japan
  • Invited
• [Presentation] Hierarchical nested wrinkle structures with stimuli-response on silica-polymer hybrid films (2013)
  • Author(s): K. Suzuki, Y. Tokudome, and M. Takahashi
  • Organizer: The 17th International Sol-Gel Conference
  • Place of Presentation: Madrid, Spain
  • Year and Date: 2013-08-13
• [Presentation] Spontaneous formation of crystalline hydroxide monolith with interconnected hierarchical channels : enhanced adsorption capability for anionic species (2013)
  • Author(s): Y. Tokudome, N. Tarutani, K. Nakanishi, and M. Takahashi
  • Organizer: The 17th International Sol-Gel Conference
  • Place of Presentation: Madrid, Spain
  • Year and Date: 2013-08-13
• [Presentation] Synthesis and characterization of layered double hydroxide-based monolithic material with controlled hierarchical channels (2013)
  • Author(s): N. Tarutani, Y. Tokudome, K. Nakanishi, and M. Takahashi
  • Organizer: The 17th International Sol-Gel Conference
  • Place of Presentation: Madrid, Spain
  • Year and Date: 2013-08-13
• [Presentation] ブロックコポリマーのミクロ相分離構造をテンプレートにした導電性基板上へのメソポーラスカーボン薄膜の作製と構造制御 (2013)
  • Author(s): 中根浩平,徳留靖明,高橋雅英
  • Organizer: 日本ゾル-ゲル学会第11回討論会
  • Place of Presentation: 広島
  • Year and Date: 2013-08-02
• [Presentation] ソフトテンプレート法を用いた導電性基板上へのメソポーラスカーボン薄膜の作製と構造制御 (2013)
  • Author(s): 中根浩平,徳留靖明,高橋雅英
  • Organizer: 第8回日本セラミックス協会関西支部学術講演会
  • Place of Presentation: 大津
  • Year and Date: 2013-07-26
• [Presentation] Synthesis of Layered Double Hydroxide (LDH)-based Monolithic Composite with Hierarchical Macro/Meso Channels for Improved Ion-exchange Characteristics (2013)
  • Author(s): Y. Tokudome, N. Tarutani, K. Nakanishi, and M. Takahashi
  • Organizer: 2013 MRS spring meeting & exhibit
  • Place of Presentation: San Francisco, USA
  • Year and Date: 2013-04-04
• [Presentation] Spontaneous formation of crystalline hydroxide monolith with interconnected hierarchical channels: enhanced adsorption capability for anionic species (2013)
  • Author(s): Y. Tokudome, N. Tarutani, K. Nakanishi, M. Takahashi
  • Organizer: The 17th International Sol-Gel Conference
  • Place of Presentation: Madrid, Spain
• [Presentation] ソフトテンプレート法を用いた導電性基板上へのメソポーラスカーボン薄膜の作製と構造制御 (2013)
  • Author(s): 中根浩平、徳留靖明、高橋雅英
  • Organizer: 第8回日本セラミックス協会関西支部学術講演会
  • Place of Presentation: 大津市
• [Presentation] ブロックコポリマーのミクロ相分離構造をテンプレートにした導電性基板上へのメソポーラスカーボン薄膜の作製と構造制御 (2013)
  • Author(s): 中根浩平、徳留靖明、高橋雅英
  • Organizer: 日本ゾル-ゲル学会第11回討論会
  • Place of Presentation: 広島市
• [Presentation] Synthesis of Layered Double Hydroxide (LDH)-based Monolithic Composite with Hierarchical (2013)
  • Author(s): Yasuaki Tokudome, Naoki Tarutani, Kazuki Nakanishi, Masahide Takahashi
  • Organizer: 2013 MRS spring meeting & exhibit
  • Place of Presentation: San Francisco, CA, USA
• [Presentation] Formation of Titanate Nanotube Brushes on various substrates for interfacial applications (2013)
  • Author(s): Masahide Takahahshi, Kenji Okada, Yasuaki Tokudome
  • Organizer: The 13th International Symposium on Biomimetic Materials Processing
  • Place of Presentation: 高山、岐阜
  • Invited
• [Presentation] ナノ粒子二次元配列マスクを用いた表面微細構造の形成 (2012)
  • Author(s): 矢木信介,徳留靖明,高橋雅英,西井準治
  • Organizer: 第53回ガラスおよびフォトニクス材料討論会
  • Place of Presentation: 北海道
  • Year and Date: 2012-10-25
• [Presentation] ブロックコポリマーの光誘起相転移を利用した階層的高次構造酸化物薄膜の形成 (2012)
  • Author(s): 岡田健司,徳留靖明,高橋雅英, P. Falcaro
  • Organizer: 第53回ガラスおよびフォトニクス材料討論会
  • Place of Presentation: 北海道
  • Year and Date: 2012-10-25
• [Presentation] 組成傾斜メソポーラスシリカ膜における階層的高次構造の形成 (2012)
  • Author(s): 徳留靖明,朝倉元樹,鈴木一正,高橋雅英
  • Organizer: 日本セラミックス協会第25回秋季シンポジウム
  • Place of Presentation: 名古屋
  • Year and Date: 2012-09-20
• [Presentation] Spontaneous Formation of Macroporous Inorganic Materials : Synthesis Strategy for Mixed Metal Oxides and Phosphates with a Monolithic Form (2012)
  • Author(s): Y. Tokudome, N. Tarutani, K. Nakanishi, and M. Takahashi
  • Organizer: 2012 OPU-KIST-ECUST Joint Symposium on Advanced Materials and Applications
  • Place of Presentation: Osaka, Japan
  • Year and Date: 2012-09-10
• [Presentation] Blue-shifted Luminescence from Alq_3 Isolated in Silica Matrix : Analysis by Solid-State NMR (2012)
  • Author(s): Y. Tokudome, M. Fukuchi, F. Suzuki, M. Takahashi, and H. Kaji
  • Organizer: 9th International Conference on Electroluminescence & Organic Optoelectronics
  • Place of Presentation: Fukuoka, Japan
  • Year and Date: 2012-09-04
• [Presentation] Monolithic Columns with Extended Materials Compositions (2012)
  • Author(s): K. Nakanishi, K. Kanamori, K. Morisato, G. Hasegawa, Y. Tokudome
  • Organizer: 38th International Symposium on High Performance Liquid Phase Separations and Related Techniques
  • Place of Presentation: Anaheim, CA USA
  • Year and Date: 2012-06-20
• [Presentation] Spontaneous formation of macroporous inorganic materials: synthesis strategy for mixed metal oxides and phosphates with a monolithic form (2012)
  • Author(s): Yasuaki Tokudome, Naoki Tarutani, Kazuki Nakanishi, Masahide Takahashi
  • Organizer: 2012 OPU-KIST-ECUST Joint Symposium on Advanced Materials and their Applications
  • Place of Presentation: Osaka prefecture University, Osaka, Japan
  • Invited
• [Presentation] Monolithic Columns with Extended Materials Compositions (2012)
  • Author(s): Kazuki Nakanishi, Kazuyoshi Kanamori, Kei Morisato, George Hasegawa, Yasuaki Tokudome
  • Organizer: 38 th International Symposium on High Performance Liquid Phase Separations and Related Techniques
  • Place of Presentation: Anaheim, CA USA
• [Presentation] Blue-shifted Luminescence from Alq3 Isolated in Silica Matrix: Analysis by Solid-state NMR (2012)
  • Author(s): Yasuaki Tokudome, Masashi Fukuchi, Furitsu Suzuki, Masahide Takahashi, Hironori Kaji
  • Organizer: 9th International Conference on Electroluminescence & Organic Optoelectronics
  • Place of Presentation: The Luigans, Fukuoka, Japan
• [Presentation] 高効率イオン交換反応の実現に向けたバルク型マクロ多孔性層状腹水酸化物の作製 (2012)
  • Author(s): 徳留靖明、樽谷直紀、高橋雅英、中西和樹
  • Organizer: 日本材料学会第61期学術講演会
  • Place of Presentation: 岡山大学
• [Presentation] 光誘起によるSiO2－ポリマーハイブリッド薄膜への入れ子状しわ構造の形成と外部刺激応答性の開拓 (2012)
  • Author(s): 鈴木一正、北永卓也、徳留靖明、高橋雅英
  • Organizer: 日本ゾル-ゲル学会第10回討論会
  • Place of Presentation: 慶応義塾大学
• [Presentation] 交互共重合型ケイリン酸塩系オリゴマーの分子形態制御 (2012)
  • Author(s): 吉井雄飛、徳留靖明、高橋雅英
  • Organizer: 日本ゾル-ゲル学会第10回討論会
  • Place of Presentation: 慶應義塾大学
• [Presentation] ナノ粒子二次元配列マスクを用いた表面微細構造の形成 (2012)
  • Author(s): 矢木信介、徳留靖明、高橋雅英
  • Organizer: 第53回ガラスおよびフォトニクス材料討論会
  • Place of Presentation: 北海道大学
• [Presentation] ブロックコポリマーの光誘起相転移を利用した階層的高次構造酸化物薄膜の形成 (2012)
  • Author(s): 高橋雅英、岡田健司、徳留靖明
  • Organizer: 第53回ガラスおよびフォトニクス材料討論会
  • Place of Presentation: 北海道大学
• [Presentation] 層間ゲストの超高速交換に向けた層状水酸化物階層的多孔構造の作製 (2012)
  • Author(s): 徳留靖明、樽谷直紀、中西和樹、高橋雅英
  • Organizer: 日本セラミックス協会 第25回秋季シンポジウム
  • Place of Presentation: 名古屋大学
• [Presentation] 酸塩基反応を用いたケイリン酸塩系オリゴマーの分子設計 (2012)
  • Author(s): 吉井雄飛、徳留靖明、高橋雅英
  • Organizer: 日本セラミックス協会 第25回秋季シンポジウム
  • Place of Presentation: 名古屋大学
• [Presentation] 組成傾斜メソポーラスシリカ膜における階層的高次構造の形成 (2012)
  • Author(s): 徳留靖明、朝倉元樹、鈴木一正、高橋雅英
  • Organizer: 日本セラミックス協会 第25回秋季シンポジウム
  • Place of Presentation: 名古屋大学
• [Book] 月刊「化学」68[10] (2014)
  • Author(s): 徳留靖明、高橋雅英
  • Publisher: 化学同人
• [Book] ゾル-ゲル法の最新応用と展望(第1章7項) (2014)
  • Author(s): 高橋雅英、徳留靖明
  • Publisher: シーエムシー出版
• [Book] 月刊「化学」 68〔10〕 (2014)
  • Author(s): 徳留靖明，高橋雅英
  • Total Pages: 2
  • Publisher: 化学同人
• [Book] ゾル-ゲル法の最新応用と展望 (2014)
  • Author(s): 徳留靖明，高橋雅英
  • Total Pages: 320
  • Publisher: シーエムシー出版