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creation of strengthening functional hydrogel through the incorporation of porous inorganic particles

Research Project

Project/Area Number 24750213
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionHokkaido University

Principal Investigator

MITOMO Hideyuki  北海道大学, 電子科学研究所, 助教 (50564952)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsハイドロゲル / 高強度化 / 複合材料 / 光学的機能 / 金ナノ粒子 / 表面増強ラマン散乱 / 距離制御 / ゲル / 縫い込み型 / 物性
Outline of Final Research Achievements

To improve mechanical strength of the hydrogels and to give optical functionality to the gels, two issues were studied in this study.
1. Hydrogels, in which organic polymers and porous inorganic particles were topologically conjugated, were prepared. It was showed that strengthening could be performed with little loss of the extensibility when the particle size is less than 1 um.
2. Metal nanostructures were formed on the solid substrates and they were transferred onto the hydrogel through the in situ polymerization on this substrate. Interparticle distance of the metal nanostructures on the gel could be tuned by the volume change of the hydrogel through the change of swelling state.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (32 results)

All 2015 2014 2013 2012 Other

All Journal Article (12 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 1 results) Presentation (16 results) (of which Invited: 2 results) Book (1 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Enzymatic synthesis of a DNA Triblock copolymer composed of natural and unnatural nucleotides2015

    • Author(s)
      Hideyuki Mitomo, Yukie Watanabe, Yasutaka Matsuo, Kenichi Niikura, and Kuniharu Ijiro,
    • Journal Title

      Chem. Asian J.

      Volume: 10 Issue: 2 Pages: 455-460

    • DOI

      10.1002/asia.201403108

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Encapsulation of a gold nanoparticle in a DNA origami container,2015

    • Author(s)
      Akinori Kuzuya, Masafumi Kaino, Mirai Hashizume, Kazuki Matsumoto, Takeaki Uehara, Yasutaka Matsuo, Hideyuki Mitomo, Kenichi Niikura, Kuniharu Ijiro and Yuichi Ohya
    • Journal Title

      Polymer J.

      Volume: 47 Issue: 2 Pages: 177-182

    • DOI

      10.1038/pj.2014.128

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Janus-Like Gold Nanoparticles with Hydrophilic/Hydrophobic Faces by Surface Ligand Exchange and Their Self-Assemblies in Water2015

    • Author(s)
      Ryo Iida, Hitoshi Kawamura, Kenichi Niikura, Takashi Kimura, Shota Sekiguchi, Yasumasa Joti, Yoshitaka Bessho, Hideyuki Mitomo, Yoshinori Nishino, and Kuniharu Ijiro
    • Journal Title

      Langmuir

      Volume: - Issue: 14 Pages: 4054-4062

    • DOI

      10.1021/la504647z

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Amphiphilic Gold Nanoparticles Displaying Flexible Bifurcated Ligands as a Carrier for siRNA Delivery into the Cell Cytosol2014

    • Author(s)
      Kenichi Niikura, Kenya Kobayashi, Chie Takeuchi, Naoki Fujitani, Shuko Takahara, Takafumi Ninomiya, Kyoji Hagiwara, Hideyuki Mitomo, Yoshihiro Ito, Yoshihito Osada, and Kuniharu Ijiro,
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 6 Issue: 24 Pages: 22146-22154

    • DOI

      10.1021/am505577j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] DNAミメティクス2014

    • Author(s)
      三友 秀之、居城 邦治
    • Journal Title

      日本画像学会誌

      Volume: 53 Pages: 199-206

    • NAID

      130004800891

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Enhanced Cellular Uptake of Amphiphilic Gold Nanoparticles with Ester Functionality2014

    • Author(s)
      K. Kobayashi, K. Niikura, C. Takeuchi, S. Sekiguchi, T. Ninomiya, K. Hagiwara, H. Mitomo, Y. Ito, Y. Osada and K. Ijiro
    • Journal Title

      Chem. Commun.

      Volume: 50 Issue: 10 Pages: 1265-1267

    • DOI

      10.1039/c3cc48532c

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] DNA-templated plasmonic Ag/AgCl nanostructures for molecular selective photocatalysis and photocatalytic inactivation of cancer cells2013

    • Author(s)
      王 国慶・三友 秀之・松尾 保孝・島本 直伸・新倉 謙一・居城 邦治
    • Journal Title

      Journal of Materials Chemistry B

      Volume: 1 Issue: 43 Pages: 5899-5907

    • DOI

      10.1039/c3tb20954g

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation of Triblock DNA as a Template for Fabrication of Nano-Gap Structures Using Sequence-Selective Metallization2013

    • Author(s)
      三友秀之・渡辺雪江・松尾保孝・新倉謙一・居城邦治
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 70 Issue: 7 Pages: 337-340

    • DOI

      10.1295/koron.70.337

    • NAID

      10031188190

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Sub-100 nm Gold Nanoparticle Vesicles as a Drug Delivery Carrier enabling Rapid Drug Release upon Light Irradiation2013

    • Author(s)
      K. Niikura, N. Iyo, Y. Matsuo, H. Mitomo, and K. Ijiro
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 5 Issue: 9 Pages: 3900-3907

    • DOI

      10.1021/am400590m

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 生物に学ぶ動的に色を変えるナノ構造材料2013

    • Author(s)
      三友 秀之、居城 邦治
    • Journal Title

      工業材料

      Volume: 61 Pages: 40-43

    • Related Report
      2013 Research-status Report
  • [Journal Article] Biomimetic Materials in Imitation of Eye-Opening Colors from Nano-Structure in Nature2013

    • Author(s)
      三友秀之、島本直伸、居城邦治
    • Journal Title

      Journal of The Surface Finishing Society of Japan

      Volume: 64 Issue: 1 Pages: 9-14

    • DOI

      10.4139/sfj.64.9

    • NAID

      10031148103

    • ISSN
      0915-1869, 1884-3409
    • Related Report
      2012 Research-status Report
  • [Journal Article] Nanopattern fabrication of gold on hydrogels and application to tunable photonic crystal2012

    • Author(s)
      Naonobu Shimamoto, Yoshito Tanaka, Hideyuki Mitomo, Ryuzo Kawamura, Kuniharu Ijiro, Keiji Sasaki, Yoshihito Osada
    • Journal Title

      Advanced Materials

      Volume: 24 Issue: 38 Pages: 5243-5248

    • DOI

      10.1002/adma.201201522

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Amphiphilic Gold Nanoparticles: Design of Bifurcated Surface Ligands for siRNA Delivery into the Cell Cytosol2014

    • Author(s)
      Kenya Kobayashi, Hideyuki Mitomo, Chie Takeuchi, Naoki Fujitani, Shuko Takahara, Takafumi Ninomiya, Yoshihiro Ito, Yoshihito Osada, Kenichi Niikura, Kuniharu Ijiro
    • Organizer
      The 15th Ries-Hokudai International symposium
    • Place of Presentation
      シャトレーゼ ガトーキングダム サッポロ(北海道札幌市)
    • Year and Date
      2014-12-16 – 2014-12-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Preparation of tunable plasmonic device using hydrogels2014

    • Author(s)
      Hideyuki Mitomo, Kenta Horie, Yasutaka Matsuo, Kenichi Niikura, Takeharu Tani, Masayuki Naya, Kuniharu Ijiro
    • Organizer
      Asia NANO 2014
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2014-10-27 – 2014-10-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] DNAブラシを鋳型とした金属パターニング2014

    • Author(s)
      三友 秀之, 鈴木 康修, 中村 聡, 松尾 保孝, 新倉 謙一, 居城邦治
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学文教キャンパス(長崎県長崎市)
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Metal array structures on the stimuli-responsive gel2014

    • Author(s)
      Hideyuki Mitomo, Kenta Horie, Naonobu Shimamoto, Yasutaka Matsuo, Kenichi Niikura, and Kuniharu Ijiro,
    • Organizer
      SPIE. optics+photonics
    • Place of Presentation
      San Diego, CA, USA
    • Year and Date
      2014-08-17 – 2014-08-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 3次元金属パターニングに向けたDNAブラシの作製2014

    • Author(s)
      三友 秀之, 鈴木 康修,中村 聡, 松尾 保孝, 新倉 謙一, 居城 邦治
    • Organizer
      第24回バイオ・高分子シンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Year and Date
      2014-07-24 – 2014-07-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高感度ラマン分光法に向けたハイドロゲルによる金ナノ粒子間距離の制御2013

    • Author(s)
      三友 秀之, 堀江 健太, 島本 直伸, 松尾 保孝, 新倉 謙一, 長田 義仁, 居城 邦治
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      京都国際会館(京都市)
    • Related Report
      2013 Research-status Report
  • [Presentation] ハイドロゲルと金ナノ粒子を用いた動的表面増強ラマン散乱基板の作製2013

    • Author(s)
      三友 秀之, 堀江 健太, 王 国慶, 松尾 保孝, 新倉 謙一, 谷 武晴, 納谷 昌之, 居城 邦治
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス(京田辺市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Hybridization of inorganic matters to polymer gels for enhancing the strength and functionality2013

    • Author(s)
      Hideyuki Mitomo, Naonobu Shimamoto, Ken-Ichi Sano, Yoshihito Osada, and Kuniharu Ijiro
    • Organizer
      International Symposium on Advanced Soft Materials
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Dynamic Control of the Distance between Metal Nanostructures by using Polymer Network2013

    • Author(s)
      Hideyuki Mitomo, Kenta Horie, Naonobu Shimamoto, Yasutaka Matsuo, Kenichi Niikura, and Kuniharu Ijiro
    • Organizer
      The 14th RIES-HOKUDAI International Symposium
    • Place of Presentation
      シャトレーゼ ガトーキングダム サッポロ(札幌市)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 高感度ラマン分光法に向けたハイドロゲル上での金ナノ粒子間距離の制御2013

    • Author(s)
      堀江 健太、三友 秀之、島本 直伸、松尾 保孝、新倉 謙一、長田 義仁、居城 邦治
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県草津市)
    • Related Report
      2012 Research-status Report
  • [Presentation] ゲルの強度・機能性を向上させる無機物質の複合化方法2013

    • Author(s)
      三友 秀之、島本 直伸、佐野 健一、長田 義仁、居城 邦治
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学(滋賀県草津市)
    • Related Report
      2012 Research-status Report
  • [Presentation] 多孔性無機粒子を用いた高強度化有機・無機複合材料の創成2012

    • Author(s)
      三友 秀之、佐野 健一、長田 義仁、居城 邦治
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学(名古屋市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Enhancement of the mechanical properties of the gels by porous inorganic particles2012

    • Author(s)
      H. Mitomo, K.I. Sano, K. Ijiro, and Y Osada
    • Organizer
      9th international Gel Symposium -Gelsympo 2012-
    • Place of Presentation
      筑波国際会議場(つくば市)
    • Related Report
      2012 Research-status Report
  • [Presentation] Fabrication of metal thin film micro pattern on hydrogels for photonic applications2012

    • Author(s)
      N. Shimamoto, Y. Tanaka, H. Mitomo, T. Hayashi, R. Kawamura, H. Akimoto, K. Ijiro, K. Sasaki, and Y. Osada
    • Organizer
      9th international Gel Symposium -Gelsympo 2012-
    • Place of Presentation
      筑波国際会議場(つくば市)
    • Related Report
      2012 Research-status Report
  • [Presentation] ハイドロゲルによる金ナノ粒子間距離の制御

    • Author(s)
      堀江 健太,三友 秀之, 島本 直伸, 松尾 保孝, 新倉 謙一, 長田 義仁, 居城 邦治
    • Organizer
      日本化学会北海道支部2013年夏季研究発表会
    • Place of Presentation
      北見工業大学(北見市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 高感度ラマン分光法に向けたハイドロゲルを用いた金ナノ粒子の距離間制御

    • Author(s)
      堀江 健太、三友 秀之、島本 直伸、松尾 保孝、新倉 謙一、長田 義仁、居城 邦治
    • Organizer
      第47回高分子学会北海道支部研究発表会
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2012 Research-status Report
  • [Book] 生物模倣技術と新材料・新製品開発への応用 (分担)第7章 第1節「生物の持つ発色メカニズムとその応用展開」2014

    • Author(s)
      三友 秀之、居城 邦治
    • Total Pages
      702
    • Publisher
      技術情報協会
    • Related Report
      2014 Annual Research Report
  • [Remarks] 北海道大学 電子科学研究所 生体分子デバイス研究分野

    • URL

      http://chem.es.hokudai.ac.jp

    • Related Report
      2014 Annual Research Report
  • [Remarks] 北海道大学電子科学研究所 生体分子デバイス研究分野

    • URL

      http://chem.es.hokudai.ac.jp/

    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 導電性ゲルおよび導電性ゲルの製造方法2013

    • Inventor(s)
      長田義仁、島本直伸、三友秀之、岸良一、居城邦治、中村直樹
    • Industrial Property Rights Holder
      長田義仁、島本直伸、三友秀之、岸良一、居城邦治、中村直樹
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-001403
    • Filing Date
      2013-01-08
    • Related Report
      2012 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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