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Development of high-temperature growth technique for high-quality GaN ingots

Research Project

Project/Area Number 24760011
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Applied materials science/Crystal engineering
Research InstitutionOsaka University

Principal Investigator

IMADE MAMORU  大阪大学, 工学(系)研究科(研究院), 助教 (40457007)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords窒化ガリウム / 酸化ガリウム / 高温成長 / 高速成長 / 結晶工学 / 結晶成長 / 半導体物性 / 窒化ガリウム / 酸化ガリウム
Research Abstract

High-temperature growth technique for high-quality GaN ingots have been developed. In this study, progresses as follows have been obtained. (1)High-temperature growth, H2 carrier gas and optimization of surface state of seed crystals enabled to increase the growth rate (180um/h) and improve crystallinity. (2)New reaction between Ga metal and H2O vapor for synthesizing Ga2O vapor has been developed to perform the long-term growth. (3)New CVD gas flow pattern has been developed by the fluid calculation. By using this new pattern, 400um-thick GaN crystals could be obtained.
These results indicate that the high-temperature GaN growth technique using Ga2O vapor, which has been developed in this research, is useful for fabricating high-quality GaN ingots.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (44 results)

All 2014 2013 2012 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (40 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Effect of H2 carrier gas on the physical properties of a GaN layer grown using Ga2O vapor and NH32014

    • Author(s)
      Yuan Bu et al.
    • Journal Title

      Journal of Crystal Growth

      Volume: vol.392 Pages: 1-4

    • DOI

      10.1016/j.jcrysgro.2014.01.031

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dramatic increase in the growth rate of GaN layers grown from Ga2O vapor by epitaxial growth on HVPE-GaN substrates with a well-prepared surface2014

    • Author(s)
      Yuan Bu et al.
    • Journal Title

      Applied Physics Express

      Volume: Vol.7 Issue: 3 Pages: 0355041-4

    • DOI

      10.7567/apex.7.035504

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] High Temperature Growth of Non-polar a-Plane GaN Film Grown Using Gallium-Oxide as Ga Source2013

    • Author(s)
      Tomoaki Sumi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 2R Pages: 0255031-3

    • DOI

      10.7567/jjap.52.025503

    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 金属Gaを出発原料としたGa_2Oを用いたGaN結晶の成長2014

    • Author(s)
      隅智則、重田真実、卜渊、北本啓、今出完、吉村政志、伊勢村雅士、森勇介
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス、神奈川県
    • Year and Date
      2014-03-18
    • Related Report
      2013 Final Research Report
  • [Presentation] Ga_2OをGa源としたGaN気相成長法によるNaフラックス基板上高速成長2014

    • Author(s)
      高津啓彰、重田真実、隅智亮、渊ト、北本啓、今出完、吉村政志、伊勢村雅士、森勇介
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス、神奈川県
    • Year and Date
      2014-03-18
    • Related Report
      2013 Final Research Report
  • [Presentation] Effect of H_2 Carrier Gas on the Physical Properties of GaN Layer Growth by Using Ga_2O Vapor and NH_42013

    • Author(s)
      Y. Bu, M. Juta, T, Sumi, A. Kitamoto, M. Imade, M. Yoshimura, M. Isemura and Y. Mori
    • Organizer
      JSAP- MRS Joint Symposia 2013
    • Place of Presentation
      Kyoto JAPAN
    • Year and Date
      2013-09-16
    • Related Report
      2013 Final Research Report
  • [Presentation] Growth of GaN crystal with high growth rate synthesized from Ga_2O vapor-T2013

    • Author(s)
      T. Sumi, M. Juta, Y. Bu, A. Kitamoto, M. Imade, M. Yoshimura. M. Isemura and Y. Mori
    • Organizer
      JSAP- MRS Joint Symposia 2013
    • Place of Presentation
      Kyoto JAPAN
    • Year and Date
      2013-09-16
    • Related Report
      2013 Final Research Report
  • [Presentation] Effect of H_2 Carrier Gas on the Physical Properties of GaN Layer Growth by Using Ga_2O Vapor and NH_42013

    • Author(s)
      Y. Bu, M. Juta, T. Sumi, A. Kitamoto, M. Imade, M. Yoshimura, M. Isemura and Y. Mori
    • Organizer
      10th International Conference on Nitride Semiconductors
    • Place of Presentation
      Washington,USA
    • Year and Date
      2013-08-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Growth of GaN Crystal with High Growth Rate Using Ga_2O as Ga Source2013

    • Author(s)
      T. Sumi, M. Juta, J. Takino, Y. Bu, A. Kitamoto, M. Imade, M. Yoshimura, M. Isemura and Y. Mori
    • Organizer
      10th International Conference on Nitride Semiconductors
    • Place of Presentation
      Washington,USA
    • Year and Date
      2013-08-27
    • Related Report
      2013 Final Research Report
  • [Presentation] Influence of the GaN Layer Thickness on the Crystallinity in the Vapor Phase Epitaxy Growth of GaN Using Ga_2O2013

    • Author(s)
      T. Sumi, M. Juta, J. Takino, Y. Bu, A. Kitamoto, M. Imade, M. Yoshimura, M. Isemura, M. Hata and Y. Mori
    • Organizer
      Conference on LED and ItsIndustrial Application'13
    • Place of Presentation
      Kanagawa JAPAN
    • Year and Date
      2013-04-24
    • Related Report
      2013 Final Research Report
  • [Presentation] Effect of growth temperature on crystalline of GaN layers by vapor phase epitaxy using Ga_2O as a Ga source2013

    • Author(s)
      Y. Bu, M. Juta, T. Sumi, A. Kitamoto, M. Imade, M. Yoshimura and Y. Mori
    • Organizer
      Conference on LED and ItsIndustrial Application'13
    • Place of Presentation
      Kanagawa JAPAN
    • Year and Date
      2013-04-24
    • Related Report
      2013 Final Research Report
  • [Presentation] Naフラックス製GaN自立基板上へのGa_2Oを用いたGaN気相成長2012

    • Author(s)
      滝野淳一、隅智亮、卜渊、北本啓、今出完、吉村政志、秦雅彦、伊勢村雅士、森勇介
    • Organizer
      第42回結晶成長国内会議
    • Place of Presentation
      九州大学筑紫キャンパス総合研究棟、福岡県
    • Year and Date
      2012-11-09
    • Related Report
      2013 Final Research Report
  • [Presentation] Ga_2O原料GaN気相成長法における基板表面処理効果の検討2012

    • Author(s)
      重田真実、滝野淳一、隅智亮、卜渊、北本啓、今出完、吉村政志、秦雅彦、伊勢村雅士、森勇介
    • Organizer
      第42回結晶成長国内会議
    • Place of Presentation
      九州大学筑紫キャンパス総合研究棟、福岡県
    • Year and Date
      2012-11-09
    • Related Report
      2013 Final Research Report
  • [Presentation] Growth of a low dislocation GaN layer on a Na-flux-GaN substrate using Ga_2O as a Ga source2012

    • Author(s)
      J. Takino, T. Sumi, Y. Bu, A. Kitamoto, M. Imade, M. Yoshimura, M. Isemura and Y. Mori
    • Organizer
      International Workshop on nitride Semiconductors 2012
    • Place of Presentation
      Hokkaido JAPAN
    • Year and Date
      2012-10-16
    • Related Report
      2013 Final Research Report
  • [Presentation] Growth of thick GaN layers by the vapor phase epitaxy using Ga_2O source2012

    • Author(s)
      T. Sumi, J. Takino, Y. Bu, A. Kitamoto, M. Imade, M. Yoshimura, M. Isemura and Y. Mori
    • Organizer
      International Workshop on nitride Semiconductors(IWN2012)
    • Place of Presentation
      Hokkaido JAPAN
    • Year and Date
      2012-10-16
    • Related Report
      2013 Final Research Report
  • [Presentation] High temperature growth of high crystalline GaN layers with a high growth rate by vapor phase epitaxy using Ga_2O as a Ga source2012

    • Author(s)
      Y.Bu, J. Takino, T. Sumi, A. Kitamoto, M. Imade, M. Yoshimura, M. Isemura and Y. Mori
    • Organizer
      International Workshop on nitride Semiconductors (IWN2012)
    • Place of Presentation
      Hokkaido JAPAN
    • Year and Date
      2012-10-15
    • Related Report
      2013 Final Research Report
  • [Presentation] Ga_2O原料GaN気相成長法における基板表面処理効果の検討2012

    • Author(s)
      重田真実、滝野淳一、隅智亮、卜渊、北本啓、今出完、吉村政志、秦雅彦、伊勢村雅士、森勇介
    • Organizer
      第36回結晶成長討論
    • Place of Presentation
      国民宿舎虹の松原ホテル、佐賀県
    • Year and Date
      2012-09-26
    • Related Report
      2013 Final Research Report
  • [Presentation] Ga_2Oを用いた気相成長法によるHVPE自立基板上へのGaN結晶成長2012

    • Author(s)
      滝野淳一、重田真実、隅智亮、卜渊、北本啓、今出完、吉村政志、秦雅彦、伊勢村雅士、森勇介
    • Organizer
      第36回結晶成長討論会
    • Place of Presentation
      国民宿舎虹の松原ホテル、佐賀県
    • Year and Date
      2012-09-26
    • Related Report
      2013 Final Research Report
  • [Presentation] Naフラックス製GaN自立基板上へのGa2Oを用いたGaN気相成長2012

    • Author(s)
      滝野淳一、隅智亮、卜渊、北本啓、今出完、吉村政志、伊勢村雅士、森勇介
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      松山大学文京キャンパス、愛媛県
    • Year and Date
      2012-09-13
    • Related Report
      2013 Final Research Report
  • [Presentation] Growth of GaN layer with high crystallinity on free-standing GaN substrate using Ga_2O as Ga source2012

    • Author(s)
      T. Sumi, J. Takino, Y. Bu, A. Kitamoto, M. Imade, M. Yoshimura, M. Isemura and Y. Mori
    • Organizer
      4th International Symposium on Growth of III-Nitrides(ISGN4)
    • Place of Presentation
      RUSSIA
    • Year and Date
      2012-07-17
    • Related Report
      2013 Final Research Report
  • [Presentation] Ga_2Oを原料としたGaN結晶成長法における厚膜化に向けた取り組み2012

    • Author(s)
      隅智亮、池田憲治、滝野淳一、卜渊、北本啓、今出完、吉村政志、伊勢村雅士、森勇介
    • Organizer
      第4回窒化物半導体結晶成長講演会
    • Place of Presentation
      東京大学生産技術研究所、東京都
    • Year and Date
      2012-04-27
    • Related Report
      2013 Final Research Report
  • [Presentation] High crystallinity GaN growth on c- and a-plane free-standing GaN substrates using Ga_2O vapor and NH_<3,>2012

    • Author(s)
      Y. Bu, M. Juta, J. Takino, T. Sumi, A. Kitamoto, M. Imade, M. Yoshimura and Y. Mori
    • Organizer
      7th Photonics Center Symposium "Nanophotonics in Asia 2012"
    • Place of Presentation
      Ishikawa JAPAN
    • Related Report
      2013 Final Research Report
  • [Presentation] Growth of high crystalline GaN layers at high temperature on freestanding GaN substrates by vapor phase epitaxy using Ga_2O as Ga source2012

    • Author(s)
      Y. Bu, M. Juta, J. Takino, T. Sumi, A. Kitamoto, M. Imade, M. Yoshimura and Y. Mori
    • Organizer
      4th International Symposium on Growth of III-Nitrides(ISGN4)
    • Place of Presentation
      Miyagi JAPAN
    • Related Report
      2013 Final Research Report
  • [Presentation] Growth of high crystalline GaN layers at high temperature on freestanding GaN substrates by vapor phase epitaxy using Ga2O as Ga source2012

    • Author(s)
      Bu,Yuan; Imade,Mamoru
    • Organizer
      International Crystal Growth School (ICGS2)
    • Place of Presentation
      Hotel Sakan, Convention Center Akiu, Sendai
    • Related Report
      2012 Research-status Report
  • [Presentation] High crystallinity GaN growth on c- and a-plane free-standing GaN substrates using Ga2O vapor and NH32012

    • Author(s)
      Bu,Yuan; Imade,Mamoru
    • Organizer
      7th Photonics Center Symposium "Nanophotonics in Asia 2012"
    • Place of Presentation
      金沢
    • Related Report
      2012 Research-status Report
  • [Presentation] Effect of growth temperature on crystalline of GaN layers by vapor phase epitaxy using Ga2O as a Ga source

    • Author(s)
      Bu,Yuan et al.
    • Organizer
      Conference on LED and ItsIndustrial Application’13
    • Place of Presentation
      Kanagawa JAPAN
    • Related Report
      2013 Annual Research Report
  • [Presentation] Influence of the GaN Layer Thickness on the Crystallinity in the Vapor Phase Epitaxy Growth of GaN Using Ga2O

    • Author(s)
      Tomoaki Sumi et al.
    • Organizer
      Conference on LED and ItsIndustrial Application’13
    • Place of Presentation
      Kanagawa JAPAN
    • Related Report
      2013 Annual Research Report
  • [Presentation] Growth of GaN Crystal with High Growth Rate Using Ga2O as Ga Source

    • Author(s)
      Tomoaki Sumi et al.
    • Organizer
      10th International Conference on Nitride Semiconductors
    • Place of Presentation
      Washington USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effect of H2 Carrier Gas on the Physical Properties of GaN Layer Growth by Using Ga2O Vapor and NH4

    • Author(s)
      Bu,Yuan et al.
    • Organizer
      10th International Conference on Nitride Semiconductors
    • Place of Presentation
      Washington USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Growth of GaN crystal with high growth rate synthesized from Ga2O vapor

    • Author(s)
      Tomoaki Sumi et al.
    • Organizer
      JSAP - MRS Joint Symposia 2013
    • Place of Presentation
      Kyoto JAPAN
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effect of H2 Carrier Gas on the Physical Properties of GaN Layer Growth by Using Ga2O Vapor and NH4

    • Author(s)
      Bu,Yuan et al.
    • Organizer
      JSAP - MRS Joint Symposia 2013
    • Place of Presentation
      Kyoto JAPAN
    • Related Report
      2013 Annual Research Report
  • [Presentation] Ga2OをGa源としたGaN気相成長法によるNaフラックス基板上高速成長

    • Author(s)
      高津啓彰 他
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川県
    • Related Report
      2013 Annual Research Report
  • [Presentation] 金属Gaを出発原料としたGa2Oを用いたGaN結晶の成長

    • Author(s)
      隅智亮 他
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川県
    • Related Report
      2013 Annual Research Report
  • [Presentation] Ga2O を原料としたGaN 結晶成長法における厚膜化に向けた取り組み

    • Author(s)
      隅 智亮、 今出 完
    • Organizer
      第4回窒化物半導体結晶成長講演会  FR-10
    • Place of Presentation
      東京大学生産技術研究所 An棟2階 コンベンションホール
    • Related Report
      2012 Research-status Report
  • [Presentation] Growth of GaN layer with high crystallinity on free-standing GaN substrate using Ga2O as Ga source

    • Author(s)
      Sumi,Tomoaki; Imade,Mamoru
    • Organizer
      4th International Symposium on Growth of III-Nitrides(ISGN4), Tu-63p
    • Place of Presentation
      The Hotel Saint-Petersburg, Russia
    • Related Report
      2012 Research-status Report
  • [Presentation] Naフラックス製GaN自立基板上へのGa2Oを用いたGaN気相成長

    • Author(s)
      滝野 淳一、 今出 完
    • Organizer
      第73回応用物理学会学術講演会, 13p-H9-4
    • Place of Presentation
      松山大学文京キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] Ga2Oを用いた気相成長法によるHVPE自立基板上へのGaN結晶成長

    • Author(s)
      滝野 淳一、 今出 完
    • Organizer
      第36回結晶成長討論会, PW11
    • Place of Presentation
      国民宿舎 虹の松原ホテル(佐賀県唐津市東唐津4丁目)
    • Related Report
      2012 Research-status Report
  • [Presentation] Ga2O原料GaN気相成長法における基板表面処理効果の検討

    • Author(s)
      重田真実、 今出 完
    • Organizer
      第36回結晶成長討論会, PW8
    • Place of Presentation
      国民宿舎 虹の松原ホテル(佐賀県唐津市東唐津4丁目)
    • Related Report
      2012 Research-status Report
  • [Presentation] High temperature growth of high crystalline GaN layers with a high growth rate by vapor phase epitaxy using Ga2O as a Ga source

    • Author(s)
      Bu,Yuan; Imade,Mamoru
    • Organizer
      International Workshop on nitride Semiconductors (IWN2012), MoP-GR-73
    • Place of Presentation
      Sapporo Convention Center. Sapporo
    • Related Report
      2012 Research-status Report
  • [Presentation] Growth of thick GaN layers by the vapor phase epitaxy using Ga2O source

    • Author(s)
      Sumi,Tomoaki; Imade,Mamoru
    • Organizer
      International Workshop on nitride Semiconductors (IWN2012), TuP-GR-43
    • Place of Presentation
      Sapporo Convention Center. SapporoSapporo Convention Center.
    • Related Report
      2012 Research-status Report
  • [Presentation] Growth of a low dislocation GaN layer on a Na-flux-GaN substrate using Ga2O as a Ga source

    • Author(s)
      Takino,Junichi; Imade,Mamoru
    • Organizer
      International Workshop on nitride Semiconductors (IWN2012),TuP-GR-44
    • Place of Presentation
      Sapporo Convention Center. Sapporo
    • Related Report
      2012 Research-status Report
  • [Presentation] Ga2O 原料GaN 気相成長法における基板表面処理効果の検討

    • Author(s)
      重田真実、 今出 完
    • Organizer
      第42回結晶成長国内会議,10PS13
    • Place of Presentation
      九州大学 筑紫キャンパス 総合研究棟(C-CUBE) (福岡県春日市春日公園6-1)
    • Related Report
      2012 Research-status Report
  • [Presentation] Naフラックス製GaN自立基板上へのGa2Oを用いたGaN気相成長

    • Author(s)
      滝野淳一、 今出 完
    • Organizer
      第42回結晶成長国内会議,09aC07
    • Place of Presentation
      九州大学 筑紫キャンパス 総合研究棟(C-CUBE) (福岡県春日市春日公園6-1)
    • Related Report
      2012 Research-status Report
  • [Patent(Industrial Property Rights)] III-V族窒化物結晶製造方法、種結晶形成基板製造方法、III-V族窒化物結晶、半導体装置、III-V族化合物結晶製造装置、種結晶形成基板製造装置2013

    • Inventor(s)
      森勇介 他
    • Industrial Property Rights Holder
      森勇介 他
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-10-09
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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