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Control of organic semiconductor layer using Moire surface potential distribution of graphene

Research Project

Project/Area Number 24760023
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionUniversity of Tsukuba

Principal Investigator

YAMADA Yoichi  筑波大学, 数理物質系, 講師 (20435598)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsgrapehe / モアレ / 有機半導体 / アルカリドーピング / グラフェン / graphene / 自己組織化
Outline of Final Research Achievements

We aimed electronic and structural controll of the organic semiconductors using Moire potential distribution of graphene surface on metal substrate. Special stress was put on the alkali-metal doping of molecular layers on graphene. In the limited period of this study, we achieved two main subjects; (1) detailed characterization of the Moire potential distribution of graphene and (2) structural and electronic characterization of the alkali-doped organic films.
(1) Using surface sensitive He atom scattering, we quantify the force constant of the graphene-substrate bonding interms of the Debye temperature and clarify the in-plane distribution of the force constant which is quite relevant in the formation of the Moire-potetial distribution.
(2) The structural detail of the K-doped monolayer of picene and coronene were studied in the molecular scale using STM. We clarify the presence of the alkali-induced reordering of the organic layer, which is in close relation to the electronic structre.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (37 results)

All 2015 2014 2013 2012 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results,  Acknowledgement Compliant: 5 results) Presentation (23 results) (of which Invited: 1 results) Remarks (1 results)

  • [Journal Article] Probing interlayer interactions between graphene and metal substrates by Supersonic Rare-Gas Atom Scattering2015

    • Author(s)
      H. Shichibe, Y. Satake, K. Watanabe, A. Kinjyo, A. Kunihara, Y. Yamada, M Sasaki, W. W. Hayes and J. R. Manson
    • Journal Title

      Phys. Rev. B

      Volume: 91 Issue: 15 Pages: 155403-155403

    • DOI

      10.1103/physrevb.91.155403

    • NAID

      120007130291

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] In situ synchrotron radiation photoemission study of ultrathin surface oxides of Ge(111)-c(2 ' 8) induced by supersonic O2 beams2015

    • Author(s)
      Ryuta Okada, Akitaka Yoshigoe, Yuden Teraoka, Yoichi Yamada, and Masahiro Sasaki
    • Journal Title

      Appl. Phys. Express

      Volume: 8 Issue: 2 Pages: 025701-025701

    • DOI

      10.7567/apex.8.025701

    • NAID

      210000137404

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of graphene nanoribbons from amyloid fibrils by solid-phase graphitization using liquid gallium catalyst2014

    • Author(s)
      K.Murakami, T.Dong, Y.Kajiwara, T.Hiyama, R.Ueki, G.Ohashi, K.Shiraki, Y.Yamada and J.Fujita
    • Journal Title

      2014MRS Proceedings

      Volume: 1658 Pages: 1658-1658

    • DOI

      10.1557/opl.2014.502

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reordering and Disordering of Copper Hexadecafluorophthalocyanine Monolayer by K Doping2014

    • Author(s)
      Yuri Hasegawa, *Yoichi Yamada, Masahiro Sasaki
    • Journal Title

      J. Phys. Chem. C

      Volume: 118 Issue: 42 Pages: 24490-24490

    • DOI

      10.1021/jp506682t

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Well-Ordered Monolayers of Alkali-doped Coronene and Picene: Molecular Arrangements and Electronic structures2014

    • Author(s)
      Masahiro Yano , Megumi Endo , Yuri Hasegawa , Ryosuke Okada , Yoichi Yamada, Masahiro Sasaki
    • Journal Title

      J. Chem. Phys

      Volume: 141 Issue: 3 Pages: 034708-034708

    • DOI

      10.1063/1.4887776

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Charge-Separated Fmoc-peptide β-Sheets: Sequence-Secondary Structure Relationship for Arranging Charged Side Chains on Both Sides2014

    • Author(s)
      Toru Nakayama,Taro Sakuraba, Shunsuke Tomita, Akira Kaneko, Eisuke Takai, Kentaro Shiraki, Kentaro Tashiro, Noriyuki Ishii, Yuri Hasegawa, Yoichi Yamada, Reiji Kumai, and Yohei Yamamoto
    • Journal Title

      Asian J. Org. Chem.

      Volume: 3 Issue: 11 Pages: 1182-1182

    • DOI

      10.1002/ajoc.201402129

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Microscopic structure of K-doped organic monolayers2014

    • Author(s)
      Masahiro Yano, Ryosuke Okada, Megumi Endo, Ryosuke Shimizu, Yuri Hasegawa, Yoichi Yamada* and Masahiro Sasaki
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: -

    • NAID

      130004438894

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Cysteine Inhibits Amyloid Fibrillation of Lysozyme and Directs the Formation of Small Worm-Like Aggregates through Non-Covalent Interactions2014

    • Author(s)
      Eisuke Takai, Ken Uda, Shuhei Matsushita, Yui Shikiya, Yoichi Yamada, and Kentaro Shiraki, Tamotsu Zako and Mizuo Maeda
    • Journal Title

      Biotechnol Progress

      Volume: -

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] SCANNING ELECTRON MICROSCOPE IMAGING OF AMYLOID FIBRILS2014

    • Author(s)
      Eisuke Takai, Gai Ohashi, Ryuichi Ueki, Yoichi Yamada, Jun-Ichi Fujita, Kentaro Shiraki
    • Journal Title

      American Journal of Biochemistry and Biotechnology

      Volume: 10 Issue: 1 Pages: 31-39

    • DOI

      10.3844/ajbbsp.2014.31.39

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 膠膜表面に及ぼす加熱処理の影響2013

    • Author(s)
      福田 喜美子、長谷川 友里、松井 暁子、山田 洋一、佐々木 正洋、白木 賢太郎
    • Journal Title

      C & I Commun

      Volume: 38 Pages: 8-11

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] coronene単分子層へのアルカリ金属吸着2013

    • Author(s)
      遠藤めぐみ、矢野雅大、長谷川友里、岡田遼介、山田 洋一、佐々木正洋
    • Journal Title

      表面科学

      Volume: 34 Pages: 432-436

    • NAID

      10031190599

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] coronene単分子層へのアルカリ金属吸着2013

    • Author(s)
      遠藤めぐみ、矢野雅大、長谷川友里、岡田遼介、山田洋一、佐々木正洋
    • Journal Title

      表面科学

      Volume: in press

    • NAID

      10031190599

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Ordering of C_<60> on one-dimensional template of single-domain Ge(110)-16x2 and Si(110)-16x2 surfaces2012

    • Author(s)
      Y. Yokoyama, A. Sinsarp, Y. Yamada, H. Asaoka and M. Sasaki
    • Journal Title

      Appl. Phys. Express

      Volume: 5 Issue: 2 Pages: 25203-25203

    • DOI

      10.1143/apex.5.025203

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 先鋭化したシャープペンシル芯からの電界電子放出2015

    • Author(s)
      明神 拓真、麻薙 健、堀江 翔太、山田 洋一、佐々木 正洋
    • Organizer
      第62回応用物理学会春期学術講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Ge(100)表面の大気酸化物の放射光光電子分光分析2015

    • Author(s)
      吉越 章隆、岡田 隆太、岩井 優太郎、寺岡 有殿、山田 洋一、佐々木 正洋
    • Organizer
      第62回応用物理学会春期学術講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] DNTT多層膜の成長過程の分子レベル観察2015

    • Author(s)
      長谷川 友里、山田 洋一、佐々木 正洋、若山 裕
    • Organizer
      第62回応用物理学会春期学術講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Ge(110)表面におけるPt/Auナノワイヤー単一ドメインの作製2015

    • Author(s)
      渡邉 貴弘、石津 友康、山田 洋一、佐々木 正洋
    • Organizer
      第62回応用物理学会春期学術講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] 超音速希ガス原子線を用いたPt(111)上のgrapheneとh-BNの状態計測2015

    • Author(s)
      生津 達也、金城 厚、國原 淳、山田 洋一、佐々木 正洋
    • Organizer
      第62回応用物理学会春期学術講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Molecular arrangements and electronic modification of coronene and picene monolayers by K-doping2014

    • Author(s)
      M. Yano, M. Endo, R. Okada, Y. Hasegawa, Y, Yamada, M. Sasaki
    • Organizer
      Pacific Rim Symposium on Surfaces, Coatings and Interfaces (PacSurf 2014)
    • Place of Presentation
      Hapna Beach Prince Hotel, Hawaii
    • Year and Date
      2014-12-07 – 2014-12-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Well-Ordered Monolayers of Alkali-doped Coronene and Picene2014

    • Author(s)
      Y. Yamada, M. Yano, M. Endo, R. Shimizu, Y. Hasegawa, M. Sasaki
    • Organizer
      Pacific Rim Symposium on Surfaces, Coatings and Interfaces (PacSurf 2014)
    • Place of Presentation
      Hapna Beach Prince Hotel, Hawaii
    • Year and Date
      2014-12-07 – 2014-12-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synchrotron Radiation Photoelectron Spectroscopy Study on Surface Oxidation of Ge(100) and Ge(111) at Room Temperature2014

    • Author(s)
      A. Yoshigoe, R. Okada, Y. Teraoka, Y. Yamada, M. Sasaki
    • Organizer
      Pacific Rim Symposium on Surfaces, Coatings and Interfaces (PacSurf 2014)
    • Place of Presentation
      Hapna Beach Prince Hotel, Hawaii
    • Year and Date
      2014-12-07 – 2014-12-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Kドープしたフタロシアニン単分子層の分子レベル構造と電子状態2014

    • Author(s)
      長谷川友里、山田洋一、佐々木正洋、若山裕
    • Organizer
      第34回表面科学学術講演会
    • Place of Presentation
      島根県立産業交流会館(島根県松江市)
    • Year and Date
      2014-11-06 – 2014-11-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] Li内包C60の電子物性評価と電気二重層キャパシタへの応用2014

    • Author(s)
      佐藤翔、山田洋一、佐々木正洋、境誠司、權 垠相、笠間泰彦
    • Organizer
      第34回表面科学学術講演会
    • Place of Presentation
      島根県立産業交流会館(島根県松江市)
    • Year and Date
      2014-11-06 – 2014-11-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] He原子線散乱によるアルカリドーピングした有機単分子層の構造計測2014

    • Author(s)
      國原淳、金城厚、生津達也、山田洋一、佐々木正洋
    • Organizer
      第34回表面科学学術講演会
    • Place of Presentation
      島根県立産業交流会館(島根県松江市)
    • Year and Date
      2014-11-06 – 2014-11-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属及び半導体表面上でのpicene分子膜の成長過程計測2014

    • Author(s)
      清水亮介、矢野雅大、遠藤めぐみ、佐々木正洋、山田洋一
    • Organizer
      第34回表面科学学術講演会
    • Place of Presentation
      島根県立産業交流会館(島根県松江市)
    • Year and Date
      2014-11-06 – 2014-11-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] He原子線散乱を用いたKドープ coronene分子層の構造変化の計測2014

    • Author(s)
      國原淳,七辺寛幸,金城厚,山田洋一,佐々木正洋
    • Organizer
      第61回応用物理学会春期学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Kドープしたpicene単分子層の微視的構造2014

    • Author(s)
      清水亮助,矢野雅大,岡田遼介,遠藤めぐみ,山田洋一,佐々木正洋
    • Organizer
      第61回応用物理学会春期学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] K ドープされたフタロシアニン単分子膜の秩序形成2013

    • Author(s)
      長谷川友里,山田洋一,佐々木正洋,若山裕
    • Organizer
      2013年真空・表面科学合同講演会
    • Place of Presentation
      つくば国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] 超音速希ガス原子線散乱による金属基板上単層grapheneの計測2013

    • Author(s)
      七辺寛幸,金城厚,國原淳,山田洋一,佐々木正洋
    • Organizer
      第74回応用物理学会秋期学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Alkali Adsorption on Coronene Monolayer2013

    • Author(s)
      Y. Yamada, M. Yano、M. Endo, Y. Hasegawa R. Okada, M. Sasaki
    • Organizer
      NIMS conference 2013
    • Place of Presentation
      EPOCAL筑波
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 異なる基板上のcoronene分子層へのカリウム吸着2013

    • Author(s)
      矢野雅大,遠藤めぐみ,長谷川友里,岡田遼介,石津友康,山田洋一,佐々木正洋
    • Organizer
      第74回応用物理学会秋期学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Microscopic of Structure of metal-doped Organic layers2013

    • Author(s)
      Y. Yamada, M. Yano, M. Endo, R. Okada, Y. Hasegawa, and M. Sasaki
    • Organizer
      ACSIN-12
    • Place of Presentation
      つくば国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] K and Li Adsorption on Coronene layers on Different Substrates2013

    • Author(s)
      Masahiro Yano Megumi Endo, Yuri Hasegawa, Ryosuke Okada, Yoichi Yamada and Masahiro Sasaki
    • Organizer
      NIMS conference 2013
    • Place of Presentation
      EPOCAL筑波
    • Related Report
      2013 Research-status Report
  • [Presentation] 超音速希ガス原子線散乱による金属基板上単層grapheneの振動状態計測2013

    • Author(s)
      金城厚、七辺寛幸、山田洋一、佐々木正洋
    • Organizer
      応用物理学会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 希ガス原子線散乱による有機単分子層の計測2012

    • Author(s)
      渡邊研人、七辺寛幸、山田洋一、佐々木正洋
    • Organizer
      表面科学会
    • Place of Presentation
      東北大学片平キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] 超音速希ガス原子線散乱による有機単分子層の計測2012

    • Author(s)
      七辺寛幸、渡邊研人、山田洋一、佐々木正洋
    • Organizer
      真空に関する連合講演会
    • Place of Presentation
      甲南大学ポートアイランドキャンパス
    • Related Report
      2012 Research-status Report
  • [Remarks] 佐々木山田研究室

    • URL

      http://bukko.bk.tsukuba.ac.jp/~surflab/

    • Related Report
      2014 Annual Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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