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High-resolution analysis on ionic-liquid/electrode interfaces by freqency modulation AFM

Research Project

Project/Area Number 24760027
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionKyoto University

Principal Investigator

ICHII Takashi  京都大学, 工学(系)研究科(研究院), 助教 (30447908)

Research Collaborator SUGIMURA Hiroyuki  京都大学, 大学院工学研究科, 教授 (10293656)
MURASE Kuniaki  京都大学, 大学院工学研究科, 教授 (30283633)
NEGAMI Masahiro  京都大学, 大学院工学研究科, 修士課程学生
Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsイオン液体 / 固ー液界面 / 電気化学 / 原子間力顕微鏡 / 走査プローブ顕微鏡 / 固-液界面 / 界面
Research Abstract

We newly developed an electrochemical frequency modulation atomic force microscope (EC-FM-AFM) for imaging on ionic-liquid(IL)/electrode interfaces. A quartz tuning fork sensor was used as a force sensor instead of a Si cantilever, which enabled atomic-resolution imaging even in viscous ionic liquid. In addition, the AFM system was installed in a vacuum chamber in order to reduce the effect of water. By using this AFM, reconstruction of ions on the IL/electrode interface was directly visualized.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (47 results)

All 2014 2013 2012 Other

All Journal Article (4 results) (of which Peer Reviewed: 2 results) Presentation (38 results) (of which Invited: 6 results) Book (4 results) Remarks (1 results)

  • [Journal Article] Structural Analysis of Ionic-Liquid/ Organic-Monolayer Intarface by Phase Modulation Atomic Force Microscopy Utilizing a Quartz Tuning Fork Sensor2014

    • Author(s)
      Takashi Ichii, Masahiro Negami, Motohiko Fujimura, Kuniaki Murase, Hiroyuki Sugimura
    • Journal Title

      Electrochemistry

      Volume: 82(5) Pages: 380-384

    • Related Report
      2013 Final Research Report
  • [Journal Article] Structural Analysis of Ionic-Liquid/Organic-Monolayer Interface by Phase Modulation Atomic Force Microscopy Utilizing a Quartz Tuning Fork Sensor2014

    • Author(s)
      Takashi Ichii, Masahiro Negami, Motohiko Fujimura, Kuniaki Murase, Hiroyuki Sugimura
    • Journal Title

      Electrochemistry

      Volume: 82(5) Pages: 1-5

    • NAID

      130004562465

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Visualization of Ionic-Liquid/Solid Interfaces by Frequency Modulation Atomic Force Microscopy2012

    • Author(s)
      Masahiro Negami, Takashi Ichii, Kuniaki Murase, and Hiroyuki Sugimura
    • Journal Title

      ECS. Trans.

      Volume: 50(11) Pages: 349-355

    • Related Report
      2013 Final Research Report
  • [Journal Article] Visualization of Ionic-Liquid/Solid Interfaces by Frequency Modulation Atomic Force Microscopy2012

    • Author(s)
      Masahiro Negami, Takashi Ichii, Kuniaki Murase, Hiroyuki Sugimura
    • Journal Title

      ECS Transactions

      Volume: 50(11) Pages: 349-355

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] qPlusセンサ2014

    • Author(s)
      一井崇
    • Organizer
      平成25年度SPM実践セミナー
    • Place of Presentation
      産業技術総合研究所
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] qPlusセンサ2014

    • Author(s)
      一井 崇
    • Organizer
      平成25年度SPM実践セミナー
    • Place of Presentation
      産業技術総合研究所 つくば中央第2
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 周波数変調AFMによるイオン液体/アルカリハライド界面の構造分析2013

    • Author(s)
      一井崇,根上将大,杉村博之
    • Organizer
      第4回イオン液体圏討論会
    • Place of Presentation
      慶応義塾大学
    • Related Report
      2013 Final Research Report
  • [Presentation] 光干渉計を用いた液中FM-AFMの低ノイズ化2013

    • Author(s)
      下崎博貴,一井崇,杉村博之
    • Organizer
      第15回関西表面技術フォーラム
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Final Research Report
  • [Presentation] High-resolution FM-AFM Analysis on Ionic-Liquid/Ionic-Crystal Interfaces2013

    • Author(s)
      Takashi Ichii, Masahiro Negami, Hiroyuki Sugimura
    • Organizer
      12th International Conference on Atomically Controlles Surfaces, Interfaces and Nanostructures
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] 光干渉計を用いた液中FM-AFMの低ノイズ化2013

    • Author(s)
      下崎博貴,一井崇,杉村博之
    • Organizer
      2013年秋季第74回応用物理学会学術講演会
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Final Research Report
  • [Presentation] FM-AFMによるイオン液体/イオン結晶界面の構造分析2013

    • Author(s)
      一井崇,根上将大,杉村博之
    • Organizer
      2013年秋季第74回応用物理学会学術講演会
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Final Research Report
  • [Presentation] Low-noise deflection detection system of AFM with quartz tuning fork sensor for imaging in viscous liquid2013

    • Author(s)
      Hiroki Shitazaki, Masahiro Negami, Takashi Ichii, Hiroyuki Sugimura
    • Organizer
      19th International Vacuum Congress/International Conference on Nanoscience and Technology
    • Place of Presentation
      France
    • Related Report
      2013 Final Research Report
  • [Presentation] Direct Visualization of Electrochemical Behavior on Ionic-Liquid/Solid Interfaces by Frequency Modulation Atomic Force Microscopy2013

    • Author(s)
      Takashi Ichii, Masahiro Negami, Kuniaki Murase, Hiroyuki Sugimura
    • Organizer
      19th International Vacuum Congress/International Conference on Nanoscience and Technology
    • Place of Presentation
      France
    • Related Report
      2013 Final Research Report
  • [Presentation] QPlus FM-AFM for imaging in viscous ionic liquid2013

    • Author(s)
      Takashi Ichii, Masahiro Negami, Kuniaki Murase, Hiroyuki Sugimura
    • Organizer
      16th International Conference on Non-contact Atomic Force Microscopy
    • Place of Presentation
      USA
    • Related Report
      2013 Final Research Report
  • [Presentation] 電気化学AFMによるイオン液体-電極界面の構造分析2013

    • Author(s)
      一井崇
    • Organizer
      2013年度第1回関西電気化学研究会
    • Place of Presentation
      神戸大学
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 真空電気化学FM-AFMによるイオン液体-電極界面の構造分析2013

    • Author(s)
      根上将大,一井崇,邑瀬邦明,杉村博之
    • Organizer
      2013年春季第60回応用物理学会学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2013 Final Research Report
  • [Presentation] AFMで切り開くイオン液体の電気化学2013

    • Author(s)
      一井崇,根上将大,邑瀬邦明,杉村博之
    • Organizer
      2013年春季第60回応用物理学会学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] 電気化学AFMによるイオン液体-電極界面の構造分析2013

    • Author(s)
      一井 崇
    • Organizer
      2013年度第1回関西電気化学研究会
    • Place of Presentation
      神戸大学六甲台第2キャンパス
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] QPlus FM-AFM for imaging in viscous ionic liquid2013

    • Author(s)
      Takashi Ichii, Masahiro Negami, Kuniaki Murase, Hiroyuki Sugimura
    • Organizer
      16th International Conference on Non-Contact Atomic Force Microscopy
    • Place of Presentation
      Maryland, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] Direct Visualization of Electrochemical Behavior on Ionic-Liquid/Electrode Interfaces by Frequency Modulation Atomic Force Microscopy2013

    • Author(s)
      Takashi Ichii, Masahiro Negami, Kuniaki Murase, Hiroyuki Sugimura
    • Organizer
      19th International Vacuum Congress/International Conference on Nanoscience and Technology
    • Place of Presentation
      Paris, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] Low-noise deflection detection system of AFM with quartz tuning fork sensor for imaging in viscous liquid2013

    • Author(s)
      Hiroki Shitazaki, Masahiro Negami, Takashi,Ichiii, Hiroyuki Sugimura
    • Organizer
      19th International Vacuum Congress/International Conference on Nanoscience and Technology
    • Place of Presentation
      Paris, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] FM-AFMによるイオン液体/イオン結晶界面の構造分析2013

    • Author(s)
      一井 崇、根上 将大、杉村 博之
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] 光干渉計を用いた液中FM-AFMの低ノイズ化2013

    • Author(s)
      下崎 博貴,一井 崇,杉村 博之
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学 京田辺キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] High-resolution FM-AFM Analysis on Ionic-Liquid/Ionic-Crystal Interfaces2013

    • Author(s)
      Takashi Ichii, Masahiro Negami, Hiroyuki Sugimura
    • Organizer
      12th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures (ACSIN-12)
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] 光干渉変位計測による液中AFMの低ノイズ化2013

    • Author(s)
      下崎博貴,一井崇,杉村博之
    • Organizer
      第15回関西表面技術フォーラム
    • Place of Presentation
      岡山大学 津島キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] 周波数変調AFMによるイオン液体/アルカリハライド界面の構造分析2013

    • Author(s)
      一井 崇、根上 将大、杉村 博之
    • Organizer
      第4回イオン液体討論会
    • Place of Presentation
      慶應義塾大学日吉キャンパス独立館
    • Related Report
      2013 Annual Research Report
  • [Presentation] AFMで切り開くイオン液体の電気化学2013

    • Author(s)
      一井 崇,根上 将大,邑瀬 邦明,杉村 博之
    • Organizer
      2013年春季 第60回応用物理学会学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 真空電気化学FM-AFMによるイオン液体-電極界面の構造分析2013

    • Author(s)
      根上 将大,一井 崇,邑瀬 邦明,杉村 博之
    • Organizer
      2013年春季 第60回応用物理学会学術講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 電気化学FM-AFMによるイオン液体-電極界面のin situ構造分析2012

    • Author(s)
      一井崇,根上将大,邑瀬邦明,杉村博之
    • Organizer
      第3回イオン液体討論会
    • Place of Presentation
      沖縄
    • Related Report
      2013 Final Research Report
  • [Presentation] Ionic-Liquid/Electrode Interfaces Investigated by Electrochemical FM-AFM with a Quartz Tuning Fork Sensor2012

    • Author(s)
      Takashi Ichii, Masahiro Negami, Kuniaki Murase, and Hiroyuki Sugimura
    • Organizer
      The 20th International Colloquium on Scanning Probe Microscopy
    • Place of Presentation
      Okinawa, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Development of Vacuum Electrochemical FM-AFM for Investigation of Ionic-Liquid/Electrode Interfaces2012

    • Author(s)
      Masahiro Negami, Takashi Ichii, Kuniaki Murase, and Hiroyuki Sugimura
    • Organizer
      The 20th International Colloquium on Scanning Probe Microscopy
    • Place of Presentation
      Okinawa, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Ionic-Liquid/Electrode Interfaces Investigated by Electrochemical Atomic Force Microscopy2012

    • Author(s)
      Takashi Ichii, Masahiro Negami, Kuniaki Murase, Hiroyuki Sugimura
    • Organizer
      KJF International Conference on Organic Materials for Electronics and Photonics 2012
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] 電気化学FM-AFMによるイオン液体-電極界面のin situ測定2012

    • Author(s)
      根上将大,一井崇,邑瀬邦明,杉村博之
    • Organizer
      2012年秋季第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学
    • Related Report
      2013 Final Research Report
  • [Presentation] Visualization of Ionic-Liquid/Solid Interfaces by Frequency Modulation Atomic Force Microscopy2012

    • Author(s)
      Masahiro Negami, Takashi Ichii, Kuniaki Murase, and Hiroyuki Sugimura
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science
    • Place of Presentation
      USA
    • Related Report
      2013 Final Research Report
  • [Presentation] Electrochemical Behavior of Ionic-Liquid/Electrode Interfaces Investigated by FM-AFM with Quartz Tuning Fork Sensors2012

    • Author(s)
      Takashi Ichii, Masahiro Negami, Kuniaki Murase, Hiroyuki Sugimura
    • Organizer
      15th International Conference on Non-contact Atomic Force Microscopy
    • Place of Presentation
      Czech Republic
    • Related Report
      2013 Final Research Report
  • [Presentation] Electrochemical Behavior of Ionic-Liquid/Electrode Interfaces Investigated by FM-AFM with Quartz Tuning Folk Sensors2012

    • Author(s)
      Takashi Ichii, Masahiro Negami, Kuniaki Murase, Hiroyuki Sugimura
    • Organizer
      15th International Conference on non-contact Atomic Force Microscopy
    • Place of Presentation
      Cesky Krumlov (Czech republic)
    • Related Report
      2012 Research-status Report
  • [Presentation] Visualization of Ionic-Liquid/Solid Interfaces by Frequency Modulation Atomic Force Microscopy2012

    • Author(s)
      Masahiro Negami, Takashi Ichii, Kuniaki Murase, Hiroyuki Sugimura
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science (PRiME2012)
    • Place of Presentation
      Hilton Hawaiian Village Hotel and Hawaii Convention Center (USA)
    • Related Report
      2012 Research-status Report
  • [Presentation] 電気化学FM-AFMによるイオン液体-電極界面のin situ測定2012

    • Author(s)
      根上 将大,一井 崇,邑瀬 邦明,杉村 博之
    • Organizer
      2012年 秋季 第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学城北地区,松山大学文京キャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] Ionic-Liquid/Electrode Interfaces Investigated by Electrochemical Atomic Force Microscopy2012

    • Author(s)
      Takashi Ichii, Masahiro Negami, Kuniaki Murase and Hiroyuki Sugimura
    • Organizer
      KJF International Conference on Organic Materials for Electronic and Photonics 2012
    • Place of Presentation
      Tohoku University, Sendai, Miyagi, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] Development of Vacuum Electrochemical FM-AFM for Investigation of Ionic-Liquid/Electrode Interfaces2012

    • Author(s)
      Masahiro Negami, Takashi Ichii, Kuniaki Murase and Hiroyuki Sugimura
    • Organizer
      The 20th International Colloquium on Scanning Probe Microscopy
    • Place of Presentation
      沖縄かりゆしアーバンリゾート・ナハ
    • Related Report
      2012 Research-status Report
  • [Presentation] 電気化学AFMによるイオン液体-電極界面のin situ構造分析2012

    • Author(s)
      一井 崇, 根上 将大, 邑瀬 邦明, 杉村 博之
    • Organizer
      第3回イオン液体討論会
    • Place of Presentation
      沖縄県男女共同参画センター 「てぃるる」
    • Related Report
      2012 Research-status Report
  • [Presentation] Ionic-Liquid/Electrode Interfaces Investigated by Electrochemical FM-AFM with a Quartz Tuning Fork Sensor2012

    • Author(s)
      Takashi Ichii, Masahiro Negami, Kuniaki Murase, Hiroyuki Sugimura
    • Organizer
      The 20th International Colloquium on Scanning Probe Microscopy
    • Place of Presentation
      沖縄かりゆしアーバンリゾート・ナハ
    • Related Report
      2012 Research-status Report
  • [Book] 走査型プローブ顕微鏡入門2013

    • Author(s)
      秦信宏(著),秋永広幸(監修)
    • Publisher
      オーム社
    • Related Report
      2013 Final Research Report
  • [Book] In-situ測定/その場観察実例集~各種計測技術の実践テクニックおよび材料/デバイス別分析例2013

    • Publisher
      情報機構
    • Related Report
      2013 Final Research Report
  • [Book] 走査型プローブ顕微鏡入門2013

    • Author(s)
      秦 信宏 (著), 秋永 広幸 (監修)
    • Total Pages
      252
    • Publisher
      オーム社
    • Related Report
      2013 Annual Research Report
  • [Book] In-situ測定/その場観察 実例集~各種計測技術の実践テクニックおよび材料/デバイス別分析例2013

    • Author(s)
      情報機構
    • Total Pages
      315
    • Publisher
      情報機構
    • Related Report
      2013 Annual Research Report
  • [Remarks]

    • URL

      http://www.nsa.mtl.kyotou.ac.jp/

    • Related Report
      2013 Final Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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