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Study of development of Heusler-type functional materials for high performance thermoelectric thin films

Research Project

Project/Area Number 24760536
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Physical properties of metals
Research InstitutionNagoya Institute of Technology

Principal Investigator

MIYAZAKI HIDETOSHI  名古屋工業大学, 工学(系)研究科(研究院), 助教 (10548960)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywords熱電材料 / 電子構造 / 薄膜 / 熱電変換材料 / ホイスラー化合物 / Fe2VAl
Research Abstract

For the application of thermoelectric materials to power generation, it is desirable to shift the peak temperature of the thermoelectric power factor up to, e.g., 600 K and above. The disadvantages of Fe2VAl-based thermoelectric materials are a peak temperature of the thermoelectric power factor of <400 K and a high thermal conductivity value. To improve the thermoelectric properties of the Fe2VAl-based alloys, the aims of my five-year research project were to explore new doping and substitution elements, and clarify the mechanism by which their thermoelectric properties are improved. The results are:1) Improvement of the thermoelectric properties of the Heusler Fe2VAl alloys due to the fabrication of the off-stoichiometric type Fe2V1+xAl1-x and fourth-element doping type Fe2VAl1-yTay alloys. 2) Clarification of the improvement of the thermoelectric properties of the Heusler Fe2VAl alloys. 3) Development of a thin- film deposition system for the fabrication of Fe2VAl thin films.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (22 results)

All 2014 2013 2012 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (12 results) (of which Invited: 2 results) Remarks (2 results)

  • [Journal Article] Thermoelectric Properties of the Heusler-type Off-stoichiometric Fe2V1+xAl1-x Alloys2014

    • Author(s)
      H. Miyazaki, S. Tanaka, N. Ide, K. Soda, Y. Nishino
    • Journal Title

      Materials Research Express

      Volume: 1 Issue: 1 Pages: 15901-15901

    • DOI

      10.1088/2053-1591/1/1/015901

    • NAID

      120005621880

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermoelectric properties of the Heusler-type Fe_2VTa_xAl_<1-x> alloys2014

    • Author(s)
      Krystel Renard, Arinori Mori, Yuichiro Yamada, Suguru Tanaka, Hidetoshi Miyazaki, Yoichi Nishino
    • Journal Title

      Journal of Applied Physics

      Volume: 115 Issue: 3 Pages: 33707-33707

    • DOI

      10.1063/1.4861419

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Three-Dimensional Angle-Resolved Photoemission Spectra of EuO Thin Films2014

    • Author(s)
      H. Miyazaki, H. Mitani, T. Hajiri, M. Matsunami, T. Ito, and S. Kimura
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena 191

      Volume: 7 Pages: 4-4

    • DOI

      10.1016/j.elspec.2013.10.008

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermoelectric properties of Al-(Mn, X)-Si C54-phase (X=Ru, Re)2014

    • Author(s)
      山本晃生, 宮崎秀俊, 竹内恒博
    • Journal Title

      Joumal of Applied Physics

      Volume: 115 Issue: 2 Pages: 0237081-10

    • DOI

      10.1063/1.4861643

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Strongly hybridized electronic structure of YbAl_2: An angle-resolved photoemission study2013

    • Author(s)
      M. Matsunami, T. Hajiri, H. Miyazaki, M. Kosaka, S. Kimura
    • Journal Title

      Phys. Rev.

      Volume: B 87 Issue: 16

    • DOI

      10.1103/physrevb.87.165141

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Atomic and electronic structure of ultrathin Bi(111) films grown on Bi_2Te_3(111) substrates: Evidence for a strain-induced topological phase transition2012

    • Author(s)
      T. Hirahara, N. Fukui, T. Shirasawa, M. Yamada, M. Aitani, H. Miyazaki, M. Matsunami, S. Kimura, T. Takahashi, S. Hasegawa, K. Kobayashi
    • Journal Title

      Phys. Rev. Lett.

      Volume: 109 Issue: 22 Pages: 227401-227401

    • DOI

      10.1103/physrevlett.109.227401

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Momentum-dependent hybridization gap and dispersive in-gap state of the Kondo semiconductor SmB_62012

    • Author(s)
      H. Miyazaki, T. Hajiri, T. Ito, S. Kunii, S. Kimura
    • Journal Title

      Phys. Rev.

      Volume: B 86 Issue: 7 Pages: 75105-75105

    • DOI

      10.1103/physrevb.86.075105

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fabrication of single crystalline EuO thin films with SrO buffer layer on SrTiO_03 substrate2012

    • Author(s)
      H. Miyazaki, H. Momiyama, T. Hajiri, T. Ito, K. Imura, M. Matsunami, S. Kimura
    • Journal Title

      J. Phys.: Conf. Ser.

      Volume: 391 Pages: 12047-12047

    • DOI

      10.1088/1742-6596/391/1/012047

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] ホイスラー型熱電材料Fe_2V_<1+x>Al_<1-x>における熱電特性向上のメカニズムの解明2014

    • Author(s)
      宮崎秀俊, Renard Krystel,山田友一朗,森侑礼,西野洋一
    • Organizer
      日本金属学会2014年春季講演大会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2014-03-23
    • Related Report
      2013 Final Research Report
  • [Presentation] ハーフホイスラー型熱電材料ZrNiSnにおける元素ドープが及ぼす電子構造への影響2014

    • Author(s)
      宮崎秀俊,吉田健人,服部健吾,西野洋一
    • Organizer
      日本金属学会2014年春季講演大会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2014-03-21
    • Related Report
      2013 Final Research Report
  • [Presentation] Thermoelectric properties of the Heusler-type off-stoichiometric Fe2VAl alloys2014

    • Author(s)
      Hidetoshi Miyazaki, Suguru Tanaka, and Yoichi Nishino
    • Organizer
      The 15th International Symposium on Eco-Materials Processing and Design
    • Place of Presentation
      Hanoi University of Science and Technilogy, Hanoi, Vietnam
    • Related Report
      2013 Annual Research Report
  • [Presentation] 角度分解光電子分光を用いた非化学量論組成Fe_2V_<1+x>Al_<1-x>の電子構造2013

    • Author(s)
      宮崎秀俊,西澤一晃,曽田一雄,松波雅治,木村真一,西野洋一
    • Organizer
      日本物理学会2013年秋季講演大会
    • Place of Presentation
      徳島大学
    • Year and Date
      2013-09-26
    • Related Report
      2013 Final Research Report
  • [Presentation] 高分解能粉末X線回折法によるハーフホイスラー型熱電変換材料ZrNiSnの構造解析2013

    • Author(s)
      宮崎秀俊,山田友一朗,中野輝章,西野洋一
    • Organizer
      日本金属学会2013年春季講演大会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2013-03-29
    • Related Report
      2013 Final Research Report
  • [Presentation] hermoelectric Properties of Off-stoichiomeric Heusler Compounds Fe2V1+xAl1-x2013

    • Author(s)
      Hidetoshi Miyazaki, Suguru Tanaka, Naoki Ide, Kazuo Soda, and Yoichi Nishino
    • Organizer
      The 32nd International Conference of Thermoelectrics
    • Place of Presentation
      Kobe, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Electronic and Local Crystal Structure of the Half Heusler Compound ZrNiSn2013

    • Author(s)
      Hidetoshi Miyazaki, Teruaki Nakano, Kazuo Soda, and Yoichi Nishino
    • Organizer
      The 32nd International Conference of Thermoelectrics
    • Place of Presentation
      Kobe, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] 軟X線光電子分光を用いたホイスラー型熱電材料Fe_2V_<1+x>Al_<1-x>の電子状態2012

    • Author(s)
      宮崎秀俊、田中優、山田友一朗、泉雄大、室隆桂之、曽田一雄、西野洋一
    • Organizer
      日本金属学会2012年秋季講演大会
    • Place of Presentation
      金沢大学
    • Year and Date
      2012-09-17
    • Related Report
      2013 Final Research Report
  • [Presentation] ハーフホイスラー型ZrNiSnの電子状態2012

    • Author(s)
      宮崎秀俊、中野輝章、松波雅治、木村真一、泉雄大、室隆桂之、曽田一雄、西野洋一
    • Organizer
      UVSORシンポジウム2012
    • Place of Presentation
      分子科学研究所
    • Related Report
      2012 Research-status Report
  • [Presentation] 軟X線光電子分光を用いたホイスラー型熱電材料Fe2V1+xAl1-xの電子状態2012

    • Author(s)
      宮崎秀俊、田中優、山田友一朗、泉雄大、室隆桂之、曽田一雄、西野洋一
    • Organizer
      日本金属学会2012年秋季講演大会
    • Place of Presentation
      愛媛大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 光電子分光およびバンド計算を利用した熱電変換材料の材料開発2012

    • Author(s)
      宮崎秀俊
    • Organizer
      日本熱電学会第15回研究会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Thickness-dependent exchange splitting of EuO ultrathin films2012

    • Author(s)
      Hidetoshi Miyazaki, Tetsuya Hajiri, Masaharu Matsunami, Takahiro Ito, and Shin-chi Kimura
    • Organizer
      The 19th International Conference on Magnetism
    • Place of Presentation
      釜山
    • Related Report
      2012 Research-status Report
    • Invited
  • [Remarks]

    • URL

      http://www.emat.nitech.ac.jp/solid/

    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://wakate.adm.nitech.ac.jp/node/219

    • Related Report
      2013 Final Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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